Vapor pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the attractive interactions between liquid molecules become less significant in comparison to the entropy of those molecules in the gas phase, increasing the vapor pressure. Thus, liquids with strong intermolecular interactions are likely to have smaller vapor pressures, with the reverse true for weaker interactions.
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👉 Saturation vapor pressure in the context of Bergeron process
The Wegener–Bergeron–Findeisen process (named after Alfred Wegener, Tor Bergeron, and Walter Findeisen), or "cold-rain process", is a process of ice crystal growth that occurs in mixed phase clouds (containing a mixture of supercooled water and ice) in regions where the ambient vapor pressure falls between the saturation vapor pressure over water and the lower saturation vapor pressure over ice. This is a subsaturated environment for liquid water but a supersaturated environment for ice, resulting in rapid evaporation of liquid water and rapid ice crystal growth through vapor deposition. If the number density of ice is small compared to liquid water, the ice crystals can grow large enough to fall out of the cloud, melting into raindrops if lower-level temperatures are warm enough.
The Wegener–Bergeron–Findeisen process, if occurring at all, is much more efficient in producing large particles than is the growth of larger droplets at the expense of smaller ones, since the difference in saturation pressure between liquid water and ice is larger than the enhancement of saturation pressure over small droplets (for droplets large enough to considerably contribute to the total mass). For other processes affecting particle size, see rain and cloud physics.
Saturation vapor pressure in the context of Effects of climate change on the water cycle
The effects of climate change on the water cycle are profound and have been described as an intensification or a strengthening of the water cycle (also called the hydrologic cycle). This effect has been observed since at least 1980. One example is when heavy rain events become even stronger. The effects of climate change on the water cycle have important negative effects on the availability of freshwater resources, as well as other water reservoirs such as oceans, ice sheets, the atmosphere and soil moisture. The water cycle is essential to life on Earth and plays a large role in the global climate system and ocean circulation. The warming of our planet is expected to be accompanied by changes in the water cycle for various reasons. For example, a warmer atmosphere can contain more water vapor which has effects on evaporation and rainfall.
The underlying cause of the intensifying water cycle is the increased amount of greenhouse gases in the atmosphere, which lead to a warmer atmosphere through the greenhouse effect. Fundamental laws of physics explain how the saturation vapor pressure in the atmosphere increases by 7% when temperature rises by 1 °C. This relationship is known as the Clausius-Clapeyron equation.