Atmospheric methane in the context of "8.2-kiloyear event"

The Archean (IPA: /ɑːrˈkiːən/ ar-KEE-ən, also spelled Archaean or Archæan), in older sources sometimes called the Archaeozoic, is the second of the four geologic eons of Earth's history, preceded by the Hadean Eon and followed by the Proterozoic and the Phanerozoic. The Archean represents the time period from 4,031 to 2,500 Ma (million years ago). The Late Heavy Bombardment is hypothesized to overlap with the beginning of the Archean. The oldest known glaciation occurred in the middle of the eon.

The Earth during the Archean was mostly a water world: there was continental crust, but much of it was under an ocean deeper than today's oceans. Except for some rare relict crystals (Hadean zircon), today's oldest continental crust dates back to the Archean. Much of the geological detail of the Archean has been destroyed by subsequent tectonic activity. The Earth's atmosphere was also vastly different in composition from today's: the prebiotic atmosphere was a reducing atmosphere rich in methane and lacking free oxygen.

Methane (US: /ˈmɛθeɪn/ METH-ayn, UK: /ˈmiːθeɪn/ MEE-thayn) is a chemical compound with the chemical formula CH₄ (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an organic hydrocarbon, and among the simplest of organic compounds.

Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane.

Due to climate change in the Arctic, this polar region is expected to become "profoundly different" by 2050. The speed of change is "among the highest in the world", with warming occurring at 3-4 times faster than the global average. This warming has already resulted in the profound Arctic sea ice decline, the accelerating melting of the Greenland ice sheet and the thawing of the permafrost landscape. These ongoing transformations are expected to be irreversible for centuries or even millennia.

Natural life in the Arctic is affected greatly. As the tundra warms, its soil becomes more hospitable to earthworms and larger plants, and the boreal forests spread to the north - yet this also makes the landscape more prone to wildfires, which take longer to recover from than in the other regions. Beavers also take advantage of this warming to colonize the Arctic rivers, and their dams contributing to methane emissions due to the increase in stagnant waters. The Arctic Ocean has experienced a large increase in the marine primary production as warmer waters and less shade from sea ice benefit phytoplankton. At the same time, it is already less alkaline than the rest of the global ocean, so ocean acidification caused by the increasing CO₂ concentrations is more severe, threatening some forms of zooplankton such as pteropods.

Methane clathrate (CH₄·5.75H₂O) or (4CH₄·23H₂O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice. Originally thought to occur only in the outer regions of the Solar System, where temperatures are low and water ice is common, significant deposits of methane clathrate have been found under sediments on the ocean floors of the Earth (around 1100 m below the sea level). Methane hydrate is formed when hydrogen-bonded water and methane gas come into contact at high pressures and low temperatures in oceans.

Methane clathrates are common constituents of the shallow marine geosphere and they occur in deep sedimentary structures and form outcrops on the ocean floor. Methane hydrates are believed to form by the precipitation or crystallisation of methane migrating from deep along geological faults. Precipitation occurs when the methane comes in contact with water within the sea bed subject to temperature and pressure. In 2008, research on Antarctic Vostok Station and EPICA Dome C ice cores revealed that methane clathrates were also present in deep Antarctic ice cores and record a history of atmospheric methane concentrations, dating to 800,000 years ago. The ice-core methane clathrate record is a primary source of data for global warming research, along with oxygen and carbon dioxide.

Throughout Earth's climate history (Paleoclimate) its climate has fluctuated between two primary states: greenhouse and icehouse Earth. Both climate states last for millions of years and should not be confused with the much smaller glacial and interglacial periods, which occur as alternating phases within an icehouse period (known as an ice age) and tend to last less than one million years. There are five known icehouse periods in Earth's climate history, namely the Huronian, Cryogenian, Andean-Saharan (also known as Early Paleozoic), Late Paleozoic and Late Cenozoic glaciations.

The main factors involved in changes of the paleoclimate are believed to be the concentration of atmospheric greenhouse gases such as carbon dioxide (CO₂) and less importantly methane (CH₄), changes in Earth's orbit, long-term changes in the solar constant, and oceanic and orogenic changes from tectonic plate dynamics. Greenhouse and icehouse periods have played key roles in the evolution of life on Earth by directly and indirectly forcing biotic adaptation and turnover at various spatial scales across time.

Although oxygen is the most abundant element in Earth's crust, due to its high reactivity it mostly exists in compound (oxide) forms such as water, carbon dioxide, iron oxides and silicates. Before photosynthesis evolved, Earth's atmosphere had little free diatomic elemental oxygen (O₂). Small quantities of oxygen were released by geological and biological processes, but did not build up in the reducing atmosphere due to reactions with then-abundant reducing gases such as atmospheric methane and hydrogen sulfide and surface reductants such as ferrous iron.

Oxygen began building up in the prebiotic atmosphere at approximately 2.45 Ga during the Neoarchean-Paleoproterozoic boundary, a paleogeological event known as the Great Oxygenation Event (GOE). The concentrations of O₂ attained were less than 10% of today's and probably fluctuated greatly. Around 500Mya a second event known as the Neoproterozoic Oxygenation Event lead to oxygen levels similar or even higher than the present. The increase in oxygen concentrations had wide-ranging and significant impacts on Earth's geochemistry and biosphere. Detailed connections between oxygen and evolution remain elusive.

Early Earth, also known as Proto-Earth, is loosely defined as Earth in the first one billion years — or gigayear (10 y or Ga) — of its geological history, from its initial formation in the young Solar System at about 4.55 billion years ago (Gya), to the end of the Eoarchean era at approximately 3.5 Gya. On the geologic time scale, this comprises all of the Hadean eon and approximately one-third of the Archean eon, starting with the formation of the Earth about 4.6 Gya, and ended at the start of the Paleoarchean era 3.6 Gya.

This period of Earth's history involved the planet's formation from the solar nebula via a process known as accretion, and transition of the Earth's atmosphere from a hydrogen/helium-predominant primary atmosphere collected from the protoplanetary disk to a reductant secondary atmosphere rich in nitrogen, methane and CO₂. This time period included intense impact events as the young Proto-Earth, a protoplanet of about 0.63 Earth masses, began clearing the neighborhood, including the early Moon-forming collision with Theia — a Mars-sized co-orbital planet likely perturbed from the L₄ Lagrange point — around 0.032 Ga after formation of the Solar System, which resulted in a series of magma oceans and episodes of core formation. After formation of the core, meteorites or comets from the Outer Solar System might have delivered water and other volatile compounds to the Earth's mantle, crust and ancient atmosphere in an intense "late veneer" bombardment. As the Earth's planetary surface eventually cooled and formed a stable but evolving crust during the end-Hadean, most of the water vapor condensed out of the atmosphere and precipitated into a superocean that covered nearly all of the Earth's surface, transforming the initially lava planet Earth of the Hadean into an ocean planet at the early Archean, where the earliest known life forms appeared soon afterwards.

Noctilucent clouds (NLCs), or night shining clouds, are tenuous cloud-like phenomena in the upper atmosphere. When viewed from space, they are called polar mesospheric clouds (PMCs), detectable as a diffuse scattering layer of water ice crystals near the summer polar mesopause. They consist of ice crystals and from the ground are only visible during astronomical twilight. Noctilucent roughly means "night shining" in Latin. They are most often observed during the summer months from latitudes between ±50° and ±70°. Too faint to be seen in daylight, they are visible only when the observer and the lower layers of the atmosphere are in Earth's shadow while these very high clouds are still in sunlight. Recent studies suggest that increased atmospheric methane emissions produce additional water vapor through chemical reactions once the methane molecules reach the mesosphere – creating, or reinforcing existing, noctilucent clouds.