Isotopes of thorium in the context of Breeder reactors

Otto Hahn (German: [ˈɔtoː ˈhaːn] ; 8 March 1879 – 28 July 1968) was a German chemist who was a pioneer in the field of radiochemistry. He is referred to as the father of nuclear chemistry and discoverer of nuclear fission, the science behind nuclear reactors and nuclear weapons. Hahn and Lise Meitner discovered isotopes of the radioactive elements radium, thorium, protactinium and uranium. He also discovered the phenomena of atomic recoil and nuclear isomerism, and pioneered rubidium–strontium dating. In 1938, Hahn, Meitner and Fritz Strassmann discovered nuclear fission, for which Hahn alone was awarded the 1944 Nobel Prize in Chemistry.

A graduate of the University of Marburg, which awarded him a doctorate in 1901, Hahn studied under Sir William Ramsay at University College London and at McGill University in Montreal, Canada, under Ernest Rutherford, where he discovered several new radioactive isotopes. He returned to Germany in 1906; Emil Fischer let him use a former woodworking shop in the basement of the Chemical Institute at the University of Berlin as a laboratory. Hahn completed his habilitation in early 1907 and became a Privatdozent. In 1912, he became head of the Radioactivity Department of the newly founded Kaiser Wilhelm Institute for Chemistry (KWIC). Working with Austrian physicist Lise Meitner in the building that now bears their names, they made a series of groundbreaking discoveries, culminating with her isolation of the longest-lived isotope of protactinium in 1918.

Thorium-232 (
Th) is the main naturally occurring isotope of thorium, with a relative abundance of 99.98%. It has a half-life of 14.0 billion years, which makes it the longest-lived isotope of thorium. It decays by alpha decay to radium-228; its decay chain terminates at stable lead-208.

Thorium-232 is a fertile material; it can capture a neutron to form thorium-233, which subsequently undergoes two successive beta decays to uranium-233, which is fissile. As such, it has been used in the thorium fuel cycle in nuclear reactors; various prototype thorium-fueled reactors have been designed. However, as of 2024, thorium fuel has not been widely adopted for commercial-scale nuclear power.

There are 39 known isotopes of radon (₈₆Rn), from Rn to Rn; all are radioactive. The most stable isotope is Rn with a half-life of 3.8215 days, which decays into
Po.

Six isotopes of radon, Rn, occur in trace quantities in nature as decay products of, respectively, At, At, Ra, Ra, Ra, and Ra. Rn and Rn are produced in rare branches in the decay chain of trace quantities of Np; Rn (and also Rn in a rare branch) is an intermediate step in the decay chain of U; Rn is an intermediate step in the decay chain of U; and Rn occurs in the decay chain of Th.