Clay mineral in the context of Jurassic


Clay mineral in the context of Jurassic

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⭐ Core Definition: Clay mineral

Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2Si2O5(OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.

Clay minerals form in the presence of water and have been important to life, and many theories of abiogenesis involve them. They are important constituents of soils, and have been useful to humans since ancient times in agriculture and manufacturing.

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Clay mineral in the context of Clay

Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide.

Clays develop plasticity when wet but can be hardened through firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been dated to around 14,000 BCE, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essential part of its load-bearing structure. In agriculture, clay content is a major factor in determining land arability. Clay soils are generally less suitable for crops due to poor natural drainage; however, clay soils are more fertile, due to higher cation-exchange capacity.

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Clay mineral in the context of Siltstone

Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.

Although its permeability and porosity is relatively low, siltstone is sometimes a tight gas reservoir rock, an unconventional reservoir for methane gas that requires hydraulic fracturing for economic gas production.

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Clay mineral in the context of Kaolinite

Kaolinite (/ˈk.ələˌnt, -lɪ-/ KAY-ə-lə-nyte, -⁠lih-; also called kaolin) is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one "tetrahedral" sheet of silicate tetrahedra (SiO4) linked to one "octahedral" sheet of aluminate octahedrons (AlO2(OH)4) through oxygen atoms on one side, and another such sheet through hydrogen bonds on the other side.

Kaolinite is a soft, earthy, usually white, mineral (dioctahedral phyllosilicate clay), produced by the chemical weathering of aluminium silicate minerals like feldspar. It has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g).

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Clay mineral in the context of Cementation (geology)

Cementation is a process where minerals bond grains of sediment together by growing around them. This means precipitation of ions carried in groundwater to form new crystalline material between sedimentary grains. The new pore-filling minerals form "bridges" between original sediment grains, thereby binding them together. In this way, sand becomes sandstone, and gravel becomes conglomerate or breccia.

Cementation occurs as part of the diagenesis or lithification of sediments and occurs primarily below the water table regardless of sedimentary grain sizes present. Large volumes of pore water must pass through sediment pores for new mineral cements to crystallize and so millions of years are generally required to complete the cementation process. Common mineral cements include calcite, quartz, and silica phases like cristobalite, iron oxides, and clay minerals; other mineral cements also occur.

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Clay mineral in the context of Shale

Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g., kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.

The term shale is sometimes applied more broadly, as essentially a synonym for mudrock, rather than in the narrower sense of clay-rich fissile mudrock.

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Clay mineral in the context of Diatomaceous earth

Diatomaceous earth (/ˌd.ətəˈmʃəs/ DY-ə-tə-MAY-shəs), also known as diatomite (/dˈætəmt/ dy-AT-ə-myte), celite, or kieselguhr, is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 mm to less than 1 μm, but typically 10 to 200 μm. Depending on the granularity, this powder can have an abrasive feel, similar to pumice powder, and has a low density as a result of its high porosity. The typical chemical composition of oven-dried diatomaceous earth is 80–90% silica, with 2–4% alumina (attributed mostly to clay minerals), and 0.5–2% iron oxide.

Diatomaceous earth consists of the fossilized remains of diatoms, a type of hard-shelled microalgae, that have accumulated over millions of years. It is used as a filtration aid, mild abrasive in products including metal polishes and toothpaste, mechanical insecticide, absorbent for liquids, matting agent for coatings, reinforcing filler in plastics and rubber, anti-block in plastic films, porous support for chemical catalysts, cat litter, activator in coagulation studies, a stabilizing component of dynamite, a thermal insulator, and a soil for potted plants and trees as in the art of bonsai. It is also used in gas chromatography packed columns made with glass or metal as stationary phase.

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Clay mineral in the context of Tonstein

Tonstein (from the German "Ton", meaning clay, plus "Stein", meaning stone) is a hard, compact sedimentary rock that is composed mainly of kaolinite or, less commonly, other clay minerals such as montmorillonite and illite. The clays often are cemented by iron oxide minerals, carbonaceous matter, or chlorite. Tonsteins form from volcanic ash deposited in swamps.Tonsteins occur as distinctive, thin, and laterally extensive layers in coal seams throughout the world. They are often used as key beds to correlate the strata in which they are found. The regional persistence of tonsteins and relict phenocrysts indicate that they formed as the result of the diagenetic alteration of volcanic ash falls in an acidic (low pH) and low-salinity environment, consistent with a freshwater swamp. In contrast, the alteration of a volcanic ashfall deposit in a marine environment typically produces a bentonite layer.

The induration of tonsteins is in contrast to kaolin claystones that can be mined for kaolin clay, such as the ball clays found at Bovey Tracey which formed by the erosion of a nearby kaolinised granite. These deposits are generally softer, white, and plastic.

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Clay mineral in the context of Talc

Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant. It is an ingredient in ceramics, paints, and roofing material. It is a main ingredient in many cosmetics. It occurs as foliated to fibrous masses, and in an exceptionally rare crystal form. It has a perfect basal cleavage and an uneven flat fracture, and it is foliated with a two-dimensional platy form.

The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 1 as the hardness of talc, the softest mineral. When scraped on a streak plate, talc produces a white streak, though this indicator is of little importance, because most silicate minerals produce a white streak. Talc is translucent to opaque, with colors ranging from whitish grey to green with a vitreous and pearly luster. Talc is not soluble in water, and is slightly soluble in dilute mineral acids.

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Clay mineral in the context of Salt glacier

A salt glacier (or namakier) is a rare flow of salt that is created when a rising diapir in a salt dome breaches the surface of Earth. The name ‘salt glacier’ was given to this phenomenon due to the similarity of movement when compared with ice glaciers. The causes of these formations is primarily due to salt's unique properties and its surrounding geologic environment. A rising body of salt is referred to as a diapir; which rises to the surface and feeds the salt glacier. Salt structures are usually composed of halite, anhydrite, gypsum and clay minerals. Clays may be brought up with the salt, turning it dark. These salt flows are rare on Earth. In a more recent discovery, scientists have found that they also occur on Mars, but are composed of sulfates. A paper published in November 2023 suggests that salt glaciers composed of halite might also be present on Mercury.

The salt glaciers of the Zagros Mountains in Iran are halite whereas the salt glacier of Lüneburg Kalkberg, Germany is composed of gypsum and carbonate minerals.

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Clay mineral in the context of Pelagic red clay

Pelagic red clay, also known as simply red clay, brown clay or pelagic clay, is a type of pelagic sediment.

Pelagic clay accumulates in the deepest and most remote areas of the ocean. It covers 38% of the ocean floor and accumulates more slowly than any other sediment type, at only 0.1–0.5 cm/1000 yr. Containing less than 30% biogenic material, it consists of sediment that remains after the dissolution of both calcareous and siliceous biogenic particles while they settled through the water column. These sediments consist of eolian quartz, clay minerals, volcanic ash, subordinate residue of siliceous microfossils, and authigenic minerals such as zeolites, limonite and manganese oxides. The bulk of red clay consists of eolian dust. Accessory constituents found in red clay include meteorite dust, fish bones and teeth, whale ear bones, and manganese micro-nodules.

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Clay mineral in the context of Montmorillonite

Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to resolve individual clay particles. Members of this group include saponite, nontronite, beidellite, and hectorite.

Montmorillonite is a subclass of smectite, a 2:1 phyllosilicate mineral characterized as having greater than 50% octahedral charge; its cation exchange capacity is due to isomorphous substitution of Mg for Al in the central alumina plane. The substitution of lower valence cations in such instances leaves the nearby oxygen atoms with a net negative charge that can attract cations. In contrast, beidellite is smectite with greater than 50% tetrahedral charge originating from isomorphous substitution of Al for Si in the silica sheet.

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Clay mineral in the context of Expansive clay

Expansive clay, also called expansive soil, is a clay soil prone to large volume changes (swelling and shrinking) directly related to changes in water content. Soils with a high content of expansive minerals can form deep cracks in drier seasons or years; such soils are called vertisols. Soils with smectite clay minerals, including montmorillonite, kaolinite, and illite group minerals, such as montmorillonite-containing bentonite, have the most dramatic shrink–swell capacity.

The mineral make-up of this type of soil is responsible for the moisture retaining capabilities. All clays consist of mineral sheets packaged into layers, and can be classified as either 1:1 or 2:1. These ratios refer to the proportion of tetrahedral sheets to octahedral sheets. Octahedral sheets are sandwiched between two tetrahedral sheets in 2:1 clays, while 1:1 clays have sheets in matched pairs. Expansive clays have an expanding crystal lattice in a 2:1 ratio; however, there are 2:1 non-expansive clays.

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Clay mineral in the context of Iddingsite

Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-definite crystal structure caused it to be de-listed as an official mineral by the IMA; thus, it is properly referred to as a rock.

Iddingsite forms from the weathering of basalt in the presence of liquid water and can be described as a phenocryst, i.e. it has macroscopically visible crystals in a fine-grained groundmass of a porphyritic rock. It is a pseudomorph that has a composition that is constantly transforming from the original olivine, passing through many stages of structural and chemical change to create a fully altered iddingsite.

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