Lambda point in the context of "Vapor pressure"

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⭐ Core Definition: Lambda point

The lambda point is the temperature at which normal fluid helium (helium I) makes the transition to superfluid state (helium II). At pressure of 1 atmosphere, the transition occurs at approximately 2.17 K. The lowest pressure at which He-I and He-II can coexist is the vapor−He-I−He-II triple point at 2.1768 K (−270.9732 °C) and 5.0418 kPa (0.049759 atm), which is the "saturated vapor pressure" at that temperature (pure helium gas in thermal equilibrium over the liquid surface, in a hermetic container). The highest pressure at which He-I and He-II can coexist is the bcc−He-I−He-II triple point with a helium solid at 1.762 K (−271.388 °C), 29.725 atm (3,011.9 kPa).

The point's name derives from the graph (pictured) that results from plotting the specific heat capacity as a function of temperature (for a given pressure in the above range, in the example shown, at 1 atmosphere), which resembles the Greek letter lambda . The specific heat capacity has a sharp peak as the temperature approaches the lambda point. The tip of the peak is so sharp that a critical exponent characterizing the divergence of the heat capacity can be measured precisely only in zero gravity, to provide a uniform density over a substantial volume of fluid. Hence, the heat capacity was measured within 2 nK below the transition in an experiment included in a Space Shuttle payload in 1992.

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Lambda point in the context of Triple point

In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. It is that temperature and pressure at which the sublimation, fusion, and vapourisation curves meet. For example, the triple point of mercury occurs at a temperature of −38.8 °C (−37.8 °F) and a pressure of 0.165 mPa.

In addition to the triple point for solid, liquid, and gas phases, a triple point may involve more than one solid phase, for substances with multiple polymorphs. Helium-4 is unusual in that it has no sublimation/deposition curve and therefore no triple points where its solid phase meets its gas phase. Instead, it has a vapor-liquid-superfluid point, a solid-liquid-superfluid point, a solid-solid-liquid point, and a solid-solid-superfluid point. None of these should be confused with the lambda point, which is not any kind of triple point.

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Lambda point in the context of Zero-point energy

Zero-point energy (ZPE) is the lowest possible energy that a quantum mechanical system may have. Unlike in classical mechanics, quantum systems constantly fluctuate in their lowest energy state as described by the Heisenberg uncertainty principle. Therefore, even at absolute zero, atoms and molecules retain some vibrational motion. Apart from atoms and molecules, the empty space of the vacuum also has these properties. According to quantum field theory, the universe can be thought of not as isolated particles but continuous fluctuating fields: matter fields, whose quanta are fermions (i.e., leptons and quarks), and force fields, whose quanta are bosons (e.g., photons and gluons). All these fields have zero-point energy. These fluctuating zero-point fields lead to a kind of reintroduction of an aether in physics since some systems can detect the existence of this energy. However, this aether cannot be thought of as a physical medium if it is to be Lorentz invariant such that there is no contradiction with Albert Einstein's theory of special relativity.

The notion of a zero-point energy is also important for cosmology, and physics currently lacks a full theoretical model for understanding zero-point energy in this context; in particular, the discrepancy between theorized and observed vacuum energy in the universe is a source of major contention. Yet according to Einstein's theory of general relativity, any such energy would gravitate, and the experimental evidence from the expansion of the universe, dark energy and the Casimir effect shows any such energy to be exceptionally weak. One proposal that attempts to address this issue is to say that the fermion field has a negative zero-point energy, while the boson field has positive zero-point energy and thus these energies somehow cancel out each other. This idea would be true if supersymmetry were an exact symmetry of nature; however, the Large Hadron Collider at CERN has so far found no evidence to support it. Moreover, it is known that if supersymmetry is valid at all, it is at most a broken symmetry, only true at very high energies, and no one has been able to show a theory where zero-point cancellations occur in the low-energy universe we observe today. This discrepancy is known as the cosmological constant problem and it is one of the greatest unsolved mysteries in physics. Many physicists believe that "the vacuum holds the key to a full understanding of nature".

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