Water (molecule) in the context of Multiphasic liquid

A molecule is a group of two or more atoms that are held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.

A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O₂); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H₂O). In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.

Thermohaline circulation (THC) is a part of the large-scale ocean circulation driven by global density gradients formed by surface heat and freshwater fluxes. The name thermohaline is derived from thermo-, referring to temperature, and haline, referring to salt content—factors which together determine the density of sea water.

Wind-driven surface currents (such as the Gulf Stream) travel polewards from the equatorial Atlantic Ocean, cooling and sinking en-route to higher latitudes - eventually becoming part of the North Atlantic Deep Water - before flowing into the ocean basins. While the bulk of thermohaline water upwells in the Southern Ocean, the oldest waters (with a transit time of approximately 1000 years) upwell in the North Pacific; extensive mixing takes place between the ocean basins, reducing the difference in their densities, forming the Earth's oceans a global system. The water in these circuits transport energy - as heat - and mass - as dissolved solids and gases - around the globe. Consequently, the state of the circulation greatly impacts the climate of Earth.

Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom.

Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of a molecule, i.e. they can be understood as approximately local and hence transferable properties.

Toluene (/ˈtɒl.juiːn/), also known as toluol (/ˈtɒl.ju.ɒl, -ɔːl, -oʊl/), is a substituted aromatic hydrocarbon with the chemical formula C₆H₅CH₃, often abbreviated as PhCH₃, where Ph stands for the phenyl group. It is a colorless, water-insoluble liquid with the odor associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH₃) attached to a phenyl group by a single bond. As such, its systematic IUPAC name is methylbenzene. Toluene is predominantly used as an industrial feedstock and a solvent.

As the solvent in some types of paint thinner, permanent markers, contact cement and certain types of glue, toluene is sometimes used as a recreational inhalant and has the potential of causing severe neurological harm.

Hydrogen cyanide (also called prussic acid) is a chemical compound with the formula HCN and structural formula H−C≡N. It is a highly toxic and flammable liquid that boils slightly above room temperature, at 25.6 °C (78.1 °F). HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Large-scale applications are for the production of potassium cyanide and adiponitrile, used in mining and plastics, respectively. It is more toxic than solid cyanide compounds due to its volatile nature. A solution of hydrogen cyanide in water, represented as HCN(aq), is called hydrocyanic acid. The salts of the cyanide anion are known as cyanides.

Whether hydrogen cyanide is an organic compound or not is a topic of debate among chemists. It is traditionally considered inorganic, but can also be considered a nitrile, giving rise to its alternative names of methanenitrile and formonitrile.

Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen-bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including O₂, H₂, N₂, CO₂, CH₄, H₂S, Ar, Kr, Xe, and Cl₂ as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the enclathrated guest molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase transitions, not chemical reactions. Their detailed formation and decomposition mechanisms on a molecular level are still not well understood.Clathrate hydrates were first documented in 1810 by Sir Humphry Davy who found that water was a primary component of what was earlier thought to be solidified chlorine.

Clathrates have been found to occur naturally in large quantities. Around 6.4 trillion (6.4×10) tonnes of methane is trapped in deposits of methane clathrate on the deep ocean floor. Such deposits can be found on the Norwegian continental shelf in the northern headwall flank of the Storegga Slide. Clathrates can also exist as permafrost, as at the Mallik gas hydrate site in the Mackenzie Delta of northwestern Canadian Arctic. These natural gas hydrates are seen as a potentially vast energy resource and several countries have dedicated national programs to develop this energy resource. Clathrate hydrate has also been of great interest as technology enabler for many applications like seawater desalination, gas storage, carbon dioxide capture & storage, cooling medium for data centre and district cooling etc. Hydrocarbon clathrates cause problems for the petroleum industry, because they can form inside gas pipelines, often resulting in obstructions. Deep sea deposition of carbon dioxide clathrate has been proposed as a method to remove this greenhouse gas from the atmosphere and control climate change. Clathrates are suspected to occur in large quantities on some outer planets, moons and trans-Neptunian objects, binding gas at fairly high temperatures.

Rotational–vibrational spectroscopy is a branch of molecular spectroscopy that is concerned with infrared and Raman spectra of molecules in the gas phase. Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational) transitions. When such transitions emit or absorb photons (electromagnetic radiation), the frequency is proportional to the difference in energy levels and can be detected by certain kinds of spectroscopy. Since changes in rotational energy levels are typically much smaller than changes in vibrational energy levels, changes in rotational state are said to give fine structure to the vibrational spectrum. For a given vibrational transition, the same theoretical treatment as for pure rotational spectroscopy gives the rotational quantum numbers, energy levels, and selection rules. In linear and spherical top molecules, rotational lines are found as simple progressions at both higher and lower frequencies relative to the pure vibration frequency. In symmetric top molecules the transitions are classified as parallel when the dipole moment change is parallel to the principal axis of rotation, and perpendicular when the change is perpendicular to that axis. The ro-vibrational spectrum of the asymmetric rotor water is important because of the presence of water vapor in the atmosphere.

The Mars ocean hypothesis states that nearly a third of the surface of Mars was covered by an ocean of liquid water early in the planet's geologic history. This primordial ocean, dubbed Paleo-Ocean or Oceanus Borealis (/oʊˈsiːənəs ˌbɒriˈælɪs/ oh-SEE-ə-nəs BORR-ee-AL-iss), would have filled the basin Vastitas Borealis in the northern hemisphere, a region that lies 4–5 km (2.5–3.1 mi) below the mean planetary elevation, at a time period of approximately 4.1–3.8 billion years ago. Evidence for this ocean includes geographic features resembling ancient shorelines, and the chemical properties of the Martian soil and atmosphere. Early Mars would have required a denser atmosphere and warmer climate to allow liquid water to remain at the surface.

Heavy water (deuterium oxide,
H
₂O, D
₂O) is a form of water in which hydrogen atoms are all deuterium (
H or D, also known as heavy hydrogen) rather than the common hydrogen-1 isotope (
H, also called protium) that makes up most of the hydrogen in normal water. The presence of the heavier isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water.

Dimethylformamide, DMF is an organic compound with the chemical formula HCON(CH₃)₂. Its structure is HC(=O)−N(−CH₃)₂. Commonly abbreviated as DMF (although this initialism is sometimes used for dimethylfuran, or dimethyl fumarate), this colourless liquid is miscible with water and the majority of organic liquids. DMF is a common solvent for chemical reactions. Dimethylformamide is odorless, but technical-grade or degraded samples often have a fishy smell due to impurity of dimethylamine. Dimethylamine degradation impurities can be removed by sparging samples with an inert gas such as argon or by sonicating the samples under reduced pressure. As its name indicates, it is structurally related to formamide, having two methyl groups in the place of the two hydrogens. DMF is a polar (hydrophilic) aprotic solvent with a high boiling point. It facilitates reactions that follow polar mechanisms, such as S_N2 reactions.