In organosilicon chemistry, a siloxane is an organic compound containing a functional group of two silicon atoms bound to an oxygen atom: Si−O−Si. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H[OSiH2]nOH and [OSiH2]n. Siloxanes also include branched compounds, the defining feature of which is that each pair of silicon centres is separated by one oxygen atom. The siloxane functional group forms the backbone of silicones [−R2Si−O−SiR2−]n, the premier example of which is polydimethylsiloxane (PDMS). The functional group R3SiO− (where the three Rs may be different) is called siloxy. Siloxanes are manmade and have many commercial and industrial applications because of the compounds’ hydrophobicity, low thermal conductivity, and high flexibility.
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👉 Siloxane in the context of Silicone
In organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (−O−R2Si−O−SiR2−, where "R" stands for an organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking utensils, thermal insulation, and electrical insulation. Some common forms include silicone oil, grease, rubber, resin, and caulk.
Silicone is often confused with one of its constituent elements, silicon, but they are distinct substances. Silicon is a pure chemical element, a metalloid, which forms a dark-grey semiconducting crystalline solid. In its crystalline form it is used to make integrated circuits ("electronic chips") and solar cells. In contrast, silicone is formed by the polymerization of the siloxane molecule, which itself is made up of a variable combination of carbon, hydrogen, oxygen and silicon atoms. Depending on the chemical makeup and polymer structure of a particular silicone product, it can possess a variety of physical properties, ranging from an oily liquid to a rubbery resin.
Siloxane in the context of Biogas
Biogas is a gaseous renewable energy source produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste, wastewater, and food waste. Biogas is produced by anaerobic digestion with anaerobic organisms or methanogens inside an anaerobic digester, biodigester or a bioreactor. The gas composition is primarily methane (CH
4) and carbon dioxide (CO
2) and may have small amounts of hydrogen sulfide (H
2S), moisture and siloxanes. The methane can be combusted or oxidized with oxygen. This energy release allows biogas to be used as a fuel; it can be used in fuel cells and for heating purposes, such as in cooking. It can also be used in a gas engine to convert the energy in the gas into electricity and heat.
Biogas can be upgraded to natural gas quality specifications by stripping carbon dioxide and other contaminants. Biogas that has been upgraded to interchangeability with natural gas is called Renewable Natural Gas (RNG). RNG can be used a drop-in fuel in the gas grid or to produce compressed natural gas as a vehicle fuel.
Siloxane in the context of Silicone oil
A silicone oil is any liquid polymerized siloxane with organic side chains. The most important member is polydimethylsiloxane. These polymers are of commercial interest because of their relatively high thermal stability and their lubricating properties.
Siloxane in the context of Silicone resin
Silicone resins are a type of silicone material which is formed by branched, cage-like oligosiloxanes with the general formula of RnSiXmOy, where R is a non-reactive substituent, usually methyl (Me = −CH3) or phenyl (Ph = −C6H5), and X is a functional group: hydrogen (−H), hydroxyl (−OH), chlorine (−Cl) or alkoxy (−O). These groups are further condensed in many applications, to give highly crosslinked, insoluble polysiloxane networks.
When R is methyl, the four possible functional siloxane monomeric units are described as follows: