Rhamnose in the context of Glucoside


Rhamnose in the context of Glucoside

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👉 Rhamnose in the context of Glucoside

A glucoside is a glycoside that is chemically derived from glucose. Glucosides are common in plants, but rare in animals. Glucose is produced when a glucoside is hydrolysed by purely chemical means, or decomposed by fermentation or enzymes.

The name was originally given to plant products of this nature, in which the other part of the molecule was, in the greater number of cases, an aromatic aldehydic or phenolic compound (exceptions are Jinigrin and Jalapin or Scammonin). It has now been extended to include synthetic ethers, such as those obtained by acting on alcoholic glucose solutions with hydrochloric acid, and also the polysaccharoses, e.g. cane sugar, which appear to be ethers also. Although glucose is the most common sugar present in glucosides, many are known which yield rhamnose or iso-dulcite; these may be termed pentosides. Much attention has been given to the non-sugar parts (aglycone) of the molecules; the constitutions of many have been determined, and the compounds synthesized; and in some cases the preparation of the synthetic glucoside effected.

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Rhamnose in the context of Sugars in grape juice

Sugars in wine are at the heart of what makes winemaking possible. During the process of fermentation, sugars from wine grapes are broken down and converted by yeast into alcohol (ethanol) and carbon dioxide. Grapes accumulate sugars as they grow on the grapevine through the translocation of sucrose molecules that are produced by photosynthesis from the leaves. During ripening the sucrose molecules are hydrolyzed (separated) by the enzyme invertase into glucose and fructose. By the time of harvest, between 15 and 25% of the grape will be composed of simple sugars. Both glucose and fructose are six-carbon sugars but three-, four-, five- and seven-carbon sugars are also present in the grape. Not all sugars are fermentable, with sugars like the five-carbon arabinose, rhamnose and xylose still being present in the wine after fermentation. Very high sugar content will effectively kill the yeast once a certain (high) alcohol content is reached. For these reasons, no wine is ever fermented completely "dry" (meaning without any residual sugar). Sugar's role in dictating the final alcohol content of the wine (and such its resulting body and "mouth-feel") sometimes encourages winemakers to add sugar (usually sucrose) during winemaking in a process known as chaptalization solely in order to boost the alcohol content – chaptalization does not increase the sweetness of a wine.

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Rhamnose in the context of Vibrio pectenicida

Vibrio pectenicida, sometimes abbreviated V. pec, is a species of bacterium, of which strain A365 is associated with disease in scallop (Pecten maximus) larvae. Strain A365 is the type strain (= CIP 105190) and does not use glucose or fructose as carbon sources, but uses rhamnose and betaine.

Vibrio pectenicida strain FHCF-3 has been identified as a causative agent of a sea star wasting disease in Pycnopodia helianthoides. The draft genome is 4,368,354 bp and has 3,903 coding sequences, three of which encode putative aerolysin-like toxins that can disrupt cellular membranes and are associated with virulence. The bacterium responds to enrichment with a variety of organic matter sources on asteroid surfaces, and was found in healthy sea cucumbers and sea stars, along with plankton in Australia, Hong Kong, and Okinawa.

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Rhamnose in the context of Quercitrin

Quercitrin is a glycoside formed from the flavonoid quercetin and the deoxy sugar rhamnose.

Austrian chemist Heinrich Hlasiwetz (1825-1875) is remembered for his chemical analysis of quercitrin.

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