Mathematical formulation of quantum mechanics in the context of Phase space

In physics, relativistic quantum mechanics (RQM) is any Poincaré-covariant formulation of quantum mechanics (QM). This theory is applicable to massive particles propagating at all velocities up to those comparable to the speed of light c, and can accommodate massless particles. The theory has application in high-energy physics, particle physics and accelerator physics, as well as atomic physics, chemistry and condensed matter physics. Non-relativistic quantum mechanics refers to the mathematical formulation of quantum mechanics applied in the context of Galilean relativity, more specifically quantizing the equations of classical mechanics by replacing dynamical variables by operators. Relativistic quantum mechanics (RQM) is quantum mechanics applied with special relativity. Although the earlier formulations, like the Schrödinger picture and Heisenberg picture were originally formulated in a non-relativistic background, a few of them (e.g. the Dirac or path-integral formalism) also work with special relativity.

Key features common to all RQMs include: the prediction of antimatter, spin magnetic moments of elementary spin-1/2 fermions, fine structure, and quantum dynamics of charged particles in electromagnetic fields. The key result is the Dirac equation, from which these predictions emerge automatically. By contrast, in non-relativistic quantum mechanics, terms have to be introduced artificially into the Hamiltonian operator to achieve agreement with experimental observations.

In mathematics, a Hilbert space is a real or complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space, to infinite dimensions. The inner product, which is the analog of the dot product from vector calculus, allows lengths and angles to be defined. Furthermore, completeness means that there are enough limits in the space to allow the techniques of calculus to be used. A Hilbert space is a special case of a Banach space.

Hilbert spaces were studied beginning in the first decade of the 20th century by David Hilbert, Erhard Schmidt, and Frigyes Riesz. They are indispensable tools in the theories of partial differential equations, quantum mechanics, Fourier analysis (which includes applications to signal processing and heat transfer), and ergodic theory (which forms the mathematical underpinning of thermodynamics). John von Neumann coined the term Hilbert space for the abstract concept that underlies many of these diverse applications. The success of Hilbert space methods ushered in a very fruitful era for functional analysis. Apart from the classical Euclidean vector spaces, examples of Hilbert spaces include spaces of square-integrable functions, spaces of sequences, Sobolev spaces consisting of generalized functions, and Hardy spaces of holomorphic functions.

Eugene Paul Wigner (Hungarian: Wigner Jenő Pál, pronounced [ˈviɡnɛr ˈjɛnøː ˈpaːl]; November 17, 1902 – January 1, 1995) was a Hungarian-American theoretical physicist who also contributed to mathematical physics. He received the Nobel Prize in Physics in 1963 "for his contributions to the theory of the atomic nucleus and the elementary particles, particularly through the discovery and application of fundamental symmetry principles".

A graduate of the Technical Hochschule Berlin (now Technische Universität Berlin), Wigner worked as an assistant to Karl Weissenberg and Richard Becker at the Kaiser Wilhelm Institute in Berlin, and David Hilbert at the University of Göttingen. Wigner and Hermann Weyl were responsible for introducing group theory into physics, particularly the theory of symmetry in physics. Along the way he performed ground-breaking work in pure mathematics, in which he authored a number of mathematical theorems. In particular, Wigner's theorem is a cornerstone in the mathematical formulation of quantum mechanics. He is also known for his research into the structure of the atomic nucleus. In 1930, Princeton University recruited Wigner, along with John von Neumann, and he moved to the United States, where he obtained citizenship in 1937.

In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy. Its spectrum, the system's energy spectrum or its set of energy eigenvalues, is the set of possible outcomes obtainable from a measurement of the system's total energy. Due to its close relation to the energy spectrum and time-evolution of a system, it is of fundamental importance in most formulations of quantum theory.

The Hamiltonian is named after William Rowan Hamilton, who developed a revolutionary reformulation of Newtonian mechanics, known as Hamiltonian mechanics, which was historically important to the development of quantum physics. Similar to vector notation, it is typically denoted by ${\displaystyle {\hat {H}}}$, where the hat indicates that it is an operator. It can also be written as ${\displaystyle H}$ or ${\displaystyle {\check {H}}}$.

In physics, specifically relativistic quantum mechanics (RQM) and its applications to particle physics, relativistic wave equations predict the behavior of particles at high energies and velocities comparable to the speed of light. In the context of quantum field theory (QFT), the equations determine the dynamics of quantum fields.The solutions to the equations, universally denoted as ψ or Ψ (Greek psi), are referred to as "wave functions" in the context of RQM, and "fields" in the context of QFT. The equations themselves are called "wave equations" or "field equations", because they have the mathematical form of a wave equation or are generated from a Lagrangian density and the field-theoretic Euler–Lagrange equations (see classical field theory for background).

In the Schrödinger picture, the wave function or field is the solution to the Schrödinger equation,$${\displaystyle i\hbar {\frac {\partial }{\partial t}}\psi ={\hat {H}}\psi ,}$$one of the postulates of quantum mechanics. All relativistic wave equations can be constructed by specifying various forms of the Hamiltonian operator Ĥ describing the quantum system. Alternatively, Feynman's path integral formulation uses a Lagrangian rather than a Hamiltonian operator.