Refrigerants in the context of "Chlorofluorocarbon"

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⭐ Core Definition: Refrigerants

Refrigerants are working fluids that carry heat from a cold environment to a warm environment while circulating between them. For example, the refrigerant in an air conditioner carries heat from a cool indoor environment to a hotter outdoor environment. Similarly, the refrigerant in a kitchen refrigerator carries heat from the inside the refrigerator out to the surrounding room. A wide range of fluids are used as refrigerants, with the specific choice depending on the temperature range needed and constraints related to the system involved.

Refrigerants are the basis of vapor compression refrigeration systems. The refrigerant is circulated in a loop between the cold and warm environments (see figure). In the low-temperature environment, the refrigerant absorbs heat at low pressure, causing it to evaporate. The gaseous refrigerant then enters a compressor, which raises its pressure and temperature. The pressurized refrigerant circulates through the warm environment, where it releases heat and condenses to liquid form. The high-pressure liquid is then depressurized and returned to the cold environment as a liquid-vapor mixture.

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👉 Refrigerants in the context of Chlorofluorocarbon

Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatile derivatives of methane, ethane, and propane.

The most common example of a CFC is dichlorodifluoromethane (R-12). R-12, also commonly called Freon, is used as a refrigerant. Many CFCs have been widely used as refrigerants, propellants (in aerosol applications), gaseous fire suppression systems, and solvents. As a result of CFCs contributing to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs) including R-410A, R-134a and R-1234yf.

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Refrigerants in the context of Hydrofluorocarbons

Hydrofluorocarbons (HFCs) are synthetic organic compounds that contain fluorine and hydrogen atoms, and are the most common type of organofluorine compounds. Most are gases at room temperature and pressure. They are frequently used in air conditioning and as refrigerants; R-134a (1,1,1,2-tetrafluoroethane) is one of the most commonly used HFC refrigerants. In order to aid the recovery of the stratospheric ozone layer, HFCs were adopted to replace the more potent chlorofluorocarbons (CFCs) such as R-12, which were phased out from use by the Montreal Protocol, and hydrochlorofluorocarbons (HCFCs) such as R-21 which are presently being phased out. HFCs are also used in insulating foams, aerosol propellants, as solvents and for fire protection.

HFCs may not harm the ozone layer as much as the compounds they replace, but they still contribute to global warming – with some like trifluoromethane (CHF3 or R-23) having 11,700 times the warming potential of carbon dioxide. HFC atmospheric concentrations and contribution to anthropogenic greenhouse gas emissions are rapidly increasing – consumption rose from near zero in 1990 to 1.2 billion tons of carbon dioxide equivalent in 2010 – causing international concern about their radiative forcing.

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Refrigerants in the context of Perfluorocarbons

Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often have distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Several fluorocarbons and their derivatives are commercial polymers, refrigerants, drugs, and anesthetics.

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