Silver halide in the context of "Photographic film"

⭐ In the context of photographic film, silver halide crystals are primarily responsible for which aspect of the photographic process?

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⭐ Core Definition: Silver halide

A silver halide (or silver salt) is one of the chemical compounds that can form between the element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine with silver to produce silver bromide (AgBr), silver chloride (AgCl), silver iodide (AgI), and four forms of silver fluoride, respectively.

As a group, they are often referred to as the silver halides, and are often given the pseudo-chemical notation AgX. Although most silver halides involve silver atoms with oxidation states of +1 (Ag), silver halides in which the silver atoms have oxidation states of +2 (Ag) are known, of which silver(II) fluoride is the only known stable one.

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👉 Silver halide in the context of Photographic film

Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film. Film is typically segmented in frames, that give rise to separate photographs.

The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically developed into a visible photograph. In addition to visible light, most films are sensitive to ultraviolet light, X-rays, gamma rays, and high-energy particles. Unmodified silver halide crystals are sensitive only to the blue part of the visible spectrum, producing unnatural-looking renditions of some colored subjects. This problem was resolved with the discovery that certain dyes, called sensitizing dyes, when adsorbed onto the silver halide crystals made them respond to other colors as well. First orthochromatic (sensitive to blue and green) and finally panchromatic (sensitive to all visible colors) films were developed. Panchromatic film renders all colors in shades of gray approximately matching their subjective brightness. By similar techniques, special-purpose films can be made sensitive to the infrared (IR) region of the spectrum.

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Silver halide in the context of Photographic emulsion

Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films (of cellulose nitrate, cellulose acetate or polyester), paper, or fabric. The substrate is often flexible and known as a film base.

Photographic emulsion is not a true emulsion, but a suspension of solid particles (silver halide) in a fluid (gelatin in solution). However, the word emulsion is customarily used in a photographic context. Gelatin or gum arabic layers sensitized with dichromate used in the dichromated colloid processes carbon and gum bichromate are sometimes called emulsions. Some processes do not have emulsions, such as platinum, cyanotype, salted paper, or kallitype.

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Silver halide in the context of Latent image

A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and forms a visible image. In the early days of photography, the nature of the invisible change in the silver halide crystals of the film's emulsion coating was unknown, so the image was said to be "latent" until the film was treated with photographic developer.

In more physical terms, a latent image is a small cluster of metallic silver atoms formed in or on a silver halide crystal due to reduction of interstitial silver ions by photoelectrons (a photolytic silver cluster). If intense exposure continues, such photolytic silver clusters grow to visible sizes. This is called printing out the image. On the other hand, the formation of a visible image by the action of photographic developer is called developing out the image.

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Silver halide in the context of Photographic developer

In the processing of photographic films, plates or papers, the photographic developer (or just developer) is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black when in the form of fine particles. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halide that have been exposed to light. When left in developer, all the silver halides will eventually be reduced and turn black. Generally, the longer a developer is allowed to work, the darker the image.

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Silver halide in the context of Film stock

Film stock is a type of photographic film that is used for recording motion pictures or animation. It is recorded on by a movie camera, developed, edited, and projected onto a screen using a movie projector.

Photographic film consists of a long strip of transparent plastic film base, coated on one side with a photographic emulsion: a mixture of gelatin and microscopic light-sensitive silver halide crystals. A very short exposure is made, producing an invisible latent image in the emulsion, which can be chemically developed into a visible photograph.

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Silver halide in the context of Gum bichromate

Gum printing is a way of making photographic reproductions without the use of silver halides. The process uses salts of dichromate in common with a number of other related processes such as sun printing.

Gum prints tend to be multi-layered images sometimes combined with other alternative process printing methods such as cyanotype and platinotype. A heavy weight cotton watercolor or printmaking paper that can withstand repeated and extended soakings is best. Each layer of pigment is individually coated, registered, exposed and washed. Separation negatives of cyan, magenta, and yellow or red, green, and blue are used for a full-color image. Some photographers prefer substituting the cyan emulsion in the CMYK separations with a cyanotype layer. A simple duotone separation combining orange watercolor pigment and a cyanotype can yield surprisingly beautiful results.

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Silver halide in the context of Color couplers

Dye coupler is present in chromogenic film and paper used in photography, primarily color photography. When a color developer reduces ionized (exposed) silver halide crystals, the developer is oxidized, and the oxidized molecules react with dye coupler molecules to form a dye in situ. The silver image is removed by subsequent bleach and fix processes, so the final image will consist of the dye image.

Dye coupler technology has seen considerable advancement since the beginning of modern color photography. Major film and paper manufacturers have continually improved the stability of the image dye by improving couplers, particularly since the 1980s, so that archival properties of images are enhanced in newer color papers and films. Generally speaking, dye couplers for paper use are given more emphasis on the image permanence than those for film use, but some modern films (such as Fujichrome Provia films) use variants of couplers that were originally designed for paper use to further improve the image permanence.

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