Rare earth elements in the context of "Paul-Émile Lecoq de Boisbaudran"

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⭐ Core Definition: Rare earth elements

The rare-earth elements (REE), also called rare-earth metals, or rare earths, are a set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals. The 15 lanthanides (or lanthanoids), along with scandium and yttrium, are usually included as rare earths. Compounds containing rare-earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes. Rare-earths are to be distinguished from critical minerals, which are materials of strategic or economic importance that are defined differently by different countries, and rare-earth minerals, which are minerals that contain one or more rare-earth elements as major metal constituents.

The term "rare-earth" is a misnomer, because they are not actually scarce, but because they are found only in compounds, not as pure metals, and are difficult to isolate and purify. They are relatively plentiful in the entire Earth's crust (cerium being the 25th-most-abundant element at 68 parts per million, more abundant than copper), but in practice they are spread thinly as trace impurities, so to obtain rare earths at usable purity requires processing enormous amounts of raw ore at great expense.

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👉 Rare earth elements in the context of Paul-Émile Lecoq de Boisbaudran

Paul-Émile Lecoq de Boisbaudran, also called François Lecoq de Boisbaudran (18 April 1838 – 28 May 1912), was a self-taught French chemist known for his discoveries of the chemical elements gallium, samarium and dysprosium. He developed methods for separation and purification of the rare earth elements and was one of the pioneers of the science of spectroscopy.

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Rare earth elements in the context of Sesquioxide

A sesquioxide is an oxide of an element (or radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide Al2O3 and phosphorus(III) oxide P4O6 are sesquioxides.Many sesquioxides contain a metal in the +3 oxidation state and the oxide ion O, e.g., aluminium oxide Al2O3, lanthanum(III) oxide La2O3 and iron(III) oxide Fe2O3. Sesquioxides of iron and aluminium are found in soil. The alkali metal sesquioxides are exceptions because they contain both peroxide O2−2 and superoxide O2 ions, e.g., rubidium sesquioxide Rb4O6 is formulated (Rb)4(O2−2)(O2)2. Sesquioxides of metalloids and nonmetals are better formulated as covalent, e.g. boron trioxide B2O3, dinitrogen trioxide N2O3 and phosphorus(III) oxide P4O6; chlorine trioxide Cl2O3 and bromine trioxide Br2O3 do not have oxidation state +3 on the halogen.

Many transition metal oxides crystallize in the corundum structure type, with space group R3c. Sesquioxides of rare earth elements crystalize into one or more of three crystal structures: hexagonal (type A, space group P3m1), monoclinic (type B, space group C2/m), or body-centered cubic (type C, space group Ia3).

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