Zircon in the context of "Jack Hills"

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⭐ Core Definition: Zircon

Zircon (/ˈzɜːrkɒn, -kən/) is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.

The name derives from the Persian zargun, meaning "gold-hued". This word is changed into "jargoon", a term applied to light-colored zircons. The English word "zircon" is derived from Zirkon, which is the German adaptation of this word. Yellow, orange, and red zircon is also known as "hyacinth", from the flower hyacinthus, whose name is of Ancient Greek origin.

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👉 Zircon in the context of Jack Hills

The Jack Hills are a range of hills in Mid West Western Australia. They are best known as the source of the oldest material of terrestrial origin found to date: Hadean zircons that formed around 4.404 billion years ago. These zircons have enabled deeper research into the conditions on Earth in the Hadean eon. Potentially biogenic carbon isotope ratios have been identified for graphite embedded within a 4.1 billion-year-old zircon from the site.

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In this Dossier

Zircon in the context of Earliest known life forms

The earliest known life forms on Earth may be as old as 4.1 billion years (or Ga) according to biologically fractionated graphite inside a single zircon grain in the Jack Hills range of Australia. The earliest evidence of life found in a stratigraphic unit, not just a single mineral grain, is the 3.7 Ga metasedimentary rocks containing graphite from the Isua Supracrustal Belt in Greenland. The earliest direct known life on Earth are stromatolite fossils which have been found in 3.480-billion-year-old geyserite uncovered in the Dresser Formation of the Pilbara Craton of Western Australia. Various microfossils of microorganisms have been found in 3.4 Ga rocks, including 3.465-billion-year-old Apex chert rocks from the same Australian craton region, and in 3.42 Ga hydrothermal vent precipitates from Barberton, South Africa. Much later in the geologic record, likely starting in 1.73 Ga, preserved molecular compounds of biologic origin are indicative of aerobic life. Therefore, the earliest time for the origin of life on Earth is at least 3.5 billion years ago and possibly as early as 4.1 billion years ago — not long after the oceans formed 4.5 billion years ago and after the formation of the Earth 4.54 billion years ago.

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Zircon in the context of Age of Earth

The age of Earth is estimated to be 4.54 ± 0.05 billion years. This age represents the final stages of Earth's accretion and planetary differentiation. Age estimates are based on evidence from radiometric age-dating of meteoritic material—consistent with the radiometric ages of the oldest-known terrestrial material and lunar samples—and astrophysical accretion models consistent with observations of planet formation in protoplanetary disks.

Following the development of radiometric dating in the early 20th century, measurements of lead in uranium-rich minerals showed that some were in excess of a billion years old. The oldest such minerals analyzed to date—small crystals of zircon from the Jack Hills of Western Australia—are at least 4.404 billion years old. Calcium–aluminium-rich inclusions—the oldest known solid constituents within meteorites that are formed within the Solar System—are 4.5673 ± 0.00016 billion years old giving a lower limit for the age of the Solar System.

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Zircon in the context of Hadean zircon

Hadean zircon is the oldest-surviving crustal material from the Earth's earliest geological time period, the Hadean eon, about 4 billion years ago. Zircon is a mineral that is commonly used for radiometric dating because it is highly resistant to chemical changes and appears in the form of small crystals or grains in most igneous and metamorphic host rocks.

Hadean zircon has very low abundance around the globe because of recycling of material by plate tectonics. When the rock at the surface is buried deep in the Earth it is heated and can recrystallise or melt. In the Jack Hills, Australia, scientists obtained a relatively comprehensive record of Hadean zircon crystals in contrast to other locations. The Jack Hills zircons are found in metamorphosed sediments that were initially deposited around 3 billion years ago, or during the Archean Eon. However, the zircon crystals there are older than the rocks that contain them. Many investigations have been carried out to find the absolute age and properties of zircon, for example the isotope ratios, mineral inclusions, and geochemistry of zircon. The characteristics of Hadean zircons show early Earth history and the mechanism of Earth's processes in the past. Based on the properties of these zircon crystals, many different geological models were proposed.

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Zircon in the context of Sapphire

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al2O3) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name sapphire is derived from the Latin word sapphirus, itself from the Greek word sappheiros (σάπφειρος), which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on the locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third-hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs. It occurs in association with ruby, zircon, biotite, muscovite, calcite, dravite and quartz.

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Zircon in the context of Zirconium

Zirconium is a chemical element; it has symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyish-white color that closely resembles hafnium and, to a lesser extent, titanium. It is solid at room temperature, ductile, malleable and corrosion-resistant. The name zirconium is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian zargun (zircon; zar-gun, "gold-like" or "as gold"). Besides zircon, zirconium occurs in over 140 other minerals, including baddeleyite and eudialyte; most zirconium is produced as a byproduct of minerals mined for titanium and tin.

Zirconium forms a variety of inorganic compounds, such as zirconium dioxide, and organometallic compounds, such as zirconocene dichloride. Five isotopes occur naturally, four of which are stable. The metal and its alloys are mainly used as a refractory and opacifier; zirconium alloys are used to clad nuclear fuel rods due to their low neutron absorption and strong resistance to corrosion, and in space vehicles and turbine blades where high heat resistance is necessary. Zirconium also finds uses in flashbulbs, biomedical applications such as dental implants and prosthetics, deodorant, and water purification systems.

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Zircon in the context of Uranium–lead dating

Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routine precisions in the 0.1–1 percent range.

The method is usually applied to zircon. This mineral incorporates uranium and thorium atoms into its crystal structure, but strongly rejects lead when forming. As a result, newly-formed zircon crystals will contain no lead, meaning that any lead found in the mineral is radiogenic. Since the exact rate at which uranium decays into lead is known, the current ratio of lead to uranium in a sample of the mineral can be used to reliably determine its age.

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Zircon in the context of Zirconium(IV) silicate

Zirconium silicate, also zirconium orthosilicate, ZrSiO4, is a chemical compound, a silicate of zirconium. It occurs in nature as zircon, a silicate mineral. Powdered zirconium silicate is also known as zircon flour.

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