Uranium-238 in the context of "Alpha decay"

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⭐ Core Definition: Uranium-238

Uranium-238 (
U
or U-238) is the most common isotope of uranium found in nature, with a relative abundance above 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.

The isotope has a half-life of 4.463 billion years (1.408×10 s). Due to its abundance and half-life relative rate of decay to other radioactive elements, U is responsible for about 40% of the radioactive heat produced within the Earth. The U decay chain contributes six electron anti-neutrinos per U nucleus (one per beta decay), resulting in a large detectable geoneutrino signal when decays occur within the Earth. The decay of U to daughter isotopes is extensively used in radiometric dating, particularly for material older than approximately 1 million years.

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In this Dossier

Uranium-238 in the context of Alpha radiation

Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. For example, uranium-238 undergoes alpha decay to form thorium-234.

While alpha particles have a charge +2 e, this is not usually shown because a nuclear equation describes a nuclear reaction without considering the electrons – a convention that does not imply that the nuclei necessarily occur in neutral atoms.

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Uranium-238 in the context of Uranium

Uranium is a chemical element; it has symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.

Many contemporary uses of uranium exploit its unique nuclear properties. Uranium is used in nuclear power plants and nuclear weapons because it is the only naturally occurring element with a fissile isotope – uranium-235 – present in non-trace amounts. However, because of the low abundance of uranium-235 in natural uranium (which is overwhelmingly uranium-238), uranium needs to undergo enrichment so that enough uranium-235 is present. Uranium-238 is fissionable by fast neutrons and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is studied for future industrial use in nuclear technology. Uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons; uranium-235, and to a lesser degree uranium-233, have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors and produces the fissile material for nuclear weapons. The primary civilian use for uranium harnesses the heat energy to produce electricity. Depleted uranium (U) is used in kinetic energy penetrators and armor plating.

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Uranium-238 in the context of Radon

Radon is a chemical element; it has symbol Rn and atomic number 86. It is a radioactive noble gas and is colorless and odorless. Of the three naturally occurring radon isotopes, only Rn has a sufficiently long half-life (3.825 days) for it to be released from the soil and rock where it is generated. Radon isotopes are the immediate decay products of radium isotopes.

The instability of Rn, its most stable isotope, makes radon one of the rarest elements. Radon will be present on Earth for several billion more years despite its short half-life, because it is constantly being produced as a step in the decay chains of U and Th, both of which are abundant radioactive nuclides with half-lives of at least several billion years. The decay of radon produces many other short-lived nuclides, known as "radon daughters", ending at stable isotopes of lead. Rn occurs in significant quantities as a step in the normal radioactive decay chain of U, also known as the uranium series, which slowly decays into a variety of radioactive nuclides and eventually decays into stable Pb. Rn occurs in minute quantities as an intermediate step in the decay chain of Th, also known as the thorium series, which eventually decays into stable Pb.

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Uranium-238 in the context of Daughter product

In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps (decay chain). For example, U decays to Th which decays to Pa which decays, and so on, to Pb (which is stable):

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Uranium-238 in the context of Enriched uranium

Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (U with 99.2732–99.2752% natural abundance), uranium-235 (U, 0.7198–0.7210%), and uranium-234 (U, 0.0049–0.0059%). U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons.

Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. Low-enriched uranium (below 20% U) is necessary to operate light water reactors, which make up almost 90% of nuclear electricity generation. Highly enriched uranium (above 20% U) is used for the cores of many nuclear weapons, as well as compact reactors for naval propulsion and research, as well as breeder reactors. There are about 2,000 tonnes of highly enriched uranium in the world.

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Uranium-238 in the context of Plutonium

Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune, element 94 was named after Pluto, which at the time was also considered a planet. Wartime secrecy prevented the University of California team from publishing its discovery until 1948.

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Uranium-238 in the context of Nuclear chain reaction

In nuclear physics, a nuclear chain reaction occurs when one single nuclear reaction causes an average of one or more subsequent nuclear reactions, thus leading to the possibility of a self-propagating series or "positive feedback loop" of these reactions. The specific nuclear reaction may be the fission of heavy isotopes (e.g., uranium-235, U). A nuclear chain reaction releases several million times more energy per reaction than any chemical reaction.

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Uranium-238 in the context of Fast reactor

A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV, on average), as opposed to slow thermal neutrons used in thermal-neutron reactors. Such a fast reactor needs no neutron moderator, but requires fuel that is comparatively rich in fissile material.

The fast spectrum is key to breeder reactors, which convert highly abundant uranium-238 into fissile plutonium-239, without requiring enrichment. It also leads to high burnup: many transuranic isotopes, such as of americium and curium, accumulate in thermal reactor spent fuel; in fast reactors they undergo fast fission, reducing total nuclear waste. As a strong fast-spectrum neutron source, they can also be used to transmute existing nuclear waste into manageable or non-radioactive isotopes.

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