Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks.
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The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic magma, which is high in magnesium and iron and produces basalt or gabbro, as it fractionally crystallizes to become a felsic magma, which is low in magnesium and iron and produces rhyolite or granite. Calc-alkaline rocks are rich in alkaline earths (magnesia and calcium oxide) and alkali metals and make up a major part of the crust of the continents.
The diverse rock types in the calc-alkaline series include volcanic types such as basalt, andesite, dacite, rhyolite, and also their coarser-grained intrusive equivalents (gabbro, diorite, granodiorite, and granite). They do not include silica-undersaturated, alkalic, or peralkaline rocks.
Magma (from Ancient Greek μάγμα (mágma) 'thick unguent') is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as lava) is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.
Magma is produced by melting of the mantle or the crust in various tectonic settings, which on Earth include subduction zones, continental rift zones, mid-ocean ridges and hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion, such as a dike, a sill, a laccolith, a pluton, or a batholith.
The lower oceanic crust is the lower part of the oceanic crust and represents the major part of it (the largest part by volume). It is generally located 4–8 km below the ocean floor and the major lithologies are mafic (ultramafic and gabbroic rocks) which derive from melts rising from the Earth's mantle. This part of the oceanic crust is an important zone for processes such as melt accumulation and melt modification (fractional crystallisation and crustal assimilation). The recycling of this part of the oceanic crust, together with the upper mantle has been suggested as a significant source component for tholeiitic magmas in Hawaiian volcanoes. Although the lower oceanic crust builds the link between the mantle and the MORB, and can't be neglected for the understanding of MORB evolution, the complex processes operating in this zone remain unclear and there is an ongoing debate in Earth Sciences about this. It is 6KM long.
Having a mean density of 3,346.4 kg/m, the Moon is a differentiated body, being composed of a geochemically distinct crust, mantle, and planetary core. This structure is believed to have resulted from the fractional crystallization of a magma ocean shortly after its formation about 4.5 billion years ago. The energy required to melt the outer portion of the Moon is commonly attributed to a giant impact event that is postulated to have formed the Earth-Moon system, and the subsequent reaccretion of material in Earth orbit. Crystallization of this magma ocean would have given rise to a mafic mantle and a plagioclase-rich crust.
Geochemical mapping from orbit implies that the crust of the Moon is largely anorthositic in composition, consistent with the magma ocean hypothesis. In terms of elements, the lunar crust is composed primarily of oxygen, silicon, magnesium, iron, calcium, and aluminium, but important minor and trace elements such as titanium, uranium, thorium, potassium, sulphur, manganese, chromium, and hydrogen are present as well. Based on geophysical techniques, the crust is estimated to be on average about 50 km thick.
Anorthosite (/əˈnɔːrθəsaɪt/) is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.
Anorthosites are of enormous geologic interest, because it is still not fully understood how they form. Most models involve separating plagioclase crystals based on their density. Plagioclase crystals are usually less dense than magma; so, as plagioclase crystallizes in a magma chamber, the plagioclase crystals float to the top, concentrating there.
Peralkaline rocks include those igneous rocks which have a deficiency of aluminium such that sodium and potassium are in excess of that needed for feldspar. The presence of aegerine (sodium pyroxene) and riebeckite (sodium amphibole) are indicative of peralkaline conditions. Examples are the peralkaline rhyolites, comendite and pantellerite, with comendite being the more felsic (silica-rich) rock. Another example is the peralkaline granite that forms the islet of Rockall in the North Atlantic Ocean.
Peralkaline rocks are indicative of continental rift-related volcanicity (e.g. the peralkaline rhyolites of the East African Rift in central Kenya) as well as continental and oceanic hotspot volcanicity (e.g. the peralkaline rhyolites of the Glass House Mountains in eastern Australia and the Canary Islands in the Atlantic Ocean). Peralkaline rocks related to subduction zone volcanicity have also been reported (e.g. Sardinia in Italy). Peralkaline magmas likely form when fractional crystallization removes a high proportion of plagioclase relative to mafic minerals.
A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions can be many kilometres in area covering from around 100 km (39 sq mi) to over 50,000 km (19,000 sq mi) and several hundred metres to over one kilometre (3,300 ft) in thickness. While most layered intrusions are Archean to Proterozoic in age (for example, the Paleoproterozoic Bushveld complex), they may be any age such as the Cenozoic Skaergaard intrusion of east Greenland or the Rum layered intrusion in Scotland. Although most are ultramafic to mafic in composition, the Ilimaussaq intrusive complex of Greenland is an alkalic intrusion.
Layered intrusions are typically found in ancient cratons and are rare but worldwide in distribution. The intrusive complexes exhibit evidence of fractional crystallization and crystal segregation by settling or floating of minerals from a melt.
In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals in which it is included. It is defined by a partition coefficient between rock-forming minerals and melt being much smaller than 1.
During the fractional crystallization of magma and magma generation by the partial melting of the Earth's mantle and crust, elements that have difficulty in entering cation sites of the minerals are concentrated in the melt phase of the magma (liquid phase).