Flocculation in the context of "Peptization"

Play Trivia Questions online!

or

Skip to study material about Flocculation in the context of "Peptization"




⭐ Core Definition: Flocculation

In colloidal chemistry, flocculation is a process by which colloidal particles come out of suspension to sediment in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended, under the form of a stable dispersion (where the internal phase (solid) is dispersed throughout the external phase (fluid) through mechanical agitation) and are not truly dissolved in solution.

Coagulation and flocculation are important processes in fermentation and water treatment with coagulation aimed to destabilize and aggregate particles through chemical interactions between the coagulant and colloids, and flocculation to sediment the destabilized particles by causing their aggregation into floc.

↓ Menu

👉 Flocculation in the context of Peptization

The peptization of a liquid mixture is the process of converting the mixture into a colloid by shaking it with a suitable electrolyte called a peptizing agent. That is, the insoluble solid particles which have settled out of the mixture (i.e. the precipitate) are reformed into microscopic particles suspended in the mixture. Peptization is the reverse of flocculation, the aggregation of colloidal particles into precipitate; as such, it is also known as deflocculation.

This is particularly important in colloid chemistry or for precipitation reactions in an aqueous solution. When colloidal particles bear a same sign electric charge, they mutually repel each other and cannot aggregate together. Freshly precipitated aluminium or iron hydroxide is extremely difficult to filter because the very fine colloidal particles directly pass through a paper filter. To facilitate the filtration, the colloidal suspension must be first flocculated by adding a concentrated solution of salt to the system. Multivalent cations are more efficient flocculants than monovalent cations: AlCl3 > CaCl2 > NaCl. The electrical charges present at the surface of the particles are so "neutralised" and disappear. More correctly speaking, the electrical double layer existing at the surface of the particles is compressed by the added electrolyte and collapses at high ionic strength. The electrical repulsion no longer hinders the aggregation of particles and they can then coalesce to form a flocculent precipitate that is easy to filter. If the precipitate is washed with an excessive volume of deionised water, the electrical double layer present at the surface of the particles expands again and the electrical repulsion reappears: the precipitate peptizes and the particles pass again through the filter.

↓ Explore More Topics
In this Dossier

Flocculation in the context of Water purification

Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for human consumption (drinking water), but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The history of water purification includes a wide variety of methods. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light.

Water purification can reduce the concentration of particulate matter including suspended particles, parasites, bacteria, algae, viruses, and fungi as well as reduce the concentration of a range of dissolved and particulate matter.

↑ Return to Menu

Flocculation in the context of Fissility (geology)

In geology, fissility is the ability or tendency of a rock to split along flat planes of weakness (“parting surfaces”). These planes of weakness are oriented parallel to stratification in sedimentary rocks. Fissility is differentiated from scaly fabric in hand sample by the parting surfaces’ continuously parallel orientations to each other and to stratification. Fissility is distinguished from scaly fabric in thin section by the well-developed orientation of platy minerals such as mica. Fissility is the result of sedimentary or metamorphic processes.

Planes of weakness are developed in sedimentary rocks such as shale or mudstone by clay particles aligning during compaction. Planes of weakness are developed in metamorphic rocks by the recrystallization and growth of micaceous minerals. A rock's fissility can be degraded in numerous ways during the geologic process, including clay particles flocculating into a random fabric before compaction, bioturbation during compaction, and weathering during and after uplift. The effect of bioturbation has been documented well in shale cores sampled: past variable critical depths where burrowing organisms can no longer survive, shale fissility will become more pervasive and better defined.

↑ Return to Menu

Flocculation in the context of Tofu

Tofu (Japanese: 豆腐, Hepburn: Tōfu; Korean: 두부; RR: dubu, Chinese: 豆腐; pinyin: dòufu) or bean curd is a food prepared by coagulating soy milk and then pressing the resulting curds into solid white blocks of varying softness: silken, soft, firm, and extra (or super) firm. It originated in China and has been consumed for over 2,000 years. Tofu is a traditional component of many East Asian and Southeast Asian cuisines; in modern Western cooking, it is often used as a meat substitute.

Nutritionally, tofu is low in calories, while containing a relatively large amount of protein. It is a high and reliable source of iron, and can have a high calcium or magnesium content depending on the coagulants (e.g. calcium chloride, calcium sulfate, magnesium sulfate) used in manufacturing. Cultivation of tofu, as a protein-rich food source, has one of the lowest needs for land use (1.3 m/ 1000 kcal) and emits some of the lowest amount of greenhouse gas emissions (1.6 kg CO2/ 100 g protein).

↑ Return to Menu

Flocculation in the context of Particle aggregation

Particle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called unstable. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.

Particle agglomeration can be a reversible or irreversible process. Particle agglomerates defined as "hard agglomerates" are more difficult to redisperse to the initial single particles. In the course of agglomeration, the agglomerates will grow in size, and as a consequence they may settle to the bottom of the container, which is referred to as sedimentation. Alternatively, a colloidal gel may form in concentrated suspensions which changes its rheological properties. The reverse process whereby particle agglomerates are re-dispersed as individual particles, referred to as peptization, hardly occurs spontaneously, but may occur under stirring or shear.

↑ Return to Menu

Flocculation in the context of Activated sludge

The activated sludge process is a type of biological wastewater treatment process for treating sewage or industrial wastewaters using aeration and a biological floc composed of bacteria and protozoa. It is one of several biological wastewater treatment alternatives in secondary treatment, which deals with the removal of biodegradable organic matter and suspended solids. It uses air (or oxygen) and microorganisms to biologically oxidize organic pollutants, producing a waste sludge (or floc) containing the oxidized material.

The activated sludge process for removing carbonaceous pollution begins with an aeration tank where air (or oxygen) is injected into the waste water. This is followed by a settling tank to allow the biological flocs (the sludge blanket) to settle, thus separating the biological sludge from the clear treated water. Part of the waste sludge is recycled to the aeration tank and the remaining waste sludge is removed for further treatment and ultimate disposal.

↑ Return to Menu

Flocculation in the context of Ricotta

Ricotta (Italian: [riˈkɔtta]) is an Italian whey cheese made from sheep, cow, goat, or Italian water buffalo milk whey left over from the production of other cheeses. However, modern ricotta is often made from milk instead of whey. Like other whey cheeses, it is made by coagulating the proteins that remain after the casein has been used to make cheese, notably albumin and globulin.

Ricotta (lit.'recooked' or 'refined') protein can be harvested if the whey is first allowed to become more acidic by additional fermentation (by letting it sit for 12–24 hours at room temperature). Then the acidified whey is heated to near boiling. The combination of low pH and high temperature denatures the protein and causes it to flocculate, forming a fine curd. Once cooled, it is separated by passing the liquid through a fine cloth, leaving the curd behind.

↑ Return to Menu

Flocculation in the context of Ferrofluid

Ferrofluid is a dark coloured liquid that is attracted to the poles of a magnet. It is a colloidal liquid made of nanoscale ferromagnetic or ferrimagnetic particles suspended inside acarrier fluid (usually an organic solvent or water). Each magnetic particle is thoroughly coated with a surfactant to inhibit clumping. Large ferromagnetic particles can be ripped out of the homogeneous colloidal mixture, forming a separate clump of magnetic dust when exposed to strong magnetic fields. The magnetic attraction of tiny nanoparticles is weak enough that the surfactant's Van der Waals force is sufficient to prevent magnetic clumping or agglomeration. Ferrofluids usually do not retain magnetization in the absence of an externally applied field and thus are often classified as "superparamagnets" rather than ferromagnets. A recent review article titled "Magnetic nanofluids (Ferrofluids): Recent advances, applications, challenges, and future directions", provides a pedagogical description of magnetic fluids, with the necessary background, key concepts, physics, experimental protocols, design of experiments, challenges, and future directions.

In contrast to ferrofluids, magnetorheological fluids (MR fluids) are magnetic fluids with larger particles. That is, a ferrofluid contains primarily nanoparticles, while an MR fluid contains primarily micrometre-scale particles. The particles in a ferrofluid are suspended by Brownian motion and generally will not settle under normal conditions, while particles in an MR fluid are too heavy to be suspended by Brownian motion. Particles in an MR fluid will therefore settle over time because of the inherent density difference between the particles and their carrier fluid. As a result, ferrofluids and MR fluids have very different applications.

↑ Return to Menu

Flocculation in the context of Coagulation (water treatment)

In water treatment, coagulation and flocculation involve the addition of compounds that promote the clumping of fine floc into larger floc so that they can be more easily separated from the water. Coagulation is a chemical process that involves neutralization of charge whereas flocculation is a physical process and does not involve neutralization of charge. The coagulation-flocculation process can be used as a preliminary or intermediary step between other water or wastewater treatment processes like filtration and sedimentation. Iron and aluminium salts are the most widely used coagulants but salts of other metals such as titanium and zirconium have been found to be highly effective as well.

↑ Return to Menu