Molecular diffusion in the context of Turbosphere


Molecular diffusion in the context of Turbosphere

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⭐ Core Definition: Molecular diffusion

Molecular diffusion is the motion of atoms, molecules, or other particles of a gas or liquid at temperatures above absolute zero. The rate of this movement is a function of temperature, viscosity of the fluid, size and density (or their product, mass) of the particles. This type of diffusion explains the net flux of molecules from a region of higher concentration to one of lower concentration.

Once the concentrations are equal the molecules continue to move, but since there is no concentration gradient the process of molecular diffusion has ceased and is instead governed by the process of self-diffusion, originating from the random motion of the molecules. The result of diffusion is a gradual mixing of material such that the distribution of molecules is uniform. Since the molecules are still in motion, but an equilibrium has been established, the result of molecular diffusion is called a "dynamic equilibrium". In a phase with uniform temperature, absent external net forces acting on the particles, the diffusion process will eventually result in complete mixing.

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Molecular diffusion in the context of Pulmonary alveolus

A pulmonary alveolus (pl.alveoli; from Latin alveolus 'little cavity'), also called an air sac or air space, is one of millions of hollow, distensible cup-shaped cavities in the lungs where pulmonary gas exchange takes place. Oxygen is exchanged for carbon dioxide at the blood–air barrier between the alveolar air and the pulmonary capillary. Alveoli make up the functional tissue of the mammalian lungs known as the lung parenchyma, which takes up 90 percent of the total lung volume.

Alveoli are first located in the respiratory bronchioles that mark the beginning of the respiratory zone. They are located sparsely in these bronchioles, line the walls of the alveolar ducts, and are more numerous in the blind-ended alveolar sacs. The acini are the basic units of respiration, with gas exchange taking place in all the alveoli present. The alveolar membrane is the gas exchange surface, surrounded by a network of capillaries. Oxygen is diffused across the membrane into the capillaries and carbon dioxide is released from the capillaries into the alveoli to be breathed out.

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Molecular diffusion in the context of Electrochemical gradient

An electrochemical gradient is a gradient of electrochemical potential, usually for an ion that can move across a membrane. The gradient consists of two parts:

  • The chemical gradient, or difference in solute concentration across a membrane.
  • The electrical gradient, or difference in charge across a membrane.

If there are unequal concentrations of an ion across a permeable membrane, the ion will move across the membrane from the area of higher concentration to the area of lower concentration through simple diffusion. Ions also carry an electric charge that forms an electric potential across a membrane. If there is an unequal distribution of charges across the membrane, then the difference in electric potential generates a force that drives ion diffusion until the charges are balanced on both sides of the membrane.

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Molecular diffusion in the context of Mass transfer

Mass transfer is the net movement of mass from one location (usually meaning stream, phase, fraction, or component) to another. Mass transfer occurs in many processes, such as absorption, evaporation, drying, precipitation, membrane filtration, and distillation. Mass transfer is used by different scientific disciplines for different processes and mechanisms. The phrase is commonly used in engineering for physical processes that involve diffusive and convective transport of chemical species within physical systems.

Some common examples of mass transfer processes are the evaporation of water from a pond to the atmosphere, the purification of blood in the kidneys and liver, and the distillation of alcohol. In industrial processes, mass transfer operations include separation of chemical components in distillation columns, absorbers such as scrubbers or stripping, adsorbers such as activated carbon beds, and liquid-liquid extraction. Mass transfer is often coupled to additional transport processes, for instance in industrial cooling towers. These towers couple heat transfer to mass transfer by allowing hot water to flow in contact with air. The water is cooled by expelling some of its content in the form of water vapour.

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Molecular diffusion in the context of Lipid signaling

Lipid signaling, broadly defined, refers to any biological cell signaling event involving a lipid messenger that binds a protein target, such as a receptor, kinase or phosphatase, which in turn mediate the effects of these lipids on specific cellular responses. Lipid signaling is thought to be qualitatively different from other classical signaling paradigms (such as monoamine neurotransmission) because lipids can freely diffuse through membranes (see osmosis). One consequence of this is that lipid messengers cannot be stored in vesicles prior to release and so are often biosynthesized "on demand" at their intended site of action. As such, many lipid signaling molecules cannot circulate freely in solution but, rather, exist bound to special carrier proteins in serum.

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Molecular diffusion in the context of Diffusion

Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, as in spinodal decomposition. Diffusion is a stochastic process due to the inherent randomness of the diffusing entity and can be used to model many real-life stochastic scenarios. Therefore, diffusion and the corresponding mathematical models are used in several fields beyond physics, such as statistics, probability theory, information theory, neural networks, finance, and marketing.

The concept of diffusion is widely used in many fields, including physics (particle diffusion), chemistry, biology, sociology, economics, statistics, data science, and finance (diffusion of people, ideas, data and price values). The central idea of diffusion, however, is common to all of these: a substance or collection undergoing diffusion spreads out from a point or location at which there is a higher concentration of that substance or collection.

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Molecular diffusion in the context of Pressure solution

In structural geology and diagenesis, pressure solution or pressure dissolution is a deformation mechanism that involves the dissolution of minerals at grain-to-grain contacts into an aqueous pore fluid in areas of relatively high stress and either deposition in regions of relatively low stress within the same rock or their complete removal from the rock within the fluid. It is an example of diffusive mass transfer.

The detailed kinetics of the process was reviewed by Rutter (1976), and since then such kinetics has been used inmany applications in earth sciences.

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Molecular diffusion in the context of Turing patterns

The Turing pattern is a concept introduced by English mathematician Alan Turing in a 1952 paper titled "The Chemical Basis of Morphogenesis", which describes how patterns in nature, such as stripes and spots, can arise naturally and autonomously from a homogeneous, uniform state. The pattern arises due to Turing instability, which in turn arises due to the interplay between differential diffusion of chemical species and chemical reaction. The instability mechanism is surprising because a pure diffusion, such as molecular diffusion, would be expected to have a stabilizing influence on the system (i.e., complete mixing).

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Molecular diffusion in the context of Brownian dynamics

In physics, Brownian dynamics is a mathematical approach for describing the dynamics of molecular systems in the diffusive regime. It is a simplified version of Langevin dynamics and corresponds to the limit where no average acceleration takes place. This approximation is also known as overdamped Langevin dynamics or as Langevin dynamics without inertia.

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Molecular diffusion in the context of Eddy diffusion

In fluid dynamics, eddy diffusion, eddy dispersion, or turbulent diffusion is a process by which fluid substances mix together due to eddy motion. These eddies can vary widely in size, from subtropical ocean gyres down to the small Kolmogorov microscales, and occur as a result of turbulence (or turbulent flow). The theory of eddy diffusion was first developed by Sir Geoffrey Ingram Taylor.

In laminar flows, material properties (salt, heat, humidity, aerosols etc.) are mixed by random motion of individual molecules. By a purely probabilistic argument, the net flux of molecules from high concentration area to low concentration area is higher than the flux in the opposite direction. This down-gradient flux equilibrates the concentration profile over time. This phenomenon is called molecular diffusion, and its mathematical aspect is captured by the diffusion equation.

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Molecular diffusion in the context of Turbopause

The turbopause, also called the homopause, marks the altitude in an atmosphere below which turbulent mixing dominates. Mathematically, it is defined as the point where the coefficient of Eddy diffusion is equal to the coefficient of molecular diffusion. Because the molecular diffusion coefficient is dependent on both the composition of the diffusing molecule and the background gas, the turbopause altitude will be different for the different molecular species in an atmosphere. For example, in hydrogen (H2) dominated atmospheres, the helium (He) and methane (CH4) turbopause altitudes are different as a result of the different binary diffusion coefficients of helium and methane in molecular hydrogen.

The region below the turbopause is known as the homosphere, where the atmosphere is well mixed for chemical species which have long mean residence times. Highly reactive chemicals tend to have variable concentration throughout the atmosphere, while unreactive species have more homogeneous concentrations. The region above the turbopause is the heterosphere, where molecular diffusion dominates and the chemical composition of the atmosphere varies according to chemical species and their atomic weight.

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Molecular diffusion in the context of Heterosphere

The heterosphere is the layer of an atmosphere where gases are separated out by molecular diffusion with increasing altitude such that lighter species become more abundant relative to heavier species. The heavier molecules and atoms tend to be present in the lower layers of the heterosphere while the lighter ones are present higher up. The exact boundaries between the different molecules vary according to temperature and solar activity. The heterosphere extends from the turbopause to the edge of a planet's atmosphere and lies directly above the homosphere.

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Molecular diffusion in the context of Advection

In the fields of physics, engineering, and earth sciences, advection is the transport of a substance or quantity by bulk motion of a fluid. The properties of that substance are carried with it. Generally the majority of the advected substance is also a fluid. The properties that are carried with the advected substance are conserved properties such as energy. An example of advection is the transport of pollutants or silt in a river by bulk water flow downstream. Another commonly advected quantity is energy or enthalpy. Here the fluid may be any material that contains thermal energy, such as water or air. In general, any substance or conserved extensive quantity can be advected by a fluid that can hold or contain the quantity or substance.

During advection, a fluid transports some conserved quantity or material via bulk motion. The fluid's motion is described mathematically as a vector field, and the transported material is described by a scalar field showing its distribution over space. Advection requires currents in the fluid, and so cannot happen in rigid solids. It does not include transport of substances by molecular diffusion.

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Molecular diffusion in the context of Effusion

In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a pinhole and the escape of the gas is due to the pressure difference between the container and the exterior.

Under these conditions, essentially all molecules which arrive at the hole continue and pass through the hole, since collisions between molecules in the region of the hole are negligible. Conversely, when the diameter is larger than the mean free path of the gas, flow obeys the Sampson flow law.

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Molecular diffusion in the context of Fick's laws of diffusion

Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the diffusion coefficient, D. Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation.

Fick's first law: Movement of particles from high to low concentration (diffusive flux) is directly proportional to the particle's concentration gradient.

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