Calcium oxide in the context of Base anhydride


Calcium oxide in the context of Base anhydride

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⭐ Core Definition: Calcium oxide

Calcium oxide (formula: CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.

Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals.

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👉 Calcium oxide in the context of Base anhydride

A base anhydride is an oxide of a chemical element from group 1 or 2 (the alkali metals and alkaline earth metals, respectively). They are obtained by removing water from the corresponding hydroxide base. If water is added to a base anhydride, a corresponding hydroxide salt can be [re]-formed.

Base anhydrides are Brønsted–Lowry bases because they are proton acceptors. In addition, they are Lewis bases, because they will share an electron pair with some Lewis acids, most notably acidic oxides. They are potent alkalis and will produce alkali burns on skin, because their affinity for water (that is, their affinity for being slaked) makes them react with body water.

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Calcium oxide in the context of Calc-alkaline magma series

The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic magma, which is high in magnesium and iron and produces basalt or gabbro, as it fractionally crystallizes to become a felsic magma, which is low in magnesium and iron and produces rhyolite or granite. Calc-alkaline rocks are rich in alkaline earths (magnesia and calcium oxide) and alkali metals and make up a major part of the crust of the continents.

The diverse rock types in the calc-alkaline series include volcanic types such as basalt, andesite, dacite, rhyolite, and also their coarser-grained intrusive equivalents (gabbro, diorite, granodiorite, and granite). They do not include silica-undersaturated, alkalic, or peralkaline rocks.

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Calcium oxide in the context of Lime (material)

Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which is used as an industrial mineral and is made by heating calcium carbonate in a kiln. Calcium oxide can occur as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.

These materials are still used in large quantities in the manufacture of steel and as building and engineering materials (including limestone products, cement, concrete, and mortar), as chemical feedstocks, for sugar refining, and other uses. Lime industries and the use of many of the resulting products date from prehistoric times in both the Old World and the New World. Lime is used extensively for wastewater treatment with ferrous sulfate.

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Calcium oxide in the context of Upper mantle

The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (at about 10 km (6.2 mi) under the oceans, and about 35 km (22 mi) under the continents) and ends at the top of the lower mantle, at about 670 km (420 mi). Temperatures range from around 900 K (627 °C; 1,160 °F) at the upper boundary with the crust to around 1,200 K (930 °C; 1,700 °F) at the boundary with the lower mantle. Upper mantle material that has come up onto the surface comprises about 55% olivine, 35% pyroxene, and 5–10% of calcium oxide and aluminum oxide minerals such as plagioclase, spinel, or garnet, depending on depth.

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Calcium oxide in the context of Agricultural lime

Agricultural lime, also called aglime, agricultural limestone, garden lime or liming, is a soil additive made from pulverized limestone or chalk. The primary active component is calcium carbonate. Additional chemicals vary depending on the mineral source and may include calcium oxide. Unlike the types of lime called quicklime (calcium oxide) and slaked lime (calcium hydroxide), powdered limestone does not require lime burning in a lime kiln; it only requires milling. All of these types of lime are sometimes used as soil conditioners, with a common theme of providing a base to correct acidity, but lime for farm fields today is often crushed limestone. Historically, liming of farm fields in centuries past was often done with burnt lime; the difference is at least partially explained by the fact that affordable mass-production-scale fine milling of stone and ore relies on technologies developed since the mid-19th century.

Some effects of agricultural lime on soil are:

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Calcium oxide in the context of Bone ash

Bone ash is a white material produced by the calcination of bones. Typical bone ash consists of about 55.82% calcium oxide, 42.39% phosphorus pentoxide, and 1.79% water. The exact composition of these compounds varies depending upon the type of bones being used, but generally the formula for bone ash is Ca5(OH)(PO4)3. Bone ash usually has a density around 3.10 g/mL and a melting point of 1670 °C (3038 °F). Most bones retain their cellular structure through calcination.

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Calcium oxide in the context of Calcination

Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition.

The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (CO2).

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Calcium oxide in the context of Hydraulic lime

Hydraulic lime (HL) is a general term for a variety of lime different from calcium oxide (quicklime), that sets by hydration and consists of calcium silicate and calcium aluminate, compounds that can harden in contact with water. This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime, and hydraulic lime will set in more extreme conditions, including under water.

The terms 'hydraulic lime' and 'hydrated lime' are quite similar and may be confused but are not necessarily the same material. Hydrated lime is any lime which has been slaked whether it sets through hydration, carbonation, or both.

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Calcium oxide in the context of Calcium hydroxide

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. Annually, approximately 125 million tons of calcium hydroxide are produced worldwide.

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Calcium oxide in the context of Plate glass

Plate glass, flat glass or sheet glass is a type of glass, initially produced in plane form, commonly used for windows, glass doors, transparent walls, and windscreens. For modern architectural and automotive applications, the flat glass is sometimes bent after production of the plane sheet. Flat glass stands in contrast to container glass (used for bottles, jars, cups) and glass fibre (used for thermal insulation, in fibreglass composites, and for optical communication).

Flat glass has a higher magnesium oxide and sodium oxide content than container glass, and a lower silica, calcium oxide, and aluminium oxide content. From the lower soluble oxide content comes the better chemical durability of container glass against water, which is required especially for storage of beverages and food.

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Calcium oxide in the context of Oxygen cycle

The oxygen cycle refers to the various movements of oxygen through the Earth's atmosphere (air), biosphere (flora and fauna), hydrosphere (water bodies and glaciers) and the lithosphere (the Earth's crust). The oxygen cycle demonstrates how free oxygen is made available in each of these regions, as well as how it is used. It is the biogeochemical cycle of oxygen atoms between different oxidation states in ions, oxides and molecules through redox reactions within and between the spheres/reservoirs of the planet Earth. The word oxygen in the literature typically refers to the most common oxygen allotrope, elemental/diatomic oxygen (O2), as it is a common product or reactant of many biogeochemical redox reactions within the cycle. Processes within the oxygen cycle are considered to be biological or geological and are evaluated as either a source (O2 production) or sink (O2 consumption).

Oxygen is one of the most common elements on Earth and represents a large portion of each main reservoir. By far the largest reservoir of Earth's oxygen is within the silicate and oxide minerals of the crust and mantle (99.5% by weight). The Earth's atmosphere, hydrosphere, and biosphere together hold less than 0.05% of the Earth's total mass of oxygen. Besides O2, additional oxygen atoms are present in various forms spread throughout the surface reservoirs in the molecules of biomass, H2O, CO2, HNO3, NO, NO2, CO, H2O2, O3, SO2, H2SO4, MgO, CaO, Al2O3, SiO2, and PO3−4.

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Calcium oxide in the context of Ceramic flux

Fluxes are substances, usually oxides, used in glasses, glazes and ceramic bodies to lower the high melting point of the main glass forming constituents, usually silica and alumina. A ceramic flux functions by promoting partial or complete liquefaction. The most commonly used fluxing oxides in a ceramic glaze contain lead, sodium, potassium, lithium, calcium, magnesium, barium, zinc, strontium, and manganese. These are introduced to the raw glaze as compounds, for example lead as lead oxide. Boron is considered by many to be a glass former rather than a flux.

Some oxides, such as calcium oxide, flux significantly only at high temperature. Lead oxide is the traditional low temperature flux used for crystal glass, but it is now avoided because it is toxic even in small quantities. It is being replaced by other substances, especially boron and zinc oxides.

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Calcium oxide in the context of Basic oxygen furnace

Basic oxygen steelmaking (BOS, BOP, BOF, or OSM), also known as Linz-Donawitz steelmaking or the oxygen converter process, is a method of primary steelmaking in which carbon-rich molten pig iron is made into steel. Blowing oxygen through molten pig iron lowers the carbon content of the alloy and changes it into low-carbon steel. The process is known as basic because fluxes of calcium oxide or dolomite, which are chemical bases, are added to promote the removal of impurities and protect the lining of the converter.

The process was invented in 1948 by Swiss engineer Robert Durrer and commercialized in 1952–1953 by the Austrian steelmaking company VOEST and ÖAMG. The LD converter, named after the Austrian towns Linz and Donawitz (a district of Leoben) is a refined version of the Bessemer converter which replaces blowing air with blowing oxygen. It reduced capital cost of the plants and smelting time, and increased labor productivity. Between 1920 and 2000, labor requirements in the industry decreased by a factor of 1,000, from more than 3 man-hours per metric ton to just 0.003. By 2000 the basic oxygen furnace accounted for 60% of global steel output.

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Calcium oxide in the context of Lime kiln

A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is: CaCO3 + heat → CaO + CO2

This reaction can take place at anywhere above 840 °C (1,540 °F), but is generally considered to occur at 900 °C (1,650 °F) (at which temperature the partial pressure of CO2 is 1 atmosphere), but a temperature around 1,000 °C (1,830 °F) (at which temperature the partial pressure of CO2 is 3.8 atmospheres) is usually used to make the reaction proceed quickly. Excessive temperature is avoided because it produces unreactive, "dead-burned" lime.

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