Potosí Department in the context of "Salar de Uyuni"

Ollagüe (Spanish pronunciation: [oˈʎaɣwe]) or Ullawi (Aymara: [uˈʎawi]) is a massive andesite stratovolcano in the Andes on the Bolivia–Chile border, within the Antofagasta Region of Chile and the Potosi Department of Bolivia. Part of the Central Volcanic Zone of the Andes, its highest summit is 5,868 metres (19,252 ft) above sea level and features a summit crater that opens to the south. The western rim of the summit crater is formed by a compound of lava domes, the youngest of which features a vigorous fumarole that is visible from afar.

Ollagüe is mostly of Pleistocene age. It started developing more than one million years ago, forming the so-called Vinta Loma and Santa Rosa series mostly of andesitic lava flows. A fault bisects the edifice and two large landslides occurred in relation to it. Later two groups of dacitic lava domes formed, Ch'aska Urqu on the southeastern slope and La Celosa on the northwestern. Another centre named La Poruñita formed at that time on the western foot of the volcano, but it is not clear whether it is part of the main Ollagüe system. Activity at the summit continued during this time, forming the El Azufre sequence.

Chuquisaca (Spanish pronunciation: [tʃukiˈsaka]); Guarani: Chuquisaca; Quechua: Chuqichaka; Aymara: Chuqisaka) is a department of Bolivia located in the center south. It borders on the departments of Cochabamba, Tarija, Potosí, and Santa Cruz. The departmental capital is Sucre, which is also the constitutional capital of Bolivia.

Potosí, known as Villa Imperial de Potosí in the colonial period, is the capital city and a municipality of the Department of Potosí in Bolivia. It is one of the highest cities in the world at a nominal 4,067 m (13,343 ft).

Diego Huallpa, an indigenous prospector, is traditionally credited with the discovery of the Cerro Rico in 1545, which led to the founding and rapid growth of Potosí due to its extraordinary silver wealth.