Polyacrylonitrile in the context of Lithium polymer battery


Polyacrylonitrile in the context of Lithium polymer battery

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⭐ Core Definition: Polyacrylonitrile

Polyacrylonitrile (PAN) is a synthetic, semicrystalline organic polymer resin, with the linear formula (CH2CHCN)n. Almost all PAN resins are copolymers with acrylonitrile as the main monomer. PAN is used to produce large variety of products including ultra filtration membranes, hollow fibers for reverse osmosis, fibers for textiles, and oxidized PAN fibers. PAN fibers are the chemical precursor of very high-quality carbon fiber. PAN is first thermally oxidized in air at 230 °C to form an oxidized PAN fiber and then carbonized above 1000 °C in inert atmosphere to make carbon fibers found in a variety of both high-tech and common daily applications such as civil and military aircraft primary and secondary structures, missiles, solid propellant rocket motors, pressure vessels, fishing rods, tennis rackets and bicycle frames. It is a component repeat unit in several important copolymers, such as styrene-acrylonitrile (SAN) and acrylonitrile butadiene styrene (ABS) plastic.

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👉 Polyacrylonitrile in the context of Lithium polymer battery

A lithium polymer battery, or more correctly, lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly, and others), is a rechargeable battery derived from lithium-ion and lithium-metal battery technology. The primary difference is that instead of using a liquid lithium salt (such as lithium hexafluorophosphate, LiPF6) held in an organic solvent (such as EC/DMC/DEC) as the electrolyte, the battery uses a solid (or semi-solid) polymer electrolyte such as polyethylene glycol (PEG), polyacrylonitrile (PAN), poly(methyl methacrylate) (PMMA) or poly(vinylidene fluoride) (PVdF). Other terms used in the literature for this system include hybrid polymer electrolyte (HPE), where hybrid denotes the combination of the polymer matrix, the liquid solvent, and the salt.

Polymer electrolytes can be divided into two large categories: dry solid polymer electrolytes (SPE) and gel polymer electrolytes (GPE).

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Polyacrylonitrile in the context of Acrylic fiber

Acrylic fibers are synthetic fibers made from a polymer (polyacrylonitrile) with an average molecular weight of ~100,000, about 1900 monomer units. For a fiber to be called "acrylic" in the US, the polymer must contain at least 85% acrylonitrile monomer. Typical comonomers are vinyl acetate or methyl acrylate. DuPont created the first acrylic fibers in 1941 and trademarked them under the name Orlon. It was first developed in the mid-1940s but was not produced in large quantities until the 1950s. Strong and warm, acrylic fiber is often used for sweaters and tracksuits and as linings for boots and gloves, as well as in furnishing fabrics and carpets. It is manufactured as a filament, then cut into short staple lengths similar to wool hairs, and spun into yarn.

Modacrylic is a modified acrylic fiber that contains at least 35% and at most 85% acrylonitrile. Vinylidene chloride or vinyl bromide used in modacrylic give the fiber flame retardant properties. End-uses of modacrylic include faux fur, wigs, hair extensions, and protective clothing.

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Polyacrylonitrile in the context of Acrylonitrile

Acrylonitrile is an organic compound with the formula CH2CHCN and the structure H2C=CH−C≡N. It is a colorless, volatile liquid. It has a pungent odor of garlic or onions. Its molecular structure consists of a vinyl group (−CH=CH2) linked to a nitrile (−C≡N). It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. It is reactive and toxic at low doses.

Acrylonitrile is one of the components of ABS plastic (acrylonitrile butadiene styrene).

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