Fayalite (Fe 2SiO 4, commonly abbreviated to Fa) is the iron-rich end-member of the olivinesolid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system (space groupPbnm) with cell parameters a = 4.82 Å, b = 10.48 Å and c = 6.09 Å.
Fayalite forms solid solution series with the magnesium olivine endmember forsterite (Mg2SiO4) and also with the manganese rich olivine endmember tephroite (Mn2SiO4).
An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of some chemical elements, rather than as substances with an exact chemical formula. There may be two or more endmembers in a group or series of minerals.
For example, forsterite (Mg 2SiO 4) and fayalite (Fe 2SiO 4) are the two end-members of the olivinesolid-solution series, varying in Mg and Fe in their chemical composition. So, the chemical formula of olivine can be better expressed as Mg(2−x)FexSiO4 or MgxFe(2−x)SiO4.
While chemically pure materials have a single melting point, chemical mixtures often partially melt at the temperature known as the solidus (TS or Tsol), and fully melt at the higher liquidus temperature (TL or Tliq). The solidus is always less than or equal to the liquidus, but they need not coincide. If a gap exists between the solidus and liquidus it is called the freezing range, and within that gap, the substance consists of a mixture of solid and liquid phases (like a slurry). Such is the case, for example, with the olivine (forsterite-fayalite) system, which is common in Earth's mantle.
The mineralolivine (/ˈɒl.ɪˌviːn/) is a magnesium iron silicate with the chemical formula (Mg,Fe)2SiO4. It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. Olivine has many uses, such as the gemstoneperidot (or chrysolite), as well as industrial applications like metalworking processes.
The ratio of magnesium to iron varies between the two endmembers of the solid solution series: forsterite (Mg-endmember: Mg 2SiO 4) and fayalite (Fe-endmember: Fe 2SiO 4). Compositions of olivine are commonly expressed as molar percentages of forsterite (Fo) and/or fayalite (Fa) (e.g., Fo70Fa30, or just Fo70 with Fa30 implied). Forsterite's melting temperature is unusually high at atmospheric pressure, almost 1,900 °C (3,450 °F), while fayalite's is much lower – about 1,200 °C (2,190 °F). Melting temperature varies smoothly between the two endmembers, as do other properties. Olivine incorporates only minor amounts of elements other than oxygen (O), silicon (Si), magnesium (Mg) and iron (Fe). Manganese (Mn) and nickel (Ni) commonly are the additional elements present in highest concentrations.
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivinesolid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space groupPbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).
Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe. In 2011 it was observed as tiny crystals in the dusty clouds of gas around a forming star.