Cathode in the context of Hofmann voltameter


Cathode in the context of Hofmann voltameter

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⭐ Core Definition: Cathode

A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead–acid battery. This definition can be recalled by using the mnemonic CCD for Cathode Current Departs. Conventional current describes the direction in which positive charges move. Electrons, which are the carriers of current in most electrical systems, have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow: this means that electrons flow into the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode.

The electrode through which conventional current flows the other way, into the device, is termed an anode.

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👉 Cathode in the context of Hofmann voltameter

A Hofmann voltameter is an apparatus for electrolysing water, invented by August Wilhelm von Hofmann (1818–1892) in 1866. It consists of three joined upright cylinders, usually glass. The inner cylinder is open at the top to allow addition of water which contains a low concentration of a compound such as sulfuric acid to improve conductivity and complete the circuit. A platinum electrode is placed inside the bottom of each of the two side cylinders, connected to the positive and negative terminals of a source of electricity. When current is run through Hofmann's voltameter, gaseous oxygen forms at the anode and gaseous hydrogen at the cathode. Each gas displaces water and collects at the top of the two outer tubes.

The tubes which collect the product gases are usually graduated, so that the volume of gas can be measured.

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Cathode in the context of Pitting corrosion

Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic (oxidation reaction) while an unknown but potentially vast area becomes cathodic (reduction reaction), leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.

Another term arises, pitting factor, which is defined as the ratio of the depth of the deepest pit (from localized corrosion) to the average penetration depth (mean thickness of the corrosion layer produced by the general uniform corrosion), which can be calculated based on the weight loss and corrosion products density.

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Cathode in the context of Electrofishing

Electrofishing is a fishing technique that uses direct current electricity flowing between a submerged cathode and anode. This affects the movements of nearby fish so that they swim toward the anode, where they can be caught or stunned.

Electrofishing is a common scientific survey method used to sample fish populations to determine abundance, population density and species composition. When performed correctly, electrofishing results in no permanent harm to the fish, which return to their natural mobility state in as little as two minutes after being caught.

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Cathode in the context of Battery (electricity)

An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. The terminal marked negative is the source of electrons. When a battery is connected to an external electric load, those negatively charged electrons flow through the circuit and reach the positive terminal, thus causing a redox reaction by attracting positively charged ions, or cations. Thus, higher energy reactants are converted to lower energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell.

Primary (single-use or "disposable") batteries are used once and discarded, as the electrode materials are irreversibly changed during discharge; a common example is the alkaline battery used for flashlights and a multitude of portable electronic devices. Secondary (rechargeable) batteries can be discharged and recharged multiple times using an applied electric current; the original composition of the electrodes can be restored by reverse current. Examples include the lead–acid batteries used in vehicles and lithium-ion batteries used for portable electronics such as laptops and mobile phones.

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Cathode in the context of Michael Faraday

Michael Faraday (UK: /ˈfærəˌd/ FAR-uh-day, US: /ˈfærədi/ FAR-uh-dee; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic induction, diamagnetism, and electrolysis. Although Faraday received little formal education, as a self-made man, he was one of the most influential scientists in history. It was by his research on the magnetic field around a conductor carrying a direct current that Faraday established the concept of the electromagnetic field in physics. Faraday also established that magnetism could affect rays of light and that there was an underlying relationship between the two phenomena. He similarly discovered the principles of electromagnetic induction, diamagnetism, and the laws of electrolysis. His inventions of electromagnetic rotary devices formed the foundation of electric motor technology, and it was largely due to his efforts that electricity became practical for use in technology. The SI unit of capacitance, the farad, is named after him.

As a chemist, Faraday discovered benzene and carbon tetrachloride, investigated the clathrate hydrate of chlorine, invented an early form of the Bunsen burner and the system of oxidation numbers, and popularised terminology such as "anode", "cathode", "electrode" and "ion". Faraday ultimately became the first and foremost Fullerian Professor of Chemistry at the Royal Institution, a lifetime position.

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Cathode in the context of Fluorescent lamp

A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, to produce ultraviolet and make a phosphor coating in the lamp glow. Fluorescent lamps convert electrical energy into visible light much more efficiently than incandescent lamps, but are less efficient than most LED lamps. The typical luminous efficacy of fluorescent lamps is 50–100 lumens per watt, several times the efficacy of general lighting incandescent bulbs with comparable light output, which is on the close order of 16 lm/W.

Fluorescent lamp fixtures are more costly than incandescent lamps because, among other things, they require a ballast to regulate current through the lamp, but the initial cost is offset by a much lower running cost. Compact fluorescent lamps (CFL) made in the same sizes as incandescent lamp bulbs are used as an energy-saving alternative to incandescent lamps in homes.

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Cathode in the context of Diode

A diode is a two-terminal electronic component that conducts electric current primarily in one direction (asymmetric conductance). It has low (ideally zero) resistance in one direction and high (ideally infinite) resistance in the other.

A semiconductor diode, the most commonly used type today, is a crystalline piece of semiconductor material with a p–n junction connected to two electrical terminals. It has an exponential current–voltage characteristic. Semiconductor diodes were the first semiconductor electronic devices. The discovery of asymmetric electrical conduction across the contact between a crystalline mineral and a metal was made by German physicist Ferdinand Braun in 1874. Today, most diodes are made of silicon, but other semiconducting materials such as gallium arsenide and germanium are also used.

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Cathode in the context of Cathode ray

Cathode rays are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to electrons emitted from the cathode (the electrode connected to the negative terminal of the voltage supply). They were first observed in 1859 by German physicist Julius Plücker and Johann Wilhelm Hittorf, and were named in 1876 by Eugen Goldstein Kathodenstrahlen, or cathode rays. In 1897, British physicist J. J. Thomson showed that cathode rays were composed of a previously unknown negatively charged particle, which was later named the electron. Cathode-ray tubes (CRTs) use a focused beam of electrons deflected by electric or magnetic fields to render an image on a screen.

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Cathode in the context of Nixie tube

A Nixie tube (/ˈnɪk.s/ NIK-see), or cold cathode display, is an electronic device used for displaying numerals or other information using glow discharge.

The glass tube contains a wire-mesh anode and multiple cathodes, shaped like numerals or other symbols. Applying power to one cathode surrounds it with an orange glow discharge. The tube is filled with a gas at low pressure, usually mostly neon and a small amount of argon, in a Penning mixture. In later nixies, in order to extend the usable life of the device, a tiny amount of mercury was added to reduce cathode poisoning and sputtering.

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Cathode in the context of Electroplating

Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be coated acts as the cathode (negative electrode) of an electrolytic cell; the electrolyte is a solution of a salt whose cation is the metal to be coated, and the anode (positive electrode) is usually either a block of that metal, or of some inert conductive material. The current is provided by an external power supply.

Electroplating is widely used in industry and decorative arts to improve the surface qualities of objects—such as resistance to abrasion and corrosion, lubricity, reflectivity, electrical conductivity, or appearance. It is used to build up thickness on undersized or worn-out parts and to manufacture metal plates with complex shape, a process called electroforming. It is used to deposit copper and other conductors in forming printed circuit boards and copper interconnects in integrated circuits. It is also used to purify metals such as copper.

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Cathode in the context of Triode

A triode is an electronic amplifying vacuum tube (or thermionic valve in British English) consisting of three electrodes inside an evacuated glass envelope: a heated filament or cathode, a grid, and a plate (anode).

Developed from Lee De Forest's 1906 Audion, a partial vacuum tube that added a grid electrode to the thermionic diode (Fleming valve), the triode was the first practical electronic amplifier and the ancestor of other types of vacuum tubes such as the tetrode and pentode. Its invention helped make amplified radio technology and long-distance telephony possible. Triodes were widely used in consumer electronics devices such as radios and televisions until the 1970s, when transistors replaced them. Today, their main remaining use is in high-power RF amplifiers in radio transmitters and industrial RF heating devices. In recent years there has been a resurgence in demand for low power triodes due to renewed interest in tube-type audio equipment by audiophiles who prefer the sound of tube-based electronics.

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Cathode in the context of Electrode

An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a variety of materials (chemicals) depending on the type of cell. An electrode may be called either a cathode or anode according to the direction of the electric current, unrelated to the potential difference between electrodes.

Michael Faraday coined the term "electrode" in 1833; the word recalls the Greek ἤλεκτρον (ḗlektron, "amber") and ὁδός (hodós, "path, way").

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Cathode in the context of Hot cathode

In vacuum tubes and gas-filled tubes, a hot cathode or thermionic cathode is a cathode electrode which is heated to make it emit electrons due to thermionic emission. This is in contrast to a cold cathode, which does not have a heating element. The heating element is usually an electrical filament heated by a separate electric current passing through it. Hot cathodes typically achieve much higher power density than cold cathodes, emitting significantly more electrons from the same surface area. Cold cathodes rely on field electron emission or secondary electron emission from positive ion bombardment, and do not require heating. There are two types of hot cathode. In a directly heated cathode, the filament is the cathode and emits the electrons. In an indirectly heated cathode, the filament or heater heats a separate metal cathode electrode which emits the electrons.

From the 1920s to the 1960s, a wide variety of electronic devices used hot-cathode vacuum tubes. Today, hot cathodes are used as the source of electrons in fluorescent lamps, vacuum tubes, and the electron guns used in cathode-ray tubes and laboratory equipment such as electron microscopes.

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Cathode in the context of Anode

An anode usually is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, which is usually an electrode of the device through which conventional current leaves the device. A common mnemonic is ACID, for "anode current into device". The direction of conventional current (the flow of positive charges) in a circuit is opposite to the direction of electron flow, so (negatively charged) electrons flow from the anode of a galvanic cell, into an outside or external circuit connected to the cell. For example, the end of a household battery marked with a "+" is the cathode (while discharging).

In both a galvanic cell and an electrolytic cell, the anode is the electrode at which the oxidation reaction occurs. In a galvanic cell the anode is the wire or plate having excess negative charge as a result of the oxidation reaction. In an electrolytic cell, the anode is the wire or plate upon which excess positive charge is imposed. As a result of this, anions will tend to move towards the anode where they will undergo oxidation.

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Cathode in the context of Electrowinning

Electrowinning, also called electroextraction, is the electrodeposition of metals from their ores that have been put in solution via a process commonly referred to as leaching. Electrorefining uses a similar process to remove impurities from a metal. However, in electrorefining, the overall electron balance is zero, whereas electrowinning shows a net positive electron consumption in the overall reaction. Both processes use electroplating on a large scale and are important techniques for the economical and straightforward purification of non-ferrous metals. The resulting metals are said to be electrowon.

In electrowinning, an electrical current is passed from an inert anode through a leach solution containing the dissolved metal ions so that the metal is recovered as it is reduced and deposited in an electroplating process onto the cathode. In electrorefining, the anode consists of the impure metal (e.g., copper) to be refined. The impure metallic anode is oxidized and the metal dissolves into solution. The metal ions migrate through the electrolyte towards the cathode where the pure metal is deposited. Insoluble solid impurities sedimenting below the anode often contain valuable rare elements such as gold, silver and selenium.

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Cathode in the context of Non-ferrous extractive metallurgy

Non-ferrous extractive metallurgy is one of the two branches of extractive metallurgy which pertains to the processes of reducing valuable, non-iron metals from ores or raw material. Metals like zinc, copper, lead, aluminium as well as rare and noble metals are of particular interest in this field, while the more common metal, iron, is considered a major impurity. Like ferrous extraction, non-ferrous extraction primarily focuses on the economic optimization of extraction processes in separating qualitatively and quantitatively marketable metals from its impurities (gangue).

Any extraction process will include a sequence of steps or unit processes for separating highly pure metals from undesirables in an economically efficient system. Unit processes are usually broken down into three categories: pyrometallurgy, hydrometallurgy, and electrometallurgy. In pyrometallurgy, the metal ore is first oxidized through roasting or smelting. The target metal is further refined at high temperatures and reduced to its pure form. In hydrometallurgy, the object metal is first dissociated from other materials using a chemical reaction, which is then extracted in pure form using electrolysis or precipitation. Finally, electrometallurgy generally involves electrolytic or electrothermal processing. The metal ore is either distilled in an electrolyte or acid solution, then magnetically deposited onto a cathode plate (electrowinning); or smelted then melted using an electric arc or plasma arc furnace (electrothermic reactor).

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