A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolithium compounds and triethylborane. Pyrophoric materials are often water-reactive as well and will ignite when they contact water or humid air. They can be handled safely in atmospheres of argon or (with a few exceptions) nitrogen. Fire classification fire extinguishers are designated for use in fires involving metals but not pyrophoric materials in general. A related concept is hypergolicity, in which two compounds spontaneously ignite when mixed.
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In this Dossier
Hypergolic propellant in the context of Titan IV
Titan IV was a family of heavy-lift space launch vehicles developed by Martin Marietta and operated by the United States Air Force from 1989 to 2005. Launches were conducted from Cape Canaveral Air Force Station, Florida and Vandenberg Air Force Base, California.
The Titan IV was the last of the Titan family of rockets, originally developed by the Glenn L. Martin Company in 1958. It was retired in 2005 due to their high cost of operation and concerns over its toxic hypergolic propellants, and replaced with the Atlas V and Delta IV launch vehicles under the EELV program. The final launch (B-30) from Cape Canaveral occurred on 29 April 2005, and the final launch from Vandenberg AFB occurred on 19 October 2005. Lockheed Martin Space Systems built the Titan IVs near Denver, Colorado, under contract to the US government.
Hypergolic propellant in the context of Hydrolox
The highest specific impulse chemical rockets use liquid propellants (liquid-propellant rockets). They can consist of a single chemical (a monopropellant) or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.
About 170 different propellants made of liquid fuel have been tested, excluding minor changes to a specific propellant such as propellant additives, corrosion inhibitors, or stabilizers. In the U.S. alone at least 25 different propellant combinations have been flown.