Sulfur dioxide in the context of "Smelted"

Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead, and zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil-fuel source of carbon, such as carbon monoxide from incomplete combustion of coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures, as the chemical potential energy of the bonds in carbon dioxide (CO₂) is lower than that of the bonds in the ore.

Sulfide ores such as those commonly used to obtain copper, zinc, or lead, are roasted before smelting in order to convert the sulfides to oxides, which are more readily reduced to the metal. Roasting heats the ore in the presence of oxygen from air, oxidizing the ore and liberating the sulfur as sulfur dioxide gas.

A volcanic winter is a reduction in global temperatures caused by droplets of sulfuric acid obscuring the Sun and raising Earth's albedo (increasing the reflection of solar radiation) after a large, sulfur-rich, particularly explosive volcanic eruption. Climate effects are primarily dependent upon the amount of injection of SO₂ and H₂S into the stratosphere where they react with OH and H₂O to form H₂SO₄ on a timescale of a week, and the resulting H₂SO₄ aerosols produce the dominant radiative effect. Volcanic stratospheric aerosols cool the surface by reflecting solar radiation and warm the stratosphere by absorbing terrestrial radiation for several years. Moreover, the cooling trend can be further extended by atmosphere–ice–ocean feedback mechanisms. These feedbacks can continue to maintain the cool climate long after the volcanic aerosols have dissipated.

Haze is traditionally an atmospheric phenomenon in which dust, smoke, and other dry particulates suspended in air obscure visibility and the clarity of the sky. The World Meteorological Organization manual of codes includes a classification of particulates causing horizontal obscuration into categories of fog, ice fog, steam fog, mist, haze, smoke, volcanic ash, dust, sand, and snow. Sources for particles that cause haze include farming (stubble burning, ploughing in dry weather), traffic, industry, windy weather, volcanic activity and wildfires.Seen from afar (e.g. an approaching airplane) and depending on the direction of view with respect to the Sun, haze may appear brownish or bluish, while mist tends to be bluish grey instead. Whereas haze often is considered a phenomenon occurring in dry air, mist formation is a phenomenon in saturated, humid air. However, haze particles may act as condensation nuclei that leads to the subsequent vapor condensation and formation of mist droplets; such forms of haze are known as "wet haze".

In meteorological literature, the word haze is generally used to denote visibility-reducing aerosols of the wet type suspended in the atmosphere. Such aerosols commonly arise from complex chemical reactions that occur as sulfur dioxide gases emitted during combustion are converted into small droplets of sulfuric acid when exposed. The reactions are enhanced in the presence of sunlight, high relative humidity, and an absence of air flow (wind). A small component of wet-haze aerosols appear to be derived from compounds released by trees when burning, such as terpenes. For all these reasons, wet haze tends to be primarily a warm-season phenomenon. Large areas of haze covering many thousands of kilometers may be produced under extensive favorable conditions each summer.

The Permian–Triassic extinction event, colloquially known as the Great Dying, was an extinction event that occurred approximately 251.9 million years ago (mya), at the boundary between the Permian and Triassic geologic periods, and with them the Paleozoic and Mesozoic eras. It is Earth's most severe known extinction event, with the extinction of 57% of biological families, 62% of genera, 81% of marine species, and 70% of terrestrial vertebrate species. It is also the greatest known mass extinction of insects. It is the greatest of the "Big Five" mass extinctions of the Phanerozoic. There is evidence for one to three distinct pulses, or phases, of extinction.

The scientific consensus is that the main cause of the extinction was the flood basalt volcanic eruptions that created the Siberian Traps, which released sulfur dioxide and carbon dioxide, resulting in euxinia (oxygen-starved, sulfurous oceans), elevated global temperatures,and acidified oceans.The level of atmospheric carbon dioxide rose from around 400 ppm to 2,500 ppm with approximately 3,900 to 12,000 gigatonnes of carbon being added to the ocean-atmosphere system during this period.

Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances.

On planet Earth, the term 'volatiles' often refers to the volatile components of magma. In astrogeology volatiles are investigated in the crust or atmosphere of a planet or moon. Volatiles include hydrogen, nitrogen, oxygen, water, ammonia, methane, carbon dioxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, phosphine, halogens, noble gases and others.

Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.

These fuels are intended to substitute for more carbon intensive energy sources like gasoline and diesel in transportation and can help to contribute to decarbonization and reductions in pollution. Alternative fuel is also shown to reduce non-carbon emissions such as the release of nitric oxide and nitrogen dioxide, as well as sulfur dioxide and other harmful gases in the exhaust. This is especially important in industries such as mining, where toxic gases can accumulate more easily.

Smog, or smoke fog, is a type of intense air pollution. The word "smog" was coined in the early 20th century, and is a portmanteau of the words smoke and fog to refer to smoky fog due to its opacity, and odour. The word was then intended to refer to what was sometimes known as pea soup fog, a familiar and serious problem in London from the 19th century to the mid-20th century, where it was commonly known as a London particular or London fog. This kind of visible air pollution is composed of nitrogen oxides, sulfur oxide, ozone, smoke and other particulates. Man-made smog is derived from coal combustion emissions, vehicular emissions, industrial emissions, forest and agricultural fires and photochemical reactions of these emissions.

Smog is often categorized as being either summer smog or winter smog. Summer smog is primarily associated with the photochemical formation of ozone. During the summer season when the temperatures are warmer and there is more sunlight present, photochemical smog is the dominant type of smog formation. During the winter months when the temperatures are colder, and atmospheric inversions are common, there is an increase in coal and other fossil fuel usage to heat homes and buildings. These combustion emissions, together with the lack of pollutant dispersion under inversions, characterize winter smog formation. Smog formation in general relies on both primary and secondary pollutants. Primary pollutants are emitted directly from a source, such as emissions of sulfur dioxide from coal combustion. Secondary pollutants, such as ozone, are formed when primary pollutants undergo chemical reactions in the atmosphere.

Roasting is a process of heating an ore under flowing air. It is a step in the processing of certain ores. More specifically, roasting is often a metallurgical process involving gas–solid reactions at elevated temperatures with the goal of purifying the metal component(s). Often before roasting, the ore has already been partially purified, e.g. by froth flotation. The concentrate is mixed with other materials to facilitate the process. The technology is useful in making certain ores usable but it can also be a serious source of air pollution.

Roasting consists of thermal gas–solid reactions, which can include oxidation, reduction, chlorination, sulfation, and pyrohydrolysis. In roasting, the ore or ore concentrate is treated with very hot air. This process is generally applied to sulfide minerals. During roasting, the sulfide is converted to an oxide, and sulfur is released as sulfur dioxide, a gas. For the ores Cu₂S (chalcocite) and ZnS (sphalerite), balanced equations for the roasting are: