Spin quantum number in the context of "Bosons"

In particle physics, a boson (/ˈboʊzɒn/ /ˈboʊsɒn/) is a subatomic particle whose spin quantum number has an integer value (0, 1, 2, ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have half odd-integer spin (1/2, 3/2, 5/2, ...). Every observed subatomic particle is either a boson or a fermion. Paul Dirac coined the name boson to commemorate the contribution of Satyendra Nath Bose, an Indian physicist.

Some bosons are elementary particles occupying a special role in particle physics, distinct from the role of fermions (which are sometimes described as the constituents of "ordinary matter"). Certain elementary bosons (e.g. gluons) act as force carriers, which give rise to forces between other particles, while one (the Higgs boson) contributes to the phenomenon of mass. Other bosons, such as mesons, are composite particles made up of smaller constituents.

In quantum mechanics, the Pauli exclusion principle (German: Pauli-Ausschlussprinzip) states that two or more identical particles with half-integer spins (i.e. fermions) cannot simultaneously occupy the same quantum state within a system that obeys the laws of quantum mechanics. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925 for electrons, and later extended to all fermions with his spin–statistics theorem of 1940.

In the case of electrons in atoms, the exclusion principle can be stated as follows: in a poly-electron atom it is impossible for any two electrons to have the same two values of all four of their quantum numbers, which are: n, the principal quantum number; ℓ, the azimuthal quantum number; m_ℓ, the magnetic quantum number; and m_s, the spin quantum number. For example, if two electrons reside in the same orbital, then their values of n, ℓ, and m_ℓ are equal. In that case, the two values of m_s (spin) pair must be different. Since the only two possible values for the spin projection m_s are +1/2 and −1/2, it follows that one electron must have m_s = +1/2 and one m_s = −1/2.

In quantum mechanics, the azimuthal quantum number ℓ is a quantum number for an atomic orbital that determines its orbital angular momentum and describes aspects of the angular shape of the orbital. The azimuthal quantum number is the second of a set of quantum numbers that describe the unique quantum state of an electron (the others being the principal quantum number n, the magnetic quantum number m_ℓ, and the spin quantum number m_s).

For a given value of the principal quantum number n (electron shell), the possible values of ℓ are the integers from 0 to n − 1. For instance, the n = 1 shell has only orbitals with ${\displaystyle \ell =0}$, and the n = 2 shell has only orbitals with ${\displaystyle \ell =0}$, and ${\displaystyle \ell =1}$.

In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system. To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantum numbers includes the principal, azimuthal, magnetic, and spin quantum numbers. To describe other systems, different quantum numbers are required. For subatomic particles, one needs to introduce new quantum numbers, such as the flavour of quarks, which have no classical correspondence.

Quantum numbers are closely related to eigenvalues of observables. When the corresponding observable commutes with the Hamiltonian of the system, the quantum number is said to be "good", and acts as a constant of motion in the quantum dynamics.

In atomic physics, a magnetic quantum number is a quantum number used to distinguish quantum states of an electron or other particle according to its angular momentum along a given axis in space. The orbital magnetic quantum number (m_l or m) distinguishes the orbitals available within a given subshell of an atom. It specifies the component of the orbital angular momentum that lies along a given axis, conventionally called the z-axis, so it describes the orientation of the orbital in space. The spin magnetic quantum number m_s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1⁄2, and m_s is either +1⁄2 or −1⁄2, often called "spin-up" and "spin-down", or α and β. The term magnetic in the name refers to the magnetic dipole moment associated with each type of angular momentum, so states having different magnetic quantum numbers shift in energy in a magnetic field according to the Zeeman effect.

The four quantum numbers conventionally used to describe the quantum state of an electron in an atom are the principal quantum number n, the azimuthal (orbital) quantum number ${\displaystyle \ell }$, and the magnetic quantum numbers m_l and m_s. Electrons in a given subshell of an atom (such as s, p, d, or f) are defined by values of ${\displaystyle \ell }$ (0, 1, 2, or 3). The orbital magnetic quantum number takes integer values in the range from ${\displaystyle -\ell }$ to ${\displaystyle +\ell }$, including zero. Thus the s, p, d, and f subshells contain 1, 3, 5, and 7 orbitals each. Each of these orbitals can accommodate up to two electrons (with opposite spins), forming the basis of the periodic table.

In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he published in 1916.

Because electrons are fermions, the Pauli exclusion principle forbids these particles from having all the same quantum numbers. Therefore, for two electrons to occupy the same orbital, and thereby have the same orbital quantum number, they must have different spin quantum numbers. This also limits the number of electrons in the same orbital to two.

Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. High-resolution nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. NMR is also routinely used in advanced medical imaging techniques, such as in magnetic resonance imaging (MRI). The original application of NMR to condensed matter physics is nowadays mostly devoted to strongly correlated electron systems. It reveals large many-body couplings by fast broadband detection and should not be confused with solid state NMR, which aims at removing the effect of the same couplings by Magic Angle Spinning techniques.

The most commonly used nuclei are
H and
C, although isotopes of many other elements, such as
F,
P, and
Si, can be studied by high-field NMR spectroscopy as well. In order to interact with the magnetic field in the spectrometer, the nucleus must have an intrinsic angular momentum and nuclear magnetic dipole moment. This occurs when an isotope has a nonzero nuclear spin, meaning an odd number of protons and/or neutrons (see Isotope). Nuclides with even numbers of both have a total spin of zero and are therefore not NMR-active.