Zircon in the context of Rare-earth elements

The earliest known life forms on Earth may be as old as 4.1 billion years (or Ga) according to biologically fractionated graphite inside a single zircon grain in the Jack Hills range of Australia. The earliest evidence of life found in a stratigraphic unit, not just a single mineral grain, is the 3.7 Ga metasedimentary rocks containing graphite from the Isua Supracrustal Belt in Greenland. The earliest direct known life on Earth are stromatolite fossils which have been found in 3.480-billion-year-old geyserite uncovered in the Dresser Formation of the Pilbara Craton of Western Australia. Various microfossils of microorganisms have been found in 3.4 Ga rocks, including 3.465-billion-year-old Apex chert rocks from the same Australian craton region, and in 3.42 Ga hydrothermal vent precipitates from Barberton, South Africa. Much later in the geologic record, likely starting in 1.73 Ga, preserved molecular compounds of biologic origin are indicative of aerobic life. Therefore, the earliest time for the origin of life on Earth is at least 3.5 billion years ago and possibly as early as 4.1 billion years ago — not long after the oceans formed 4.5 billion years ago and after the formation of the Earth 4.54 billion years ago.

The age of Earth is estimated to be 4.54 ± 0.05 billion years. This age represents the final stages of Earth's accretion and planetary differentiation. Age estimates are based on evidence from radiometric age-dating of meteoritic material—consistent with the radiometric ages of the oldest-known terrestrial material and lunar samples—and astrophysical accretion models consistent with observations of planet formation in protoplanetary disks.

Following the development of radiometric dating in the early 20th century, measurements of lead in uranium-rich minerals showed that some were in excess of a billion years old. The oldest such minerals analyzed to date—small crystals of zircon from the Jack Hills of Western Australia—are at least 4.404 billion years old. Calcium–aluminium-rich inclusions—the oldest known solid constituents within meteorites that are formed within the Solar System—are 4.5673 ± 0.00016 billion years old giving a lower limit for the age of the Solar System.

The Jack Hills are a range of hills in Mid West Western Australia. They are best known as the source of the oldest material of terrestrial origin found to date: Hadean zircons that formed around 4.404 billion years ago. These zircons have enabled deeper research into the conditions on Earth in the Hadean eon. Potentially biogenic carbon isotope ratios have been identified for graphite embedded within a 4.1 billion-year-old zircon from the site.

Hadean zircon is the oldest-surviving crustal material from the Earth's earliest geological time period, the Hadean eon, about 4 billion years ago. Zircon is a mineral that is commonly used for radiometric dating because it is highly resistant to chemical changes and appears in the form of small crystals or grains in most igneous and metamorphic host rocks.

Hadean zircon has very low abundance around the globe because of recycling of material by plate tectonics. When the rock at the surface is buried deep in the Earth it is heated and can recrystallise or melt. In the Jack Hills, Australia, scientists obtained a relatively comprehensive record of Hadean zircon crystals in contrast to other locations. The Jack Hills zircons are found in metamorphosed sediments that were initially deposited around 3 billion years ago, or during the Archean Eon. However, the zircon crystals there are older than the rocks that contain them. Many investigations have been carried out to find the absolute age and properties of zircon, for example the isotope ratios, mineral inclusions, and geochemistry of zircon. The characteristics of Hadean zircons show early Earth history and the mechanism of Earth's processes in the past. Based on the properties of these zircon crystals, many different geological models were proposed.

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al₂O₃) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name sapphire is derived from the Latin word sapphirus, itself from the Greek word sappheiros (σάπφειρος), which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on the locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third-hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs. It occurs in association with ruby, zircon, biotite, muscovite, calcite, dravite and quartz.

Zirconium is a chemical element; it has symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyish-white color that closely resembles hafnium and, to a lesser extent, titanium. It is solid at room temperature, ductile, malleable and corrosion-resistant. The name zirconium is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian zargun (zircon; zar-gun, "gold-like" or "as gold"). Besides zircon, zirconium occurs in over 140 other minerals, including baddeleyite and eudialyte; most zirconium is produced as a byproduct of minerals mined for titanium and tin.

Zirconium forms a variety of inorganic compounds, such as zirconium dioxide, and organometallic compounds, such as zirconocene dichloride. Five isotopes occur naturally, four of which are stable. The metal and its alloys are mainly used as a refractory and opacifier; zirconium alloys are used to clad nuclear fuel rods due to their low neutron absorption and strong resistance to corrosion, and in space vehicles and turbine blades where high heat resistance is necessary. Zirconium also finds uses in flashbulbs, biomedical applications such as dental implants and prosthetics, deodorant, and water purification systems.

Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routine precisions in the 0.1–1 percent range.

The method is usually applied to zircon. This mineral incorporates uranium and thorium atoms into its crystal structure, but strongly rejects lead when forming. As a result, newly-formed zircon crystals will contain no lead, meaning that any lead found in the mineral is radiogenic. Since the exact rate at which uranium decays into lead is known, the current ratio of lead to uranium in a sample of the mineral can be used to reliably determine its age.

Zirconium silicate, also zirconium orthosilicate, ZrSiO₄, is a chemical compound, a silicate of zirconium. It occurs in nature as zircon, a silicate mineral. Powdered zirconium silicate is also known as zircon flour.

Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922 by Dirk Coster and George de Hevesy. Hafnium is named after Hafnia, the Latin name for Copenhagen, where it was discovered. The element is obtained only by separation from zirconium, with most of the world's hafnium production coming from processes that also produce zirconium. These processes make use of heavy mineral sands ore deposits, which include the minerals zircon, rutile, and ilmenite, among others.

Hafnium is most often used in alloys with nickel, and was used in larger quantities to produce the control rods used in nuclear reactors. Hafnium's large neutron capture cross section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors. It is ductile, and is also used in filaments and electrodes. Some semiconductor fabrication processes use its oxide for integrated circuits at 45 nanometres (1.8×10 in) and smaller, and superalloys used for special applications can contain hafnium in combination with niobium, titanium, or tungsten.

Jargoon or jargon (occasionally in old writings jargounce and jacounce) is a name applied by gemologists to zircons that are of sufficient quality to be cut as gemstones, but not the red color that characterizes the hyacinth or jacinth. The word is related to Persian zargun (zircon; zar-gun, "gold-like" or "as gold").

Some of the finest jargoons are green, others brown and yellow, while some are colorless. The colorless jargoon may be obtained by heating certain colored stones. When zircon is heated it sometimes changes color, or loses it, and at the same time usually increases in density and brilliancy. The so-called Matura diamonds, formerly sent from Matara (or Matura) in Sri Lanka, were decolorized zircons.

Jacinth (/ˈdʒæsɪnθ/, /ˈdʒeɪsɪnθ/) or hyacinth (/ˈhaɪ.əsɪnθ/) is a yellow-red to red-brown variety of zircon used as a gemstone.

In Exodus 28:19, one of the precious stones set into the hoshen (the breastplate worn by the High Priest of Israel) is called, in Hebrew, leshem, which has often been translated into English as "jacinth". The modern identification of leshem with jacinth seems to have been popularized by Martin Luther.

Supracrustal rocks (supra (Latin for "above")) are rocks that were deposited on the existing basement rocks of the crust, hence the name. They may be further metamorphosed from both sedimentary and volcanic rocks.

The oldest minerals on Earth are detrital zircon grains from the Yilgarn craton in the Mesoarchaean (3.2–2.8 Ga) Jack Hills, Western Australia dated to up to 4.4 Ga, meaning that granitic continental crust and probably supracrustal rocks formed during the Hadean, within 200 million years of Earth accretion. Most Hadean rocks were probably recycled into the mantle before the end of the eon, however, and such pre-4.0 Ga mineral inclusions, the only traces from the earliest rock formation on Earth, are rare.

Zirconium dioxide (ZrO
₂), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant.

Sand mining is the extraction of sand, mainly through an open pit (or sand pit) but sometimes mined from beaches and inland dunes or dredged from ocean and river beds. Sand is often used in manufacturing, for example as an abrasive or in concrete. It is also used on icy and snowy roads usually mixed with salt, to lower the melting point temperature, on the road surface. Sand can replace eroded coastline. Some uses require higher purity than others; for example sand used in concrete must be free of seashell fragments.

Sand mining presents opportunities to extract rutile, ilmenite, and zircon, which contain the industrially useful elements titanium and zirconium. Besides these minerals, beach sand may also contain garnet, leucoxene, sillimanite, and monazite.

The Grande Côte is a stretch of coastline in Senegal, running north from the Cap-Vert peninsula of Dakar to the border with Mauritania at St-Louis.

A sandy beach runs along the entire coast, which, unlike the Petite Côte, has few settlements – Kayar and Mboro being exceptions. The last stage of the Dakar Rally used to run along the beach. The coastline is also relatively rich in heavy minerals, with significant amounts of zircon having been discovered in the 2000s.

Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe₃AlSi₃O₁₀(OH)₂. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines. There are contact twins with composition surface {001} and twin axis {310}.

Annite was first described in 1868 for the first noted occurrence in Cape Ann, Rockport, Essex County, Massachusetts, US. It also occurs on Pikes Peak, El Paso County, Colorado. It occurs in igneous and metamorphic rocks that are deficient in magnesium and is associated with fluorite and zircon in the type locality.

Cubic zirconia (CZ) is the cubic crystalline form of zirconium dioxide (ZrO₂). The synthesized material is hard and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirconium silicate (ZrSiO₄). It is sometimes erroneously called cubic zirconium.

Because of its low cost, durability, and close visual likeness to diamond, synthetic cubic zirconia has remained the most gemologically and economically important competitor for diamonds since commercial production began in 1976. Its main competitor as a synthetic gemstone is a more recently cultivated material, synthetic moissanite.