In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant.
The clear liquid remaining above the precipitated or the centrifuged solid phase is also called the supernate or supernatant.
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The Messinian salinity crisis (also referred to as the Messinian event, and in its latest stage as the Lago Mare event) was an event in which the Mediterranean Sea went into a cycle of partial or nearly complete desiccation (drying-up) throughout the latter part of the Messinian age of the Miocene epoch, from 5.96 to 5.33 Ma (million years ago). It ended with the Zanclean flood, when the Atlantic reclaimed the basin.
Sediment samples from below the deep seafloor of the Mediterranean Sea, which include evaporite minerals, soils, and fossil plants, show that the precursor of the Strait of Gibraltar closed about 5.96 million years ago, sealing the Mediterranean off from the Atlantic. This resulted in a period of partial desiccation of the Mediterranean Sea, the first of several such periods during the late Miocene. After the strait closed for the last time around 5.6 Ma, the region's generally dry climate at the time dried the Mediterranean basin out nearly completely within a thousand years. This massive desiccation left a deep dry basin, reaching 3 to 5 km (1.9 to 3.1 mi) deep below normal sea level, with a few hypersaline pockets similar to today's Dead Sea. Then, around 5.5 Ma, wetter climatic conditions resulted in the basin receiving more fresh water from rivers, progressively filling and diluting the hypersaline lakes into larger pockets of brackish water (much like today's Caspian Sea). The Messinian salinity crisis ended with the Strait of Gibraltar finally reopening 5.33 Ma, when the Atlantic rapidly filled up the Mediterranean basin in what is known as the Zanclean flood.
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite, a closely related rock, which contains a high percentage of the mineral dolomite, CaMg(CO3)2. Magnesian limestone is an obsolete and poorly defined term used variously for dolomite, for limestone containing significant dolomite (dolomitic limestone), or for any other limestone containing a significant percentage of magnesium. Most limestone was formed in shallow marine environments, such as continental shelves or platforms, though smaller amounts were formed in many other environments. Much dolomite is secondary dolomite, formed by chemical alteration of limestone. Limestone is exposed over large regions of the Earth's surface, and because limestone is slightly soluble in rainwater, these exposures often are eroded to become karst landscapes. Most cave systems are found in limestone bedrock.
In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation. The hydraulic flow involved is usually due to hydrothermal circulation.
Veins are classically thought of as being planar fractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space. This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins: open-space filling and crack-seal growth.
Crystallization is a process that leads to solids with highly organized atoms or molecules, i.e. a crystal. The ordered nature of a crystalline solid can be contrasted with amorphous solids in which atoms or molecules lack regular organization. Crystallization can occur by various routes including precipitation from solution, freezing of a liquid, or deposition from a gas. Attributes of the resulting crystal can depend largely on factors such as temperature, air pressure, cooling rate, or solute concentration.
Crystallization occurs in two main phases. The first is nucleation, the appearance of a crystalline phase from either a supercooled liquid or a supersaturated solvent. The second step is known as crystal growth, which is the increase in the size of particles and leads to a crystal state. An important feature of this step is that loose particles form layers at the crystal's surface and lodge themselves into open inconsistencies such as pores, cracks, etc.
Diagenesis (/ˌdaɪ.əˈdʒɛnəsɪs/) is the process of physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion (clay sediments), while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens.
The process of diagenesis excludes surface alteration (weathering) and deep metamorphism. There is no sharp boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures. Hydrothermal solutions, meteoric groundwater, rock porosity, permeability, dissolution/precipitation reactions, and time are all influential factors.
Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (CaCO3), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.
The crystal lattice of aragonite differs from that of calcite, resulting in a different crystal shape, an orthorhombic crystal system with acicular crystal. Repeated twinning results in pseudo-hexagonal forms. Aragonite may be columnar or fibrous, occasionally in branching helictitic forms called flos-ferri ("flowers of iron") from their association with the ores at the Carinthian iron mines.
Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term tannin is widely applied to any large polyphenolic compound containing sufficient hydroxyls and other suitable groups (such as carboxyls) to form strong complexes with various macromolecules.
The term tannin (from scientific French tannin, from French tan "crushed oak bark", tanner "to tan", cognate with English tanning, Medieval Latin tannare, from Proto-Celtic *tannos "oak") refers to the abundance of these compounds in oak bark, which was used in tanning animal hides into leather.
Chert (/tʃɜːrt/) is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood. Where chert occurs in chalk or marl, it is usually called flint.
Chert is typically composed of the petrified remains of siliceous ooze, the biogenic sediment that covers large areas of the deep ocean floor, and which contains the silicon skeletal remains of diatoms, silicoflagellates, and radiolarians. Precambrian cherts are notable for the presence of fossil cyanobacteria. In addition to microfossils, chert occasionally contains macrofossils. However, some chert is devoid of any fossils.