Stationary state in the context of Eigenvector

The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum.

If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists a unitary operator that acts non-trivially on a ground state and commutes with the Hamiltonian of the system.

In mathematics, in the theory of differential equations and dynamical systems, a particular stationary or quasistationary solution to a nonlinear system is called linearly unstable if the linearization of the equation at this solution has the form ${\displaystyle dr/dt=Ar}$, where r is the perturbation to the steady state, A is a linear operator whose spectrum contains eigenvalues with positive real part. If all the eigenvalues have negative real part, then the solution is called linearly stable. Other names for linear stability include exponential stability or stability in terms of first approximation. If there exists an eigenvalue with zero real part then the question about stability cannot be solved on the basis of the first approximation and we approach the so-called "centre and focus problem".

In computational physics and chemistry, the Hartree–Fock (HF) method is used for approximating the wave function and the energy of a quantum many-body system in a stationary state. It is named after Douglas Hartree and Vladimir Fock.

The Hartree–Fock method often assumes that the exact ${\displaystyle N}$-body wave function of the system can be approximated by a single Slater determinant (in the case where the particles are fermions) or by a single permanent (in the case of bosons) of ${\displaystyle N}$ spin-orbitals. By invoking the variational method, one can derive a set of ${\displaystyle N}$ coupled equations for the ${\displaystyle N}$ spin orbitals. A solution of these equations yields the Hartree–Fock wave function and energy of the system. Hartree–Fock approximation is an instance of mean-field theory, where neglecting higher-order fluctuations in order parameter allows interaction terms to be replaced with quadratic terms, obtaining exactly solvable Hamiltonians.