Thorium in the context of Actinide

Uranium is a chemical element; it has symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.

Many contemporary uses of uranium exploit its unique nuclear properties. Uranium is used in nuclear power plants and nuclear weapons because it is the only naturally occurring element with a fissile isotope – uranium-235 – present in non-trace amounts. However, because of the low abundance of uranium-235 in natural uranium (which is overwhelmingly uranium-238), uranium needs to undergo enrichment so that enough uranium-235 is present. Uranium-238 is fissionable by fast neutrons and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is studied for future industrial use in nuclear technology. Uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons; uranium-235, and to a lesser degree uranium-233, have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors and produces the fissile material for nuclear weapons. The primary civilian use for uranium harnesses the heat energy to produce electricity. Depleted uranium (U) is used in kinetic energy penetrators and armor plating.

Having a mean density of 3,346.4 kg/m, the Moon is a differentiated body, being composed of a geochemically distinct crust, mantle, and planetary core. This structure is believed to have resulted from the fractional crystallization of a magma ocean shortly after its formation about 4.5 billion years ago. The energy required to melt the outer portion of the Moon is commonly attributed to a giant impact event that is postulated to have formed the Earth-Moon system, and the subsequent reaccretion of material in Earth orbit. Crystallization of this magma ocean would have given rise to a mafic mantle and a plagioclase-rich crust.

Geochemical mapping from orbit implies that the crust of the Moon is largely anorthositic in composition, consistent with the magma ocean hypothesis. In terms of elements, the lunar crust is composed primarily of oxygen, silicon, magnesium, iron, calcium, and aluminium, but important minor and trace elements such as titanium, uranium, thorium, potassium, sulphur, manganese, chromium, and hydrogen are present as well. Based on geophysical techniques, the crust is estimated to be on average about 50 km thick.

Nuclear material refers to the elements uranium, plutonium, and thorium, in any form, according to the IAEA. This is differentiated further into "source material", consisting of natural and depleted uranium, and "special fissionable material", consisting of enriched uranium (U-235), uranium-233, and plutonium-239. Uranium ore concentrates are considered to be a "source material", although these are not subject to safeguards under the Nuclear Non-Proliferation Treaty.

According to the Nuclear Regulatory Commission (NRC), there are four different types of regulated nuclear materials: special nuclear material, source material, byproduct material and radium. Special nuclear materials have plutonium, uranium-233 or uranium with U or U that has a content found more than in nature. Source material is thorium or uranium that has a U content equal to or less than what is in nature. Byproduct material is radioactive material that is not source or special nuclear material. It can be an isotope produced by a nuclear reactor, the tailings and waste that is produced or extracted from uranium or thorium from an ore that processed mainly for its source material content. Byproduct material can also be discrete sources of radium-226 or discrete sources of accelerator-produced isotopes or naturally occurring isotopes that pose a threat greater or equal to a discrete source of radium-226. Radium is also a regulated nuclear material that is found in nature and produced by the radioactive decay of uranium. The half-life of radium is approximately 1,600 years.

Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO₂ but because of oxidation typically contains variable proportions of U₃O₈. Radioactive decay of the uranium causes the mineral to contain oxides of lead and trace amounts of helium. It may also contain thorium and rare-earth elements.

In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps (decay chain). For example, U decays to Th which decays to Pa which decays, and so on, to Pb (which is stable):

Thorium (₉₀Th) has seven naturally occurring isotopes but none are stable. One isotope, Th, is relatively stable, with a half-life of 1.40×10 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.

Thirty-one radioisotopes have been characterized, with the most stable being Th, Th with a half-life of 75,400 years, Th with a half-life of 7,916 years, and Th with a half-life of 1.91 years. All of the remaining radioactive isotopes have half-lives that are less than thirty days and the majority of these have half-lives that are less than ten minutes. One isotope, Th, has a nuclear isomer (or metastable state) with a remarkably low excitation energy, recently measured to be 8.355733554021(8) eV It has been proposed to perform laser spectroscopy of the Th nucleus and use the low-energy transition for the development of a nuclear clock of extremely high accuracy.

Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routine precisions in the 0.1–1 percent range.

The method is usually applied to zircon. This mineral incorporates uranium and thorium atoms into its crystal structure, but strongly rejects lead when forming. As a result, newly-formed zircon crystals will contain no lead, meaning that any lead found in the mineral is radiogenic. Since the exact rate at which uranium decays into lead is known, the current ratio of lead to uranium in a sample of the mineral can be used to reliably determine its age.

KREEP, an acronym built from the letters K (the atomic symbol for potassium), REE (rare-earth elements) and P (for phosphorus), is a geochemical component of some lunar impact breccia and basaltic rocks. Its most significant feature is somewhat enhanced concentration of a majority of so-called "incompatible" elements (those that are concentrated in the liquid phase during magma crystallization) and the heat-producing elements, namely radioactive uranium, thorium, and potassium (due to presence of the radioactive K).

Technetium is a chemical element; it has symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense of atomic number are both stable. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous fission product in uranium ore and thorium ore (the most common source), or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese and rhenium in group 7 of the periodic table, and its chemical properties are intermediate between those of both adjacent elements. The most common naturally occurring isotope is Tc, in traces only.

Many of technetium's properties had been predicted by Dmitri Mendeleev before it was discovered; Mendeleev noted a gap in his periodic table and gave the undiscovered element the provisional name ekamanganese (Em). In 1937, technetium became the first predominantly artificial element to be produced, hence its name (from the Greek technetos, 'artificial', + -ium).

Enrico Fermi (Italian: [enˈriːko ˈfermi]; 29 September 1901 – 28 November 1954) was an Italian and naturalized American physicist, renowned for being the creator of the world's first artificial nuclear reactor, the Chicago Pile-1, and a member of the Manhattan Project. He has been called the "architect of the nuclear age" and the "architect of the atomic bomb". He was one of very few physicists to excel in both theoretical and experimental physics. Fermi was awarded the 1938 Nobel Prize in Physics for his work on induced radioactivity by neutron bombardment and for the discovery of transuranium elements. With his colleagues, Fermi filed several patents related to the use of nuclear power, all of which were taken over by the US government. He made significant contributions to the development of statistical mechanics, quantum theory, and nuclear and particle physics.

Fermi's first major contribution involved the field of statistical mechanics. After Wolfgang Pauli formulated his exclusion principle in 1925, Fermi followed with a paper in which he applied the principle to an ideal gas, employing a statistical formulation now known as Fermi–Dirac statistics. Today, particles that obey the exclusion principle are called "fermions". Pauli later postulated the existence of an uncharged invisible particle emitted along with an electron during beta decay, to satisfy the law of conservation of energy. Fermi took up this idea, developing a model that incorporated the postulated particle, which he named the "neutrino". His theory, later referred to as Fermi's interaction and now called weak interaction, described one of the four fundamental interactions in nature. Through experiments inducing radioactivity with the recently discovered neutron, Fermi discovered that slow neutrons were more easily captured by atomic nuclei than fast ones, and he developed the Fermi age equation to describe this. After bombarding thorium and uranium with slow neutrons, he concluded that he had created new elements. Although he was awarded the Nobel Prize for this discovery, the new elements were later revealed to be nuclear fission products.

Thorium-232 (
Th) is the main naturally occurring isotope of thorium, with a relative abundance of 99.98%. It has a half-life of 14.0 billion years, which makes it the longest-lived isotope of thorium. It decays by alpha decay to radium-228; its decay chain terminates at stable lead-208.

Thorium-232 is a fertile material; it can capture a neutron to form thorium-233, which subsequently undergoes two successive beta decays to uranium-233, which is fissile. As such, it has been used in the thorium fuel cycle in nuclear reactors; various prototype thorium-fueled reactors have been designed. However, as of 2024, thorium fuel has not been widely adopted for commercial-scale nuclear power.

Actinium is a chemical element; it has symbol Ac and atomic number 89. It was discovered by Friedrich Oskar Giesel in 1902, who gave it the name emanium; the element got its name by being wrongly identified with a substance André-Louis Debierne found in 1899 and called actinium. The actinide series, a set of 15 elements between actinium and lawrencium in the periodic table, is named after actinium. Together with polonium, radium, and radon, actinium was one of the first non-primordial radioactive elements to be discovered.

A soft, silvery-white radioactive metal, actinium reacts rapidly with oxygen and moisture in air, forming a white coating of actinium oxide that prevents further oxidation. As with most lanthanides and many actinides, actinium assumes oxidation state +3 in nearly all its chemical compounds. Actinium is found only in traces in uranium and thorium ores as the isotope Ac, which decays with a half-life of 21.772 years, predominantly emitting beta and sometimes alpha particles, and Ac, which is beta active with a half-life of 6.15 hours. One tonne of natural uranium in ore contains about 0.2 milligrams of actinium-227, and one tonne of thorium contains about 5 nanograms of actinium-228. The close similarity of physical and chemical properties of actinium and lanthanum makes the separation of actinium from the ore impractical. Instead, the element is prepared, in milligram amounts, by the neutron irradiation of Ra in a nuclear reactor. Owing to its scarcity, high price, and radioactivity, actinium has no significant industrial use. Its current applications include a neutron source and an agent for radiation therapy.

A nuclear clock or nuclear optical clock is an atomic clock being developed that will use the energy of a nuclear isomeric transition as its reference frequency, instead of the atomic electron transition energy used by conventional atomic clocks. Such a clock is expected to be more accurate than the best current atomic clocks by a factor of about 10, with an achievable accuracy approaching the 10 level.

The only nuclear state suitable for the development of a nuclear clock using existing technology is thorium-229m, an isomer of thorium-229 and the lowest-energy nuclear isomer known. With an energy of 8.355733554021(8) eV, this corresponds to a frequency of 2020407384335±2 kHz, or wavelength of 148.382182883 nm, in the vacuum ultraviolet region, making it accessible to laser excitation.

Detrital zircon geochronology is a scientific technique for understanding the age and provenance of sedimentary deposits. To determine the age of zircons deposited within a specific sedimentary unit, mass spectrometry is used to measure the abundance of radioisotopes in the grains, most commonly the uranium–lead ratio. Zircon is a common accessory or trace mineral constituent of most granite and felsic igneous rocks. Due to its hardness, durability and chemical inertness, zircon persists in sedimentary deposits and is a common constituent of most sands. Zircons contain trace amounts of uranium and thorium and can be dated using several modern analytical techniques.

Detrital zircon geochronology has become increasingly popular in geological studies from the 2000s mainly due to the advancement in radiometric dating techniques. Detrital zircon age data can be used to constrain the maximum depositional age, determine provenance, and reconstruct the tectonic setting on a regional scale.