Chlorite group in the context of X-ray diffraction


Chlorite group in the context of X-ray diffraction

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⭐ Core Definition: Chlorite group

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

Chlorite minerals show a wide variety of compositions, in which magnesium, iron, aluminium, and silicon substitute for each other in the crystal structure. A complete solid solution series exists between the two most common end members, magnesium-rich clinochlore and iron-rich chamosite. In addition, manganese, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous rocks, hydrothermal rocks and deeply buried sediments.

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Chlorite group in the context of Schist

Schist (/ˈʃɪst/ SHIST) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced schistosity (named for the rock). This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes or plates. This texture reflects a high content of platy minerals, such as mica, talc, chlorite, or graphite. These are often interleaved with more granular minerals, such as feldspar or quartz.

Schist typically forms during regional metamorphism accompanying the process of mountain building (orogeny) and usually reflects a medium grade of metamorphism. Schist can form from many different kinds of rocks, including sedimentary rocks such as mudstones and igneous rocks such as tuffs. Schist metamorphosed from mudstone is particularly common and is often very rich in mica (a mica schist). Where the type of the original rock (the protolith) is discernible, the schist is usually given a name reflecting its protolith, such as schistose metasandstone. Otherwise, the names of the constituent minerals will be included in the rock name, such as quartz-felspar-biotite schist.

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Chlorite group in the context of Tonstein

Tonstein (from the German "Ton", meaning clay, plus "Stein", meaning stone) is a hard, compact sedimentary rock that is composed mainly of kaolinite or, less commonly, other clay minerals such as montmorillonite and illite. The clays often are cemented by iron oxide minerals, carbonaceous matter, or chlorite. Tonsteins form from volcanic ash deposited in swamps.Tonsteins occur as distinctive, thin, and laterally extensive layers in coal seams throughout the world. They are often used as key beds to correlate the strata in which they are found. The regional persistence of tonsteins and relict phenocrysts indicate that they formed as the result of the diagenetic alteration of volcanic ash falls in an acidic (low pH) and low-salinity environment, consistent with a freshwater swamp. In contrast, the alteration of a volcanic ashfall deposit in a marine environment typically produces a bentonite layer.

The induration of tonsteins is in contrast to kaolin claystones that can be mined for kaolin clay, such as the ball clays found at Bovey Tracey which formed by the erosion of a nearby kaolinised granite. These deposits are generally softer, white, and plastic.

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Chlorite group in the context of Metamorphism

Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.

Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as prograde metamorphism, while decreasing temperature and pressure characterize retrograde metamorphism.

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Chlorite group in the context of Greenstone belt

Greenstone belts are zones of variably metamorphosed mafic to ultramafic volcanic sequences with associated sedimentary rocks that occur within Archaean and Proterozoic cratons between granite and gneiss bodies.

The name comes from the green hue imparted by the colour of the metamorphic minerals within the mafic rocks: The typical green minerals are chlorite, actinolite, and other green amphiboles. Greenstone belts also often contain ore deposits of gold, silver, copper, zinc, and lead.

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Chlorite group in the context of Bleb (mineralogy)

In geology, mineralogy, and petrology, a bleb is a small bubble-like inclusion of one mineral within a larger mineral. An example is a bleb of sylvite within chlorite. Blebs tend to be brightly coloured.

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Chlorite group in the context of Chamosite

Chamosite is the Fe end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low-to-moderate-grade metamorphosed iron deposits, as grey or black crystals in oolitic iron ore. Like other chlorites, it is a product of the hydrothermal alteration of pyroxenes, amphiboles and biotite in igneous rock. The composition of chlorite is often related to that of the original igneous mineral, so that more Fe-rich chlorites are commonly found as replacements of the Fe-rich ferromagnesian minerals (Deer et al., 1992).

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Chlorite group in the context of Amygdule

Amygdules or amygdales (/əˈmɪɡdjlz, -dlz/) form when the vesicles (pores from gas bubbles in lava) of a volcanic rock or other extrusive igneous rock are infilled with a secondary mineral, such as calcite, quartz, chlorite, or one of the zeolites. Amygdules usually form after the rock has been emplaced, and are often associated with low-temperature alteration. Amygdules may often be concentrically zoned. Rocks containing amygdules can be described as amygdaloidal.

The word is derived from the Latin word amygdala, meaning "almond tree", and the Greek word αμυγδαλή, meaning "almond" – reflecting the typical shape of an infilled vesicle. Amygdule is more common in American usage, while amygdale is more common in British usage.

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Chlorite group in the context of Phyllite

Phyllite (/ˈfɪlt/ FIL-yte) is a type of foliated metamorphic rock formed from slate that is further metamorphosed so that very fine grained white mica achieves a preferred orientation. It is primarily composed of quartz, sericite mica, and chlorite.

Phyllite has fine-grained mica flakes, whereas slate has extremely fine mica flakes, and schist has large mica flakes, all mica flakes of which have achieved a preferred orientation. Among foliated metamorphic rocks, it represents a gradation in the degree of metamorphism between slate and schist.

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Chlorite group in the context of Metamorphic reaction

A metamorphic reaction is a chemical reaction that takes place during the geological process of metamorphism wherein one assemblage of minerals is transformed into a second assemblage which is stable under the new temperature/pressure conditions resulting in the final stable state of the observed metamorphic rock.

Examples include the production of talc under varied metamorphic conditions:

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Chlorite group in the context of Greenschist facies

Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically 300–450 °C (570–840 °F) and 2–10 kilobars (29,000–145,000 psi). Greenschists commonly have an abundance of green minerals such as chlorite, serpentine, and epidote, and platy minerals such as muscovite and platy serpentine. The platiness gives the rock schistosity (a tendency to split into layers). Other common minerals include quartz, orthoclase, talc, carbonate minerals and amphibole (actinolite).

Greenschist is a general field petrologic term for metamorphic or altered mafic volcanic rock. In Europe, the term prasinite is sometimes used. A greenstone is sometimes a greenschist but can also be rock types without any schistosity, especially metabasalt (spilite). However, basalts may remain quite black if primary pyroxene does not revert to chlorite or actinolite. To qualify for the name, a rock must also exhibit schistosity or some foliation or layering. The rock is derived from basalt, gabbro or similar rocks containing sodium-rich plagioclase feldspar, chlorite, epidote and quartz.

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Chlorite group in the context of Greenstone (archaeology)

Greenstone is a common generic term for valuable, green-hued minerals and metamorphosed igneous rocks and stones which early cultures used in the fashioning of hardstone carvings such as jewelry, statuettes, ritual tools, and various other artifacts. Greenstone artifacts may be made of greenschist, chlorastrolite, serpentine, omphacite, chrysoprase, olivine, nephrite, chloromelanite among other green-hued minerals. The term also includes jade and jadeite, although these are perhaps more frequently identified by these latter terms. The greenish hue of these rocks generally derives from the presence of minerals such as chlorite, hornblende, or epidote.

Greenstone minerals were presumably selected for their color rather than their chemical composition. In archaeology therefore, having a loosely applied general term is at least partially influenced by the observation that ancient cultures often used and considered these various green-hued materials as interchangeable. Greenstone objects are often found very considerable distances from the source of the rock, indicating early travel or trading networks. A polished jadeite axe head in the British Museum (4000–2000 BCE) was found in Canterbury, Kent but uses stone from the Alps of Northern Italy, and objects from other parts of the world had travelled comparable distances to their findspots.

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