Insulator (electrical) in the context of Thermosetting polymer

In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to the energy difference (often expressed in electronvolts) between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. It is the energy required to promote an electron from the valence band to the conduction band. The resulting conduction-band electron (and the electron hole in the valence band) are free to move within the crystal lattice and serve as charge carriers to conduct electric current. It is closely related to the HOMO/LUMO gap in chemistry. If the valence band is completely full and the conduction band is completely empty, then electrons cannot move within the solid because there are no available states. If the electrons are not free to move within the crystal lattice, then there is no generated current due to no net charge carrier mobility. However, if some electrons transfer from the valence band (mostly full) to the conduction band (mostly empty), then current can flow (see carrier generation and recombination). Therefore, the band gap is a major factor determining the electrical conductivity of a solid. Substances having large band gaps (also called "wide" band gaps) are generally insulators, those with small band gaps (also called "narrow" band gaps) are semiconductors, and conductors either have very small band gaps or none, because the valence and conduction bands overlap to form a continuous band.

It is possible to produce laser induced insulator-metal transitions which have already been experimentally observed in some condensed matter systems, like thin films of C₆₀, doped manganites, or in vanadium sesquioxide V₂O₃. These are special cases of the more general metal-to-nonmetal transitions phenomena which were intensively studied in the last decades. A one-dimensional analytic model of laser induced distortion of band structure was presented for a spatially periodic (cosine) potential. This problem is periodic both in space and time and can be solved analytically using the Kramers-Henneberger co-moving frame. The solutions can be given with the help of the Mathieu functions.

The breakdown voltage of an insulator is the minimum voltage that causes a portion of an insulator to experience electrical breakdown and become electrically conductive.

For diodes, the breakdown voltage is the minimum reverse voltage that makes the diode conduct appreciably in reverse. Some devices (such as TRIACs) also have a forward breakdown voltage.

Conductor gallop is the high-amplitude, low-frequency oscillation of overhead power lines due to wind. The movement of the wires occurs most commonly in the vertical plane, although horizontal or rotational motion is also possible. The natural frequency mode tends to be around 1 Hz, leading the often graceful periodic motion to also be known as conductor dancing. The oscillations can exhibit amplitudes in excess of a metre, and the displacement is sometimes sufficient for the phase conductors to infringe operating clearances (coming too close to other objects), and causing flashover. The forceful motion also adds significantly to the loading stress on insulators and electricity pylons, raising the risk of mechanical failure of either.

The mechanisms that initiate gallop are not always clear, though it is thought to be often caused by asymmetric conductor aerodynamics due to ice build up on one side of a wire. The crescent of encrusted ice approximates an aerofoil, altering the normally round profile of the wire and increasing the tendency to oscillate.

A superhard material is a material with a hardness value exceeding 40 gigapascals (GPa) when measured by the Vickers hardness test. They are virtually incompressible solids with high electron density and high bond covalency. As a result of their unique properties, these materials are of great interest in many industrial areas including, but not limited to, abrasives, polishing and cutting tools, disc brakes, and wear-resistant and protective coatings.

Diamond is the hardest known material to date, with a Vickers hardness in the range of 70–150 GPa. Diamond demonstrates both high thermal conductivity and electrically insulating properties, and much attention has been put into finding practical applications of this material. However, diamond has several limitations for mass industrial application, including its high cost and oxidation at temperatures above 800 °C. In addition, diamond dissolves in iron and forms iron carbides at high temperatures and therefore is inefficient in cutting ferrous materials including steel. Therefore, recent research of superhard materials has been focusing on compounds which would be thermally and chemically more stable than pure diamond.

In electrical engineering, treeing is an electrical pre-breakdown phenomenon in solid insulation. It is a damaging process due to partial discharges and progresses through the stressed dielectric insulation, in a path resembling the branches of a tree. Treeing of solid high-voltage cable insulation is a common breakdown mechanism and source of electrical faults in underground power cables.