An isotopic signature (also isotopic fingerprint) is a ratio of non-radiogenic stable isotopes, stable radiogenic isotopes, or unstable radioactive isotopes of particular elements in an investigated material. The ratios of isotopes in a sample material are measured by isotope-ratio mass spectrometry against an isotopic reference material. This process is called isotope analysis.
The Jack Hills are a range of hills in Mid West Western Australia. They are best known as the source of the oldest material of terrestrial origin found to date: Hadean zircons that formed around 4.404 billion years ago. These zircons have enabled deeper research into the conditions on Earth in the Hadean eon. Potentially biogenic carbon isotope ratios have been identified for graphite embedded within a 4.1 billion-year-old zircon from the site.
The Toarcian extinction event, also called the Pliensbachian-Toarcian extinction event, the Early Toarcian mass extinction, the Early Toarcian palaeoenvironmental crisis, or the Jenkyns Event, was an extinction event that occurred during the early part of the Toarcian age, approximately 183 million years ago, during the Early Jurassic. The extinction event had two main pulses, the first being the Pliensbachian-Toarcian boundary event (PTo-E). The second, larger pulse, the Toarcian Oceanic Anoxic Event (TOAE), was a global oceanic anoxic event, representing possibly the most extreme case of widespread ocean deoxygenation in the entire Phanerozoic eon. In addition to the PTo-E and TOAE, there were multiple other, smaller extinction pulses within this span of time.
Occurring during the supergreenhouse climate of the Early Toarcian Thermal Maximum (ETTM), the Early Toarcian extinction was associated with large igneous province volcanism, which elevated global temperatures, acidified the oceans, and prompted the development of anoxia, leading to severe biodiversity loss. The biogeochemical crisis is documented by a high amplitude negative carbon isotope excursions, as well as black shale deposition.