Rankine cycle in the context of "Working fluid"

A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be transformed by a connecting rod and crank into rotational force for work. The term "steam engine" is most commonly applied to reciprocating engines as just described, although some authorities have also referred to the steam turbine and devices such as Hero's aeolipile as "steam engines". The essential feature of steam engines is that they are external combustion engines, where the working fluid is separated from the combustion products. The ideal thermodynamic cycle used to analyze this process is called the Rankine cycle. In general usage, the term steam engine can refer to either complete steam plants (including boilers etc.), such as railway steam locomotives and portable engines, or may refer to the piston or turbine machinery alone, as in the beam engine and stationary steam engine.

Steam-driven devices such as the aeolipile were known in the first century AD, and there were a few other uses recorded in the 16th century. In 1606 Jerónimo de Ayanz y Beaumont patented his invention of the first steam-powered water pump for draining mines. Thomas Savery is considered the inventor of the first commercially used steam powered device, a steam pump that used steam pressure operating directly on the water. The first commercially successful engine that could transmit continuous power to a machine was developed in 1712 by Thomas Newcomen. In 1764, James Watt made a critical improvement by removing spent steam to a separate vessel for condensation, greatly improving the amount of work obtained per unit of fuel consumed. By the 19th century, stationary steam engines powered the factories of the Industrial Revolution. Steam engines replaced sails for ships on paddle steamers, and steam locomotives operated on the railways.

A thermal power station, also known as a thermal power plant, is a type of power station in which the heat energy generated from various fuel sources (e.g., coal, natural gas, nuclear fuel, etc.) is converted to electrical energy. The heat from the source is converted into mechanical energy using a thermodynamic power cycle (such as a Diesel cycle, Rankine cycle, Brayton cycle, etc.). The most common cycle involves a working fluid (often water) heated and boiled under high pressure in a pressure vessel to produce high-pressure steam. This high pressure-steam is then directed to a turbine, where it rotates the turbine's blades. The rotating turbine is mechanically connected to an electric generator which converts rotary motion into electricity. Fuels such as natural gas or oil can also be burnt directly in gas turbines (internal combustion), skipping the steam generation step. These plants can be of the open cycle or the more efficient combined cycle type.

The majority of the world's thermal power stations are driven by steam turbines, gas turbines, or a combination of the two. The efficiency of a thermal power station is determined by how effectively it converts heat energy into electrical energy, specifically the ratio of saleable electricity to the heating value of the fuel used. Different thermodynamic cycles have varying efficiencies, with the Rankine cycle generally being more efficient than the Otto or Diesel cycles. In the Rankine cycle, the low-pressure exhaust from the turbine enters a steam condenser where it is cooled to produce hot condensate which is recycled to the heating process to generate even more high pressure steam.

In thermodynamics, vapor quality is the mass fraction in a saturated mixture that is vapor; in other words, saturated vapor has a "quality" of 100%, and saturated liquid has a "quality" of 0%. Vapor quality is an intensive property which can be used in conjunction with other independent intensive properties to specify the thermodynamic state of the working fluid of a thermodynamic system. It has no meaning for substances which are not saturated mixtures (for example, compressed liquids or superheated fluids).Vapor quality is an important quantity during the adiabatic expansion step in various thermodynamic cycles (like Organic Rankine cycle, Rankine cycle, etc.). Working fluids can be classified by using the appearance of droplets in the vapor during the expansion step.

Quality χ can be calculated by dividing the mass of the vapor by the mass of the total mixture:$${\displaystyle \chi ={\frac {m_{\text{vapor}}}{m_{\text{total}}}}}$$where m indicates mass.