Sulfide in the context of "Potassium sulfide"

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Bismuth was formerly understood to be the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was found to be very slightly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-life roughly a billion times longer than the estimated age of the universe.

Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO₄. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO₄·2H₂O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.

Troctolite /ˈtrɒktəlaɪt/ (from Greek τρώκτης 'trout' and λίθος 'stone') is a mafic intrusive rock type. It consists essentially of major but variable amounts of olivine and calcic plagioclase along with minor pyroxene. It is an olivine-rich anorthosite, or a pyroxene-depleted relative of gabbro. However, unlike gabbro, no troctolite corresponds in composition to a partial melt of peridotite. Thus, troctolite is necessarily a cumulate of crystals that have fractionated from melt.

Troctolite is found in some layered intrusions such as in the Archean Windimurra intrusion of Western Australia, the Voisey's Bay nickel-copper-cobalt magmatic sulfide deposit of northern Labrador, the Stillwater igneous complex of Montana, the Duluth Complex of the North American Midcontinent Rift, and the Tertiary Rhum layered intrusion of the island of Rùm, Scotland. Troctolite is also found, for example, in the Merensky Reef of the Bushveld Igneous Complex, South Africa and in the Lizard complex in Cornwall.

Lead(II) sulfide (also spelled sulphide) is an inorganic compound with the formula PbS. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses.

The sulfide minerals are a class of minerals containing sulfide (S) or disulfide (S2−2) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts. Sulfide minerals are inorganic compounds.

Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work.

Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula FeO, whereas the more common material is nonstoichiometric, with the formula Fe_0.95O. The type of equilibrium defects in non-stoichiometric compounds can vary with attendant variation in bulk properties of the material. Non-stoichiometric compounds also exhibit special electrical or chemical properties because of the defects; for example, when atoms are missing, electrons can move through the solid more rapidly. Non-stoichiometric compounds have applications in ceramic and superconductive material and in electrochemical (i.e., battery) system designs.

The sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes.Steps of the sulfur cycle are:

• Mineralization of organic sulfur into inorganic forms, such as hydrogen sulfide (H₂S), elemental sulfur, as well as sulfide minerals.
• Oxidation of hydrogen sulfide, sulfide, and elemental sulfur (S) to sulfate (SO
  ₄).
• Reduction of sulfate to sulfide.
• Incorporation of sulfide into organic compounds (including metal-containing derivatives).
• Disproportionation of sulfur compounds (elemental sulfur, sulfite, thiosulfate) into sulfate and hydrogen sulfide.