Vacuum ultraviolet in the context of "Ionizing radiation"

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⭐ Core Definition: Vacuum ultraviolet

Ultraviolet radiation or UV is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs, Cherenkov radiation, and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights.

The photons of ultraviolet have greater energy than those of visible light, from about 3.1 to 12 electron volts, around the minimum energy required to ionize atoms. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack sufficient energy, it can induce chemical reactions and cause many substances to glow or fluoresce. Many practical applications, including chemical and biological effects, are derived from the way that UV radiation can interact with organic molecules. These interactions can involve exciting orbital electrons to higher energy states in molecules potentially breaking chemical bonds. In contrast, the main effect of longer wavelength radiation is to excite vibrational or rotational states of these molecules, increasing their temperature. Short-wave ultraviolet light is ionizing radiation. Consequently, short-wave UV damages DNA and sterilizes surfaces with which it comes into contact.

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👉 Vacuum ultraviolet in the context of Ionizing radiation

Ionizing radiation, also spelled ionising radiation, consists of subatomic particles or electromagnetic waves that have enough energy per individual photon or particle to ionize atoms or molecules by detaching electrons from them. Some particles can travel up to 99% of the speed of light, and the electromagnetic waves are on the high-energy portion of the electromagnetic spectrum.

Gamma rays, X-rays, and the higher energy ultraviolet part of the electromagnetic spectrum are ionizing radiation; whereas the lower energy ultraviolet, visible light, infrared, microwaves, and radio waves are non-ionizing radiation. Nearly all types of laser light are non-ionizing radiation. The boundary between ionizing and non-ionizing radiation in the ultraviolet area cannot be sharply defined, as different molecules and atoms ionize at different energies. The energy of ionizing radiation starts around 10 electronvolts (eV).

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Vacuum ultraviolet in the context of Electromagnetic absorption by water

The absorption of electromagnetic radiation by water depends on the state of the water.

The absorption in the gas phase occurs in three regions of the spectrum. Rotational transitions are responsible for absorption in the microwave and far-infrared, vibrational transitions in the mid-infrared and near-infrared. Vibrational bands have rotational fine structure. Electronic transitions occur in the vacuum ultraviolet regions.

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Vacuum ultraviolet in the context of Photodissociation

Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light (photons). It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments.

Here, “light” is broadly defined as radiation spanning the vacuum ultraviolet (VUV), ultraviolet (UV), visible, and infrared (IR) regions of the electromagnetic spectrum. To break covalent bonds, photon energies corresponding to visible, UV, or VUV light are typically required, whereas IR photons may be sufficiently energetic to detach ligands from coordination complexes or to fragment supramolecular complexes.

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