Intensive and extensive properties in the context of Refractive index


Intensive and extensive properties in the context of Refractive index

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⭐ Core Definition: Intensive and extensive properties

Physical or chemical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes.The terms "intensive and extensive quantities" were introduced into physics by German mathematician Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917.

According to International Union of Pure and Applied Chemistry (IUPAC), an intensive property or intensive quantity is one whose magnitude (extent) is independent of the size of the system.An intensive property is not necessarily homogeneously distributed in space; it can vary from place to place in a body of matter and radiation. Examples of intensive properties include temperature, T; refractive index, n; density, ρ; and hardness, η.

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Intensive and extensive properties in the context of Physical property

A physical property is any property of a physical system that is measurable. The changes in the physical properties of a system can be used to describe its changes between momentary states. A quantifiable physical property is called physical quantity. Measurable physical quantities are often referred to as observables. Some physical properties are qualitative, such as shininess, brittleness, etc.; some general qualitative properties admit more specific related quantitative properties, such as in opacity, hardness, ductility, viscosity, etc.

Physical properties are often characterized as intensive and extensive properties. An intensive property does not depend on the size or extent of the system, nor on the amount of matter in the object, while an extensive property shows an additive relationship. These classifications are in general only valid in cases when smaller subdivisions of the sample do not interact in some physical or chemical process when combined.

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Intensive and extensive properties in the context of Internal energy

The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields. It includes the thermal energy, i.e., the constituent particles' kinetic energies of motion relative to the motion of the system as a whole. Without a thermodynamic process, the internal energy of an isolated system cannot change, as expressed in the law of conservation of energy, a foundation of the first law of thermodynamics. The notion has been introduced to describe the systems characterized by temperature variations, temperature being added to the set of state parameters, the position variables known in mechanics (and their conjugated generalized force parameters), in a similar way to potential energy of the conservative fields of force, gravitational and electrostatic. Its author is Rudolf Clausius. Without transfer of matter, internal energy changes equal the algebraic sum of the heat transferred and the work done. In systems without temperature changes, internal energy changes equal the work done by/on the system.

The internal energy cannot be measured absolutely. Thermodynamics concerns changes in the internal energy, not its absolute value. The processes that change the internal energy are transfers, into or out of the system, of substance, or of energy, as heat, or by thermodynamic work. These processes are measured by changes in the system's properties, such as temperature, entropy, volume, electric polarization, and molar constitution. The internal energy depends only on the internal state of the system and not on the particular choice from many possible processes by which energy may pass into or out of the system. It is a state variable, a thermodynamic potential, and an extensive property.

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Intensive and extensive properties in the context of Electrical resistance and conductance

The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is electrical conductance, measuring the ease with which an electric current passes. Electrical resistance shares some conceptual parallels with mechanical friction. The SI unit of electrical resistance is the ohm (Ω), while electrical conductance is measured in siemens (S) (formerly called the 'mho' and then represented by ).

The resistance of an object depends in large part on the material it is made of. Objects made of electrical insulators like rubber tend to have very high resistance and low conductance, while objects made of electrical conductors like metals tend to have very low resistance and high conductance. This relationship is quantified by resistivity or conductivity. The nature of a material is not the only factor in resistance and conductance, however; it also depends on the size and shape of an object because these properties are extensive rather than intensive. For example, a wire's resistance is higher if it is long and thin, and lower if it is short and thick. All objects resist electrical current, except for superconductors, which have a resistance of zero.

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Intensive and extensive properties in the context of Continuity equation

A continuity equation or transport equation is an equation that describes the transport of some quantity. It is particularly simple and powerful when applied to a conserved quantity, but it can be generalized to apply to any extensive quantity. Since mass, energy, momentum, electric charge and other natural quantities are conserved under their respective appropriate conditions, a variety of physical phenomena may be described using continuity equations.

Continuity equations are a stronger, local form of conservation laws. For example, a weak version of the law of conservation of energy states that energy can neither be created nor destroyed—i.e., the total amount of energy in the universe is fixed. This statement does not rule out the possibility that a quantity of energy could disappear from one point while simultaneously appearing at another point. A stronger statement is that energy is locally conserved: energy can neither be created nor destroyed, nor can it "teleport" from one place to another—it can only move by a continuous flow. A continuity equation is the mathematical way to express this kind of statement. For example, the continuity equation for electric charge states that the amount of electric charge in any volume of space can only change by the amount of electric current flowing into or out of that volume through its boundaries.

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Intensive and extensive properties in the context of Moment of inertia

The moment of inertia, otherwise known as the mass moment of inertia, angular/rotational mass, second moment of mass, or most accurately, rotational inertia, of a rigid body is defined relatively to a rotational axis. It is the ratio between the torque applied and the resulting angular acceleration about that axis. It plays the same role in rotational motion as mass does in linear motion. A body's moment of inertia about a particular axis depends both on the mass and its distribution relative to the axis, increasing with mass and distance from the axis.

It is an extensive (additive) property: for a point mass the moment of inertia is simply the mass times the square of the perpendicular distance to the axis of rotation. The moment of inertia of a rigid composite system is the sum of the moments of inertia of its component subsystems (all taken about the same axis). Its simplest definition is the second moment of mass with respect to distance from an axis.

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Intensive and extensive properties in the context of Sankey diagram

Sankey diagrams are a data visualisation technique or flow diagram that emphasizes flow/movement/change from one state to another or one time to another, in which the width of the arrows is proportional to the flow rate of the depicted extensive property. The arrows being connected are called nodes and the connections are called links.

Sankey diagrams can also visualize the energy accounts, material flow accounts on a regional or national level, and cost breakdowns. The diagrams are often used in the visualization of material flow analysis.

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Intensive and extensive properties in the context of Advection

In the fields of physics, engineering, and earth sciences, advection is the transport of a substance or quantity by bulk motion of a fluid. The properties of that substance are carried with it. Generally the majority of the advected substance is also a fluid. The properties that are carried with the advected substance are conserved properties such as energy. An example of advection is the transport of pollutants or silt in a river by bulk water flow downstream. Another commonly advected quantity is energy or enthalpy. Here the fluid may be any material that contains thermal energy, such as water or air. In general, any substance or conserved extensive quantity can be advected by a fluid that can hold or contain the quantity or substance.

During advection, a fluid transports some conserved quantity or material via bulk motion. The fluid's motion is described mathematically as a vector field, and the transported material is described by a scalar field showing its distribution over space. Advection requires currents in the fluid, and so cannot happen in rigid solids. It does not include transport of substances by molecular diffusion.

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Intensive and extensive properties in the context of Thermodynamic properties

In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as Kf (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties.

"Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive).

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Intensive and extensive properties in the context of Nondimensionalization

Nondimensionalization is the partial or full removal of physical dimensions from an equation involving physical quantities by a suitable substitution of variables. This technique can simplify and parameterize problems where measured units are involved. It is closely related to dimensional analysis. In some physical systems, the term scaling is used interchangeably with nondimensionalization, in order to suggest that certain quantities are better measured relative to some appropriate unit. These units refer to quantities intrinsic to the system, rather than units such as SI units. Nondimensionalization is not the same as converting extensive quantities in an equation to intensive quantities, since the latter procedure results in variables that still carry units.

Nondimensionalization can also recover characteristic properties of a system. For example, if a system has an intrinsic resonance frequency, length, or time constant, nondimensionalization can recover these values. The technique is especially useful for systems that can be described by differential equations. One important use is in the analysis of control systems.One of the simplest characteristic units is the doubling time of a system experiencing exponential growth, or conversely the half-life of a system experiencing exponential decay; a more natural pair of characteristic units is mean age/mean lifetime, which correspond to base e rather than base 2.

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