Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, the crystalline forms of silica (SiO2) are usually considered to be tectosilicates, and they are classified as such in the Dana system (75.1). However, the Nickel-Strunz system classifies them as oxide minerals (4.DA). Silica is found in nature as the mineral quartz and its polymorphs.
Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula Na2Al2Si3O10·2H2O. The type locality is Hohentwiel, Hegau, Germany.
It was named natrolite by Martin Heinrich Klaproth in 1803. The name is derived from natron (νατρών), the Greek word for soda, in reference to the sodium content, and lithos (λίθος), meaning stone. Needle stone or needle-zeolite are other informal names, alluding to the common acicular habit of the crystals, which are often very slender and are aggregated in divergent tufts. The crystals are frequently epitaxial overgrowths of natrolite, mesolite, and gonnardite in various orders.
Analcime (/əˈnælsiːm, -saɪm/; from Ancient Greek ἀνάλκιμος (análkimos) 'not strong') or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is NaAlSi2O6 · H2O. Minor amounts of potassium and calcium substitute for sodium. A silver-bearing synthetic variety also exists (Ag-analcite).
Analcime is usually classified as a zeolite mineral, but structurally and chemically it is more similar to the feldspathoids. Analcime is not classified as an isometric crystal, as although the crystal structure appears to be isometric, it is usually off only by a fraction of an angle. However, there are truly isometric samples of the mineral, which makes its classification even more difficult. Due to the differences between the samples being too slight, there's no merit from having multiple species names, so as a result analcime is a common example for minerals occurring in multiple crystal systems and space groups.
Sodalite (/ˈsoʊ.dəˌlaɪt/ SOH-də-lyte) is a tectosilicate mineral with the formula Na
8(Al
6Si
6O
24)Cl
2, with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of the sodalite group with hauyne, nosean, lazurite and tugtupite.
The people of the Caral culture traded for sodalite from the Collao altiplano. First discovered by Europeans in 1811 in the Ilimaussaq intrusive complex in Greenland, sodalite did not become widely important as an ornamental stone until 1891 when vast deposits of fine material were discovered in Ontario, Canada.
Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula (Na,K,Ca)
2–3Al
3(Al,Si)
2Si
13O
36•12H
2O. It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2. It commonly occurs as a devitrification product of volcanic glass shards in tuff and as vesicle fillings in basalts, andesites and rhyolites. It was described in 1969 from an occurrence in the Barstow Formation, San Bernardino County, California. Sodium levels in clinoptilolite are generally higher than potassium levels, as is the case with the San Bernardino Barstow Formation, but there are sources that are potassium-rich and have minimal sodium.
It forms a series with heulandite:
Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline has cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.
The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555.
Mesolite is a tectosilicate mineral with formula Na2Ca2Si9Al6O30·8H2O. It is a member of the zeolite group and the natrolite subgroup, also resembling natrolite in appearance.
Mesolite crystallizes in the orthorhombic system and typically forms fibrous, acicular prismatic crystals or masses. Radiating sprays of needlelike crystals are not uncommon. It is vitreous in luster and clear to white in color. It has a Mohs hardness of 5 to 5.5 and a low specific gravity of 2.2 to 2.4. The refractive indices are nα=1.505 nβ=1.505 nγ=1.506.