In physics, the S-matrix or scattering matrix is a matrix that relates the initial state and the final state of a physical system undergoing a scattering process. It is used in quantum mechanics, scattering theory and quantum field theory (QFT).
More formally, in the context of QFT, the S-matrix is defined as the unitary matrix connecting sets of asymptotically free particle states (the in-states and the out-states) in the Hilbert space of physical states: a multi-particle state is said to be free (or non-interacting) if it transforms under Lorentz transformations as a tensor product, or direct product in physics parlance, of one-particle states as prescribed by equation (1) below. Asymptotically free then means that the state has this appearance in either the distant past or the distant future.
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