Corrosion in the context of Boiler explosion


Corrosion in the context of Boiler explosion

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⭐ Core Definition: Corrosion

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

In the most common use of the word, this means electrochemical oxidation of a metal reacting with an oxidant such as oxygen (O2, gaseous or dissolved), or H3O ions (H, hydrated protons) present in aqueous solution. Rusting, the formation of red-orange iron oxides, is perhaps the most familiar example of electrochemical corrosion. This type of corrosion typically produces oxides or salts of the original metal and results in a distinctive coloration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although, in this context, the term degradation is more common. Corrosion degrades the useful properties of materials and structures including mechanical strength, appearance, and permeability to liquids and gases. Corrosive is distinguished from caustic: the former implies mechanical degradation, the latter chemical.

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Corrosion in the context of Coastal erosion

Coastal erosion is the loss or displacement of land, or the long-term removal of sediment and rocks along the coastline due to the action of waves, currents, tides, wind-driven water, waterborne ice, or other impacts of storms. The landward retreat of the shoreline can be measured and described over a temporal scale of tides, seasons, and other short-term cyclic processes. Coastal erosion may be caused by hydraulic action, abrasion, impact and corrosion by wind and water, and other forces, natural or unnatural.

On non-rocky coasts, coastal erosion results in rock formations in areas where the coastline contains rock layers or fracture zones with varying resistance to erosion. Softer areas become eroded much faster than harder ones, which typically result in landforms such as tunnels, bridges, columns, and pillars. Over time the coast generally evens out. The softer areas fill up with sediment eroded from hard areas, and rock formations are eroded away. Also erosion commonly happens in areas where there are strong winds, loose sand, and soft rocks. The blowing of millions of sharp sand grains creates a sandblasting effect. This effect helps to erode, smooth and polish rocks. The definition of erosion is grinding and wearing away of rock surfaces through the mechanical action of other rock or sand particles.

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Corrosion in the context of Steel

Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to its high elastic modulus, yield strength, fracture strength and low raw material cost, steel is one of the most commonly manufactured materials in the world. Steel is used in structures (as concrete reinforcing rods or steel beams), in bridges, infrastructure, tools, ships, trains, cars, bicycles, machines, electrical appliances, furniture, and weapons.

Iron is always the main element in steel, but other elements are used to produce various grades of steel, demonstrating altered material, mechanical, and microstructural properties. Stainless steels, for example, typically contain 18% chromium and exhibit improved corrosion and oxidation resistance versus their carbon steel counterpart. Galvanized steel is coated in a layer of zinc to achieve a similar effect. Under atmospheric pressures, steels generally take on two crystalline forms: body-centered cubic and face-centered cubic; however, depending on the thermal history and alloying, the microstructure may contain the distorted martensite phase or the carbon-rich cementite phase, which are tetragonal and orthorhombic, respectively. In the case of alloyed iron, the strengthening is primarily due to the introduction of carbon in the primarily-iron lattice, inhibiting deformation under mechanical stress. Alloying may also induce additional phases that affect the mechanical properties. In most cases, the engineered mechanical properties are at the expense of the ductility and elongation of the pure iron state, which decrease upon the addition of carbon.

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Corrosion in the context of Lithium

Lithium (from Ancient Greek: λίθος, líthos, 'stone') is a chemical element; it has symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. It exhibits a metallic luster when pure, but quickly corrodes in air to a dull silvery gray, then black tarnish. It does not occur freely in nature, but occurs mainly as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride.

The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes found in nature have among the lowest binding energies per nucleon of all stable nuclides. Because of its relative nuclear instability, lithium is less common in the Solar System than 25 of the first 32 chemical elements even though its nuclei are very light: it is an exception to the trend that heavier nuclei are less common. For related reasons, lithium has important uses in nuclear physics. The transmutation of lithium atoms to helium in 1932 was the first fully human-made nuclear reaction, and lithium deuteride serves as a fusion fuel in staged thermonuclear weapons.

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Corrosion in the context of Motor oil

Motor oil, engine oil, or engine lubricant is any one of various substances used for the lubrication of internal combustion engines. They typically consist of base oils enhanced with various additives, particularly antiwear additives, detergents, dispersants, and, for multi-grade oils, viscosity index improvers. The main function of motor oil is to reduce friction and wear on moving parts and to clean the engine from sludge (one of the functions of dispersants) and varnish (detergents). It also neutralizes acids that originate from fuel and from oxidation of the lubricant (detergents), improves the sealing of piston rings, and cools the engine by carrying heat away from moving parts.

In addition to the aforementioned basic constituents, almost all lubricating oils contain corrosion and oxidation inhibitors. Motor oil may be composed of only a lubricant base stock in the case of non-detergent oil, or a lubricant base stock plus additives to improve the oil's detergency, extreme pressure performance, and ability to inhibit corrosion of engine parts.

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Corrosion in the context of Reinforced concrete

Reinforced concrete, also called ferroconcrete or ferro-concrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ductility. The reinforcement is usually, though not necessarily, steel reinforcing bars (known as rebar) and is usually embedded passively in the concrete before the concrete sets. However, post-tensioning is also employed as a technique to reinforce the concrete. In terms of volume used annually, it is one of the most common engineering materials. In corrosion engineering terms, when designed correctly, the alkalinity of the concrete protects the steel rebar from corrosion.

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Corrosion in the context of Cor-Ten

Weathering steel, often called corten steel (or its trademarked name, COR-TEN) is a group of steel alloys that form a stable external layer of rust that eliminates the need for painting.

U.S. Steel (USS) holds the registered trademark on the name COR-TEN. The name COR-TEN refers to the two distinguishing properties of this type of steel: corrosion resistance and tensile strength. Although USS sold its discrete plate business to International Steel Group (now ArcelorMittal) in 2003, it makes COR-TEN branded material in strip mill plate and sheet forms.

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Corrosion in the context of Stainless steel

Stainless steel is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Alternatively, it is known as inox (an abbreviation of the French term inoxydable, meaning non-oxidizable), corrosion-resistant steel (CRES), Nirosta (an abbreviation of the German term nichtrostender Stahl) or rustless steel. Stainless steel's resistance to corrosion comes from its chromium content of 10.5% or more, which forms a passive film that protects the material and can self-heal when exposed to oxygen. It can be further alloyed with elements like molybdenum, carbon, nickel and nitrogen to enhance specific properties for various applications.

The alloy's properties, such as luster and resistance to corrosion, are useful in many applications. Stainless steel can be rolled into sheets, plates, bars, wire, and tubing. These can be used in cookware, cutlery, surgical instruments, major appliances, vehicles, construction material in large buildings, industrial equipment (e.g., in paper mills, chemical plants, water treatment), and storage tanks and tankers for chemicals and food products. Some grades are also suitable for forging and casting.

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Corrosion in the context of Pitting corrosion

Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic (oxidation reaction) while an unknown but potentially vast area becomes cathodic (reduction reaction), leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.

Another term arises, pitting factor, which is defined as the ratio of the depth of the deepest pit (from localized corrosion) to the average penetration depth (mean thickness of the corrosion layer produced by the general uniform corrosion), which can be calculated based on the weight loss and corrosion products density.

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Corrosion in the context of Precious metal

Precious metals are rare, naturally occurring metallic chemical elements of high economic value. Precious metals, particularly the noble metals, are more corrosion resistant and less chemically reactive than most elements. They are usually ductile and have a high lustre. Historically, precious metals were important as currency but they are now regarded mainly as investment and industrial raw materials. Gold, silver, platinum, and palladium each have an ISO 4217 currency code.

The best known precious metals are the precious coinage metals, which are gold and silver. Although both have industrial uses, they are better known for their uses in art, jewelry, and coinage. Other precious metals include the platinum group metals: ruthenium, rhodium, palladium, osmium, iridium, and platinum, of which platinum is the most widely traded.The demand for precious metals is driven not only by their practical use but also by their role as investments and a store of value. Historically, precious metals have commanded much higher prices than common industrial metals.

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Corrosion in the context of Hazardous waste

Hazardous waste is waste that must be handled properly to avoid damaging human health or the environment. Waste can be hazardous because it is toxic, reacts violently with other chemicals, or is corrosive, among other traits. As of 2022, humanity produces 300–500 million metric tons of hazardous waste annually. Some common examples are electronics, batteries, and paints. An important aspect of managing hazardous waste is safe disposal. Hazardous waste can be stored in hazardous waste landfills, burned, or recycled into something new. Managing hazardous waste is important to achieve worldwide sustainability. Hazardous waste is regulated on national scale by national governments as well as on an international scale by the United Nations (UN) and international treaties. A controlled waste is subject to legislative control in its handling or its disposal.

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Corrosion in the context of Coolant

A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator.

While the term "coolant" is commonly used in automotive and HVAC applications, in industrial processing heat-transfer fluid is one technical term more often used in high temperature as well as low-temperature manufacturing applications. The term also covers cutting fluids. Industrial cutting fluid has broadly been classified as water-soluble coolant and neat cutting fluid. Water-soluble coolant is oil in water emulsion. It has varying oil content from nil oil (synthetic coolant).

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Corrosion in the context of Inconel

Inconel is a nickel-chromium-based superalloy often utilized in extreme environments where components are subjected to high temperature, pressure or mechanical loads. Inconel alloys are oxidation- and corrosion-resistant. When heated, Inconel forms a thick, stable passivating oxide layer protecting the surface from further attack. Inconel retains strength over a wide temperature range, making it attractive for high-temperature applications in which aluminum and steel would succumb to creep as a result of thermally-induced crystal vacancies. Inconel's high-temperature strength is developed by solid solution strengthening or precipitation hardening, depending on the alloy.

Inconel alloys are typically used in high temperature applications. Common trade names for various Inconel alloys include:

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Corrosion in the context of Titanium

Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength that is resistant to corrosion in sea water, aqua regia, and chlorine.

Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide (TiO2), is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and titanium trichloride (TiCl3), which is used as a catalyst in the production of polypropylene.

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Corrosion in the context of Chromium

Chromium is a chemical element; it has symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.

Chromium is valued for its high corrosion resistance and hardness. A major development in steel production was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. Stainless steel and chrome plating (electroplating with chromium) together comprise 85% of the commercial use. Chromium is also greatly valued as a metal that is able to be highly polished while resisting tarnishing. Polished chromium reflects almost 70% of the visible spectrum, and almost 90% of infrared light. The name of the element is derived from the Greek word χρῶμα, chrōma, meaning color, because many chromium compounds are intensely colored.

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Corrosion in the context of Passivation (chemistry)

In physical chemistry and engineering, passivation is coating a material so that it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. Undesired passivation of electrodes, called "fouling", increases the circuit resistance so it interferes with some electrochemical applications such as electrocoagulation for wastewater treatment, amperometric chemical sensing, and electrochemical synthesis.

When exposed to air, many metals naturally form a hard, relatively inert surface layer, usually an oxide (termed the "native oxide layer") or a nitride, that serves as a passivation layer - i.e. these metals are "self-protecting". In the case of silver, the dark tarnish is a passivation layer of silver sulfide formed from reaction with environmental hydrogen sulfide. Aluminium similarly forms a stable protective oxide layer which is why it does not "rust". (In contrast, some base metals, notably iron, oxidize readily to form a rough, porous coating of rust that adheres loosely, is of higher volume than the original displaced metal, and sloughs off readily; all of which permit & promote further oxidation.) The passivation layer of oxide markedly slows further oxidation and corrosion in room-temperature air for aluminium, beryllium, chromium, zinc, titanium, and silicon (a metalloid). The inert surface layer formed by reaction with air has a thickness of about 1.5 nm for silicon, 1–10 nm for beryllium, and 1 nm initially for titanium, growing to 25 nm after several years. Similarly, for aluminium, it grows to about 5 nm after several years.

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Corrosion in the context of Noble metal

A noble metal is a metallic chemical element that is resistant to corrosion and is usually found in nature in its raw form. Gold, platinum, and the other platinum group metals (ruthenium, rhodium, palladium, osmium, iridium) are most often so classified. Silver, copper, and mercury are sometimes included as noble metals, but each of these usually occurs in nature combined with sulfur.

In more specialized fields of study and applications, the number of elements counted as noble metals can vary. In some contexts, the term is used only for copper, silver, and gold which have filled d-bands. In others, it is applied more broadly to any metallic or semimetallic element that does not react with a weak acid and give off hydrogen gas in the process. This broader set includes copper, mercury, technetium, rhenium, arsenic, antimony, bismuth, polonium, gold, the six platinum group metals, and silver.

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Corrosion in the context of Tarnish

Tarnish is a thin layer of corrosion that forms over copper, brass, aluminum, magnesium, neodymium and other similar metals as their outermost layer undergoes a chemical reaction. Tarnish does not always result from the sole effects of oxygen in the air. For example, silver needs hydrogen sulfide to tarnish, although it may tarnish with oxygen over time. It often appears as a dull, gray or black film or coating over metal. Tarnish is a surface phenomenon that is self-limiting, unlike rust. Only the top few layers of the metal react. The layer of tarnish seals and protects the underlying layers from reacting.

Tarnish preserves the underlying metal in outdoor use, and in this form is called chemical patina, an example of which is the green or blue-green form of copper(II) carbonate known as verdigris. Unlike patina advantageous in applications such as copper roofing and copper, bronze, and brass statues and fittings exposed to the elements, a chemical patina may be considered undesirable, as on silverware, or a matter of taste or convention, as in toning on coins.

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Corrosion in the context of Paper mill

A paper mill is a factory devoted to making paper from vegetable fibres such as wood pulp, old rags, and other ingredients. Prior to the invention and adoption of the Fourdrinier machine and other types of paper machine that use an endless belt, all paper in a paper mill was made by hand, one sheet at a time, by specialized laborers.

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