Exothermic in the context of "Ionic bonding"

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⭐ Core Definition: Exothermic

In thermodynamics, an exothermic process (from Ancient Greek έξω (éxō) 'outward' and θερμικός (thermikós) 'thermal') is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a battery), or sound (e.g. explosion heard when burning hydrogen). The term exothermic was first coined by 19th-century French chemist Marcellin Berthelot.

The opposite of an exothermic process is an endothermic process, one that absorbs energy, usually in the form of heat. The concept is frequently applied in the physical sciences to chemical reactions where chemical bond energy is converted to thermal energy (heat).

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In this Dossier

Exothermic in the context of Fire

Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products.Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce plasma. The color and intensity of the flame depend on the type of fuel and composition of the surrounding gases.

Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. It directly impacts land-based ecological systems worldwide. The positive effects of fire include stimulating plant growth and maintaining ecological balance. Its negative effects include hazards to life and property, atmospheric pollution, and water contamination. When fire removes protective vegetation, heavy rainfall can cause soil erosion. The burning of vegetation releases nitrogen into the atmosphere, unlike other plant nutrients such as potassium and phosphorus which remain in the ash and are quickly recycled into the soil. This loss of nitrogen produces a long-term reduction in the fertility of the soil, though it can be recovered by nitrogen-fixing plants such as clover, peas, and beans; by decomposition of animal waste and corpses, and by natural phenomena such as lightning.

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Exothermic in the context of Pyrotechnics

Pyrotechnics is the science and craft of creating fireworks, but also includes safety matches, oxygen candles, explosive bolts (and other fasteners), parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. This trade relies upon self-contained and self-sustained exothermic chemical reactions to make heat, light, gas, smoke and/or sound. The name comes from the Greek words pyr (πυρ; 'fire') and technikós (τεχνικός; 'artistic').

Improper use of pyrotechnics could lead to pyrotechnic accidents. People responsible for the safe storage, handling, and functioning of pyrotechnic devices are known as pyrotechnicians.

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Exothermic in the context of Stratosphere

The stratosphere is the second-lowest layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. Pronounced /ˈstrætəˌsfɪər, -t-/, the name originates from from Ancient Greek στρωτός (strōtós) 'layer, stratum' and -sphere. The stratosphere is composed of stratified temperature zones, with the warmer layers of air located higher (closer to outer space) and the cooler layers lower (closer to the planetary surface of the Earth). The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer, where ozone is exothermically photolyzed into oxygen in a cyclical fashion. This temperature inversion is in contrast to the troposphere, where temperature decreases with altitude, and between the troposphere and stratosphere is the tropopause border that demarcates the beginning of the temperature inversion.

Near the equator, the lower edge of the stratosphere is as high as 20 km (66,000 ft; 12 mi), at mid-latitudes around 10 km (33,000 ft; 6.2 mi), and at the poles about 7 km (23,000 ft; 4.3 mi). Temperatures range from an average of −51 °C (−60 °F; 220 K) near the tropopause to an average of −15 °C (5.0 °F; 260 K) near the mesosphere. Stratospheric temperatures also vary within the stratosphere as the seasons change, reaching particularly low temperatures in the polar night (winter). Winds in the stratosphere can far exceed those in the troposphere, reaching near 60 m/s (220 km/h; 130 mph) in the Southern polar vortex.

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Exothermic in the context of Ionic bond

Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds. It is one of the main types of bonding, along with covalent bonding and metallic bonding. Ions are atoms (or groups of atoms) with an electrostatic charge. Atoms that gain electrons make negatively charged ions (called anions). Atoms that lose electrons make positively charged ions (called cations). This transfer of electrons is known as electrovalence in contrast to covalence. In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be more complex, e.g. polyatomic ions like NH
4
or SO
4
. In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal to obtain a full valence shell for both atoms.

Clean ionic bonding – in which one atom or molecule completely transfers an electron to another – cannot exist: all ionic compounds have some degree of covalent bonding or electron sharing. Thus, the term "ionic bonding" is given when the ionic character is greater than the covalent character – that is, a bond in which there is a large difference in electronegativity between the cation and anion, causing the bonding to be more polar (ionic) than in covalent bonding where electrons are shared more equally. Bonds with partially ionic and partially covalent characters are called polar covalent bonds.

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Exothermic in the context of Combustion

Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science.

Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A simple example can be seen in the combustion of hydrogen and oxygen into water vapor, a reaction which is commonly used to fuel rocket engines. This reaction releases 242 kJ/mol of heat and reduces the enthalpy accordingly (at constant temperature and pressure):

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Exothermic in the context of Flame

A flame (from Latin flamma) is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction made in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasma.

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Exothermic in the context of Guns

A gun is a device that propels a projectile using pressure or explosive force. The projectiles are typically solid, but can also be pressurized liquid (e.g. in water guns or cannons), or gas (e.g. light-gas gun). Solid projectiles may be free-flying (as with bullets and artillery shells) or tethered (as with Tasers, spearguns and harpoon guns). A large-caliber gun is also called a cannon. Guns were designed as weapons for military use, and then found use in hunting. Now, there are guns, e.g., toy guns, water guns, paintball guns, etc., for many purposes.

The means of projectile propulsion vary according to designs, but are traditionally effected pneumatically by a high gas pressure contained within a barrel tube (gun barrel), produced either through the rapid exothermic combustion of propellants (as with firearms), or by mechanical compression (as with air guns). The high-pressure gas is introduced behind the projectile, pushing and accelerating it down the length of the tube, imparting sufficient launch velocity to sustain its further travel towards the target once the propelling gas ceases acting upon it after it exits the muzzle. Alternatively, new-concept linear motor weapons may employ an electromagnetic field to achieve acceleration, in which case the barrel may be substituted by guide rails (as in railguns) or wrapped with magnetic coils (as in coilguns).

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