Technetium in the context of "Noble metals"

A noble metal is a metallic chemical element that is resistant to corrosion and is usually found in nature in its raw form. Gold, platinum, and the other platinum group metals (ruthenium, rhodium, palladium, osmium, iridium) are most often so classified. Silver, copper, and mercury are sometimes included as noble metals, but each of these usually occurs in nature combined with sulfur.

In more specialized fields of study and applications, the number of elements counted as noble metals can vary. In some contexts, the term is used only for copper, silver, and gold which have filled d-bands. In others, it is applied more broadly to any metallic or semimetallic element that does not react with a weak acid and give off hydrogen gas in the process. This broader set includes copper, mercury, technetium, rhenium, arsenic, antimony, bismuth, polonium, gold, the six platinum group metals, and silver.

Rhenium is a chemical element; it has symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is one of the rarest elements in the Earth's crust. It has one of the highest melting and boiling points of any element. It resembles manganese and technetium chemically and is mainly obtained as a by-product of the extraction and refinement of molybdenum and copper ores. It shows in its compounds a wide variety of oxidation states ranging from −3 to +7.

Rhenium was originally discovered in 1908 by Masataka Ogawa, but he mistakenly assigned it as element 43 (now known as technetium) rather than element 75 and named it nipponium. It was rediscovered in 1925 by Walter Noddack, Ida Tacke and Otto Berg, who gave it its present name. It was named after the river Rhine in Europe, from which the earliest samples had been obtained and worked commercially.

Group 7, numbered by IUPAC nomenclature, is a group of elements in the periodic table. It contains manganese (Mn), technetium (Tc), rhenium (Re) and bohrium (Bh). This group lies in the d-block of the periodic table, and are hence transition metals. This group is sometimes called the manganese group or manganese family after its lightest member; however, the group itself has not acquired a trivial name because it belongs to the broader grouping of the transition metals.

The group 7 elements tend to have a major group oxidation state (+7), although this trend is markedly less coherent than the previous groups. Like other groups, the members of this family show patterns in their electron configurations, especially the outermost shells resulting in trends in chemical behavior. In nature, manganese is a fairly common element, whereas rhenium is rare, technetium only occurs in trace quantities, and bohrium is entirely synthetic.

Masataka Ogawa (小川 正孝, Ogawa Masataka; 21 February 1865 – 11 July 1930) was a Japanese chemist mainly known for the claimed discovery of element 43 (later known as technetium), which he named nipponium. In fact, he had discovered, but misidentified, element 75 (later called rhenium).

After graduating from the University of Tokyo, he studied under William Ramsay in London, where he worked on the analysis of the rare mineral thorianite. He extracted and isolated a small amount of an apparently unknown substance from the mineral, which he announced as the discovery of element 43, naming the newly discovered element nipponium. He published his results in 1909 and a notice was also published in the Journal of the American Chemical Society. For this work, he was awarded a doctorate and the highest prize of the Tokyo Chemical Society. However, no other researchers were able to replicate his discovery, and the announcement was forgotten.

Walter Noddack (17 August 1893 – 7 December 1960) was a German chemist. He, Ida Tacke (who later married Noddack), and Otto Berg reported the discovery of element 43 and element 75 in 1925.

A quadruple bond is a type of chemical bond between two atoms involving eight electrons. This bond is an extension of the more familiar types of covalent bonds: double bonds and triple bonds. Stable quadruple bonds are most common among the transition metals in the middle of the d-block, such as rhenium, tungsten, technetium, molybdenum and chromium. Typically the ligands that support quadruple bonds are π-donors, not π-acceptors. Quadruple bonds are rare as compared to double bonds and triple bonds, but hundreds of compounds with such bonds have been prepared.