Vapor pressure in the context of "Raoult's law"

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⭐ Core Definition: Vapor pressure

Vapor pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the attractive interactions between liquid molecules become less significant in comparison to the entropy of those molecules in the gas phase, increasing the vapor pressure. Thus, liquids with strong intermolecular interactions are likely to have smaller vapor pressures, with the reverse true for weaker interactions.

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Vapor pressure in the context of Evaporation

Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. A high concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling.

On average, only a fraction of the molecules in a liquid have enough heat energy to escape from the liquid. The evaporation will continue until an equilibrium is reached when the evaporation of the liquid is equal to its condensation. In an enclosed environment, a liquid will evaporate until the surrounding air is saturated.

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Vapor pressure in the context of Steam

Steam is water vapor, often mixed with air or an aerosol of liquid water droplets. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization. Superheated or saturated steam is invisible; however, wet steam, a visible mist or aerosol of water droplets, is often referred to as "steam".

When liquid water becomes steam, it increases in volume by 1,700 times at standard temperature and pressure; this change in volume can be converted into mechanical work by steam engines such as reciprocating piston type engines and steam turbines. Piston-type steam engines played a central role in the Industrial Revolution and steam-based generation produces 80 percent of the world's electricity. If liquid water comes in contact with a very hot surface or depressurizes quickly below its vapor pressure, it can create a steam explosion.

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Vapor pressure in the context of Boiling point

The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor.

The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum, i.e., under a lower pressure, has a lower boiling point than when that liquid is at atmospheric pressure. Because of this, water boils at 100°C (or with scientific precision: 99.97 °C (211.95 °F)) under standard pressure at sea level, but at 93.4 °C (200.1 °F) at 1,905 metres (6,250 ft) altitude. For a given pressure, different liquids will boil at different temperatures.

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Vapor pressure in the context of Tundra climate

The tundra climate is a polar climate sub-type located in high latitudes and high mountains. It is classified as ET according to the Köppen climate classification. It is a climate which at least one month has an average temperature high enough to melt snow (0 °C [32 °F]), but no month with an average temperature in excess of 10 °C (50 °F). If the climate occurs at high elevations, it is known as alpine climate.

Despite the potential diversity of climates in the ET category involving precipitation, extreme temperatures, and relative wet and dry seasons, this category is rarely subdivided. Rainfall and snowfall are generally slight due to the low vapor pressure of water in the chilly atmosphere, but as a rule potential evapotranspiration is extremely low, allowing soggy terrain of swamps and bogs even in places that get precipitation typical of deserts of lower and middle latitudes. The amount of native tundra biomass depends more on the local temperature than the amount of precipitation.

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Vapor pressure in the context of John Dalton

John Dalton FRS (/ˈdɔːltən/; 5 or 6 September 1766 – 27 July 1844) was an English chemist, physicist, and meteorologist whose work laid the foundations of modern atomic theory and stoichiometric chemistry. Building on earlier ideas about the indivisibility of matter and his own precise measurements of combining ratios, Dalton proposed that each chemical element consists of identical atoms of characteristic weight, and that compounds are formed when atoms of different elements combine in fixed whole-number proportions. His A New System of Chemical Philosophy (1808) presented a coherent atomic model, supplied relative atomic weights and symbolic notation, and established the quantitative framework that shaped nineteenth-century chemistry and remains the basis of modern chemical thought.

Dalton was also a pioneering meteorologist and physicist, keeping daily weather observations for over fifty years, formulating the first empirical law of partial pressures (later known as Dalton’s Law), and studying the behavior of gases through his work on vapor pressure and gas solubility. His investigations into his own color blindness led to the first scientific description of the condition—still called Daltonism in several languages—and helped establish experimental methods for linking perception with physiology. Elected a Fellow of the Royal Society in 1822 and awarded its Royal Medal in 1826, Dalton became the first British scientist to develop a quantitative atomic theory and one of the key figures in the transition of chemistry from a qualitative to a mathematical science.

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Vapor pressure in the context of Combustibility and flammability

A combustible material is a material that can burn (i.e., sustain a flame) in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.

The degree of flammability in air depends largely upon the volatility of the material – this is related to its composition-specific vapor pressure, which is temperature dependent. The quantity of vapor produced can be enhanced by increasing the surface area of the material forming a mist or dust. Take wood as an example. Finely divided wood dust can undergo explosive flames and produce a blast wave. A piece of paper (made from pulp) catches on fire quite easily. A heavy oak desk is much harder to ignite, even though the wood fibre is the same in all three materials.

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Vapor pressure in the context of Lambda point

The lambda point is the temperature at which normal fluid helium (helium I) makes the transition to superfluid state (helium II). At pressure of 1 atmosphere, the transition occurs at approximately 2.17 K. The lowest pressure at which He-I and He-II can coexist is the vapor−He-I−He-II triple point at 2.1768 K (−270.9732 °C) and 5.0418 kPa (0.049759 atm), which is the "saturated vapor pressure" at that temperature (pure helium gas in thermal equilibrium over the liquid surface, in a hermetic container). The highest pressure at which He-I and He-II can coexist is the bcc−He-I−He-II triple point with a helium solid at 1.762 K (−271.388 °C), 29.725 atm (3,011.9 kPa).

The point's name derives from the graph (pictured) that results from plotting the specific heat capacity as a function of temperature (for a given pressure in the above range, in the example shown, at 1 atmosphere), which resembles the Greek letter lambda . The specific heat capacity has a sharp peak as the temperature approaches the lambda point. The tip of the peak is so sharp that a critical exponent characterizing the divergence of the heat capacity can be measured precisely only in zero gravity, to provide a uniform density over a substantial volume of fluid. Hence, the heat capacity was measured within 2 nK below the transition in an experiment included in a Space Shuttle payload in 1992.

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Vapor pressure in the context of Volatile organic compound

Volatile organic compounds (VOCs) are organic compounds that have a high vapor pressure at room temperature. They are common and exist in a variety of settings and products, not limited to house mold, upholstered furniture, arts and crafts supplies, dry cleaned clothing, and cleaning supplies. VOCs are responsible for the odor of scents and perfumes as well as pollutants. They play an important role in communication between animals and plants, such as attractants for pollinators, protection from predation, and even inter-plant interactions. Some VOCs are dangerous to human health or cause harm to the environment, often despite the odor being perceived as pleasant, such as "new car smell".

Anthropogenic VOCs are regulated by law, especially indoors, where concentrations are the highest. Most VOCs are not acutely toxic, but may have long-term chronic health effects. Some VOCs have been used in pharmaceutical settings, while others are the target of administrative controls because of their recreational use. The high vapor pressure of VOCs correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a trait known as volatility.

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