Nitrogen dioxide in the context of Vapour

Palladium is a chemical element; it has the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), which was thought to be a planet at the time, which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form together a group of elements referred to as the platinum group metals. They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.

More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust (hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances (nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applications, electrochemical sensors, electrosynthesis, groundwater treatment, and jewellery. Palladium is a key component of fuel cells, in which hydrogen and oxygen react to produce electricity, heat, and water.

Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances.

On planet Earth, the term 'volatiles' often refers to the volatile components of magma. In astrogeology volatiles are investigated in the crust or atmosphere of a planet or moon. Volatiles include hydrogen, nitrogen, oxygen, water, ammonia, methane, carbon dioxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, phosphine, halogens, noble gases and others.

Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.

These fuels are intended to substitute for more carbon intensive energy sources like gasoline and diesel in transportation and can help to contribute to decarbonization and reductions in pollution. Alternative fuel is also shown to reduce non-carbon emissions such as the release of nitric oxide and nitrogen dioxide, as well as sulfur dioxide and other harmful gases in the exhaust. This is especially important in industries such as mining, where toxic gases can accumulate more easily.

In atmospheric chemistry, NO_x is shorthand for nitric oxide (NO) and nitrogen dioxide (NO₂), the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.

NO_x gases are usually produced from the reaction between nitrogen and oxygen during combustion of fuels, such as hydrocarbons, in air; especially at high temperatures, such as in car engines. In areas of high motor vehicle traffic, such as in large cities, the nitrogen oxides emitted can be a significant source of air pollution. NO_x gases are also produced naturally by lightning.

In physics, a vapor (American English) or vapour (Commonwealth English; see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature, which means that the vapor can be condensed to a liquid by increasing the pressure on it without reducing the temperature of the vapor. A vapor is different from an aerosol. An aerosol is a suspension of tiny particles of liquid, solid, or both within a gas.

For example, water has a critical temperature of 647 K (374 °C; 705 °F), which is the highest temperature at which liquid water can exist at any pressure. In the atmosphere at ordinary temperatures gaseous water (known as water vapor) will condense into a liquid if its partial pressure is increased sufficiently.

Nitric acid is an inorganic compound with the formula HNO₃. It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% HNO₃, it is referred to as fuming nitric acid. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%.

Triatomic molecules are molecules composed of three atoms, of either the same or different chemical elements. Examples include H₂O, CO₂ (pictured), HCN, O₃ (ozone) and NO₂.

The oxygen cycle refers to the various movements of oxygen through the Earth's atmosphere (air), biosphere (flora and fauna), hydrosphere (water bodies and glaciers) and the lithosphere (the Earth's crust). The oxygen cycle demonstrates how free oxygen is made available in each of these regions, as well as how it is used. It is the biogeochemical cycle of oxygen atoms between different oxidation states in ions, oxides and molecules through redox reactions within and between the spheres/reservoirs of the planet Earth. The word oxygen in the literature typically refers to the most common oxygen allotrope, elemental/diatomic oxygen (O₂), as it is a common product or reactant of many biogeochemical redox reactions within the cycle. Processes within the oxygen cycle are considered to be biological or geological and are evaluated as either a source (O₂ production) or sink (O₂ consumption).

Oxygen is one of the most common elements on Earth and represents a large portion of each main reservoir. By far the largest reservoir of Earth's oxygen is within the silicate and oxide minerals of the crust and mantle (99.5% by weight). The Earth's atmosphere, hydrosphere, and biosphere together hold less than 0.05% of the Earth's total mass of oxygen. Besides O₂, additional oxygen atoms are present in various forms spread throughout the surface reservoirs in the molecules of biomass, H₂O, CO₂, HNO₃, NO, NO₂, CO, H₂O₂, O₃, SO₂, H₂SO₄, MgO, CaO, Al₂O₃, SiO₂, and PO3−4.

Household Air Pollution (HAP) is a significant form of indoor air pollution (IAP) mostly relating to cooking and heating methods used in developing countries and even smaller islands in the Caribbean. Since much of the cooking is carried out with biomass fuel, in the form of wood, charcoal, dung, and crop residue, in indoor environments that lack proper ventilation, millions of people, primarily women and children face serious health risks. In total, about three billion people in developing countries are affected by this problem. The World Health Organization (WHO) estimates that cooking-related pollution causes 3.8 million annual deaths. The Global Burden of Disease study estimated the number of deaths in 2021 at 3.1 million. The problem is closely related to energy poverty and cooking.

Smoke from traditional household solid fuel combustion commonly contains a range of incomplete combustion products, including both fine and coarse particulate matter (e.g., PM_2.5, PM₁₀), carbon monoxide (CO), nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and a variety of organic air pollutants.

Singlet oxygen, systematically named dioxygen(singlet) and dioxidene, is a gaseous inorganic chemical with two oxygen atoms in a quantum state where all electrons are spin-paired, known as a singlet state. It is the lowest excited state of the diatomic oxygen molecule, which in general has the chemical structure O=O and chemical formula O
₂. Singlet oxygen can be written more specifically as
[O
₂] or
O
₂. The more prevalent ground state of O
₂ is known as triplet oxygen. At room temperature, singlet oxygen will slowly decay into triplet oxygen, releasing the energy of excitation.

Singlet oxygen is a gas with physical properties differing only subtly from the ground state. In terms of its chemical reactivity, however, singlet oxygen is far more reactive toward organic compounds. It is responsible for the photodegradation of many materials but can be put to constructive use in preparative organic chemistry and photodynamic therapy. Trace amounts of singlet oxygen are found in the upper atmosphere and in polluted urban atmospheres where it contributes to the formation of lung-damaging nitrogen dioxide. It often appears and coexists confounded in environments that also generate ozone, such as pine forests with photodegradation of turpentine.

Aqua regia (/ˈreɪɡiə, ˈriːdʒiə/; from Latin, "regal water" or "royal water") is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a fuming liquid. Freshly prepared aqua regia is colorless, but it turns yellow, orange, or red within seconds from the formation of nitrosyl chloride and nitrogen dioxide. It was so named by alchemists because it can dissolve noble metals, such as gold and platinum, while leaving many other metals unaffected. It has been used to process or conceal gold into the modern era.
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Many gases have toxic properties, which are often assessed using the LC₅₀ (median lethal concentration) measure. In the United States, many of these gases have been assigned an NFPA 704 health rating of 4 (may be fatal) or 3 (may cause serious or permanent injury), and/or exposure limits (TLV, TWA/PEL, STEL, or REL) determined by the ACGIH professional association. Some, but by no means all, toxic gases are detectable by odor, which can serve as a warning. Among the best known toxic gases are carbon monoxide, chlorine, nitrogen dioxide and phosgene.

Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russian rocket engineers) as amyl, is the chemical compound N₂O₄. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide. Its molar mass is 92.011 g/mol.

Dinitrogen tetroxide is a powerful oxidizer that is hypergolic (spontaneously reacts) upon contact with various forms of hydrazine, which has made the pair a common bipropellant for rockets.

Red fuming nitric acid (RFNA) is a storable oxidizer used as a rocket propellant. It consists of nitric acid (HNO₃), dinitrogen tetroxide (N₂O₄) and a small amount of water. The color of red fuming nitric acid is due to the dinitrogen tetroxide, which breaks down partially to form nitrogen dioxide. The nitrogen dioxide dissolves until the liquid is saturated, and produces toxic fumes with a suffocating odor. RFNA increases the flammability of combustible materials and is highly exothermic when reacting with water.

Since nitrogen dioxide is a product of decomposition of nitric acid, its addition stabilizes nitric acid in accordance with Le Chatelier's principle. Addition of dinitrogen tetroxide also increases oxidizing power and lowers the freezing point.

Dinitrogen trioxide (also known as nitrous anhydride) is the inorganic compound with the formula N₂O₃. It is a nitrogen oxide. It forms upon mixing equal parts of nitric oxide and nitrogen dioxide and cooling the mixture below −21°C (−6°F):

Dinitrogen trioxide is only isolable at low temperatures (i.e., in the liquid and solid phases). In liquid and solid states, it has a deep blue color. At higher temperatures the equilibrium favors the constituent gases, with K_D = 193 kPa (25°C).

In chemistry, a photoinitiator is a molecule that creates reactive species (free radicals, cations or anions) when exposed to radiation (UV or visible). Synthetic photoinitiators are key components in photopolymers (for example, photo-curable coatings, adhesives and dental restoratives).

Some small molecules in the atmosphere can also act as photoinitiators by decomposing to give free radicals (in photochemical smog). For instance, nitrogen dioxide (NO₂) is produced in large quantities by gasoline-burning internal combustion engines. NO₂ in the troposphere gives smog its brown coloration and catalyzes production of toxic ground-level ozone (O₃). Molecular oxygen (O₂) also serves as a photoinitiator in the stratosphere, breaking down into atomic oxygen and combining with O₂ in order to form the ozone in the ozone layer.