Plutonium in the context of Halogen


Plutonium in the context of Halogen

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⭐ Core Definition: Plutonium

Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune, element 94 was named after Pluto, which at the time was also considered a planet. Wartime secrecy prevented the University of California team from publishing its discovery until 1948.

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Plutonium in the context of Atomic bombings of Hiroshima and Nagasaki

On 6 and 9 August 1945, the United States detonated two atomic bombs over the Japanese cities of Hiroshima and Nagasaki, respectively, during World War II. The aerial bombings killed 150,000 to 246,000 people, most of whom were civilians, and remain the only uses of nuclear weapons in an armed conflict. Japan announced its surrender to the Allies on 15 August, six days after the bombing of Nagasaki and the Soviet Union's declaration of war against Japan and invasion of Manchuria. The Japanese government signed an instrument of surrender on 2 September, ending the war.

In the final year of World War II, the Allies prepared for a costly invasion of the Japanese mainland. This undertaking was preceded by a conventional bombing and firebombing campaign that devastated 64 Japanese cities, including an operation on Tokyo. The war in Europe concluded when Germany surrendered on 8 May 1945, and the Allies turned their full attention to the Pacific War. By July 1945, the Allies' Manhattan Project had produced two types of atomic bombs: "Little Boy", an enriched uranium gun-type fission weapon, and "Fat Man", a plutonium implosion-type nuclear weapon. The 509th Composite Group of the U.S. Army Air Forces was trained and equipped with the specialized Silverplate version of the Boeing B-29 Superfortress, and deployed to Tinian in the Mariana Islands. The Allies called for the unconditional surrender of the Imperial Japanese Armed Forces in the Potsdam Declaration on 26 July 1945, the alternative being "prompt and utter destruction". The Japanese government ignored the ultimatum.

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Plutonium in the context of Nuclear power

Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced by nuclear fission of uranium and plutonium in nuclear power plants. Nuclear decay processes are used in niche applications such as radioisotope thermoelectric generators in some space probes such as Voyager 2. Reactors producing controlled fusion power have been operated since 1958 but have yet to generate net power and are not expected to be commercially available in the near future.

The first nuclear power plant was built in the 1950s. The global installed nuclear capacity grew to 100 GW in the late 1970s, and then expanded during the 1980s, reaching 300 GW by 1990. The 1979 Three Mile Island accident in the United States and the 1986 Chernobyl disaster in the Soviet Union resulted in increased regulation and public opposition to nuclear power plants. Nuclear power plants supplied 2,602 terawatt hours (TWh) of electricity in 2023, equivalent to about 9% of global electricity generation, and were the second largest low-carbon power source after hydroelectricity. As of November 2025, there are 416 civilian fission reactors in the world, with overall capacity of 376 GW, 63 under construction and 87 planned, with a combined capacity of 66 GW and 84 GW, respectively. The United States has the largest fleet of nuclear reactors, generating almost 800 TWh per year with an average capacity factor of 92%. The average global capacity factor is 89%. Most new reactors under construction are generation III reactors in Asia.

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Plutonium in the context of Nuclear fallout

Nuclear fallout is residual radioisotope material that is created by the reactions producing a nuclear explosion or nuclear accident. In explosions, it is initially present in the radioactive cloud created by the explosion, and "falls out" of the cloud as it is moved by the atmosphere in the minutes, hours, and days after the explosion. The amount of fallout and its distribution is dependent on several factors, including the overall yield of the weapon, the fission yield of the weapon, the height of burst of the weapon, and meteorological conditions.

Fission weapons and many thermonuclear weapons use a large mass of fissionable fuel (such as uranium or plutonium), so their fallout is primarily fission products, and some unfissioned fuel. Cleaner thermonuclear weapons primarily produce fallout via neutron activation. Salted bombs, not widely developed, are tailored to produce and disperse specific radioisotopes selected for their half-life and radiation type.

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Plutonium in the context of Nuclear warfare

Nuclear warfare, also known as atomic warfare, is a military conflict or prepared political strategy that deploys nuclear weaponry. Nuclear weapons are weapons of mass destruction; in contrast to conventional warfare, nuclear warfare can produce destruction in a much shorter time and can have a long-lasting radiological result. A major nuclear exchange would likely have long-term effects, primarily from the fallout released, and could also lead to secondary effects, such as "nuclear winter", nuclear famine, and societal collapse. A global thermonuclear war with Cold War-era stockpiles, or even with the current smaller stockpiles, may lead to various scenarios including human extinction.

To date, the only use of nuclear weapons in armed conflict occurred in 1945 with the American atomic bombings of Hiroshima and Nagasaki. On August 6, 1945, a uranium gun-type device (code name "Little Boy") was detonated over the Japanese city of Hiroshima. Three days later, on August 9, a plutonium implosion-type device (code name "Fat Man") was detonated over the Japanese city of Nagasaki. Together, these two bombings resulted in the deaths of approximately 200,000 people and contributed to the surrender of Japan, which occurred before any further nuclear weapons could be deployed.

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Plutonium in the context of Nuclear materials

Nuclear material refers to the elements uranium, plutonium, and thorium, in any form, according to the IAEA. This is differentiated further into "source material", consisting of natural and depleted uranium, and "special fissionable material", consisting of enriched uranium (U-235), uranium-233, and plutonium-239. Uranium ore concentrates are considered to be a "source material", although these are not subject to safeguards under the Nuclear Non-Proliferation Treaty.

According to the Nuclear Regulatory Commission (NRC), there are four different types of regulated nuclear materials: special nuclear material, source material, byproduct material and radium. Special nuclear materials have plutonium, uranium-233 or uranium with U or U that has a content found more than in nature. Source material is thorium or uranium that has a U content equal to or less than what is in nature. Byproduct material is radioactive material that is not source or special nuclear material. It can be an isotope produced by a nuclear reactor, the tailings and waste that is produced or extracted from uranium or thorium from an ore that processed mainly for its source material content. Byproduct material can also be discrete sources of radium-226 or discrete sources of accelerator-produced isotopes or naturally occurring isotopes that pose a threat greater or equal to a discrete source of radium-226. Radium is also a regulated nuclear material that is found in nature and produced by the radioactive decay of uranium. The half-life of radium is approximately 1,600 years.

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Plutonium in the context of Trinity (nuclear test)

Trinity was the first detonation of a nuclear weapon, conducted by the United States Army at 5:29 a.m. Mountain War Time (11:29:21 GMT) on July 16, 1945, as part of the Manhattan Project. The test was of an implosion-design plutonium bomb, or "gadget" – the same design as the Fat Man bomb later detonated over Nagasaki, Japan, on August 9, 1945. Concerns about whether the complex Fat Man design would work led to a decision to conduct the first nuclear test. The code name "Trinity" was assigned by J. Robert Oppenheimer, the director of the Los Alamos Laboratory. The name was possibly inspired by the poetry of John Donne.

Planned and directed by Kenneth Bainbridge, the test was conducted in the Jornada del Muerto desert about 35 miles (56 km) southeast of Socorro, New Mexico, on what was the Alamogordo Bombing and Gunnery Range, but was renamed the White Sands Proving Ground just before the test. The only structures originally in the immediate vicinity were the McDonald Ranch House and its ancillary buildings, which scientists used as a laboratory for testing bomb components.

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Plutonium in the context of Isotope separation

Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" nuclide are used to figure out reaction mechanisms). By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. This process is crucial in the manufacture of uranium fuel for nuclear power plants and is also required for the creation of uranium-based nuclear weapons (unless uranium-233 is used). Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or grade.

While chemical elements can be purified through chemical processes, isotopes of the same element have nearly identical chemical properties which makes this type of separation impractical, except for separation of deuterium.

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Plutonium in the context of Little Boy

Little Boy was a type of atomic bomb created by the Manhattan Project during World War II. The name is also often used to describe the specific bomb (L-11) used in the bombing of the Japanese city of Hiroshima by the Boeing B-29 Superfortress Enola Gay on 6 August 1945, making it the first nuclear weapon used in warfare, and the second nuclear explosion in history, after the Trinity nuclear test. It exploded with an energy of approximately 15 kilotons of TNT (63 TJ) and had an explosion radius of approximately 1.3 kilometres (0.81 mi) which caused widespread death across the city. It was a gun-type fission weapon which used uranium that had been enriched in the isotope uranium-235 to power its explosive reaction.

Little Boy was developed by Lieutenant Commander Francis Birch's group at the Los Alamos Laboratory. It was the successor to a plutonium-fueled gun-type fission design, Thin Man, which was abandoned in 1944 after technical difficulties were discovered. Little Boy used a charge of cordite to fire a hollow cylinder (the "bullet") of highly enriched uranium through an artillery gun barrel into a solid cylinder (the "target") of the same material. The design was highly inefficient: the weapon used on Hiroshima contained 64 kilograms (141 lb) of uranium, but less than a kilogram underwent nuclear fission. Unlike the implosion design developed for the Trinity test and the Fat Man bomb design that was used against Nagasaki, which required sophisticated coordination of shaped explosive charges, the simpler but inefficient gun-type design was considered almost certain to work, and was never tested prior to its use at Hiroshima.

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Plutonium in the context of Los Alamos Laboratory

The Los Alamos Laboratory, also known as Project Y, was a secret scientific laboratory established by the Manhattan Project and overseen by the University of California during World War II. It was operated in partnership with the United States Army. Its mission was to design and build the first atomic bombs. J. Robert Oppenheimer was its first director, serving from 1943 to December 1945, when he was succeeded by Norris Bradbury. In order to enable scientists to freely discuss their work while preserving security, the laboratory was located on the isolated Pajarito Plateau in northern New Mexico. The wartime laboratory occupied buildings that had once been part of the Los Alamos Ranch School.

The development effort initially focused on a gun-type fission weapon using plutonium called Thin Man. In April 1944, the Los Alamos Laboratory determined that the rate of spontaneous fission in plutonium bred in a nuclear reactor was too great due to the presence of plutonium-240 and would cause a predetonation, a nuclear chain reaction before the core was fully assembled. Oppenheimer then reorganized the laboratory and orchestrated an all-out and ultimately successful effort on an alternative design proposed by John von Neumann, an implosion-type nuclear weapon, which was called Fat Man. A variant of the gun-type design known as Little Boy was developed using uranium-235.

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Plutonium in the context of Criticality excursion

A criticality accident is an accidental uncontrolled nuclear fission chain reaction. It is sometimes referred to as a critical excursion, critical power excursion, divergent chain reaction, or simply critical. Any such event involves the unintended accumulation or arrangement of a critical mass of fissile material, for example enriched uranium or plutonium. Criticality accidents can release potentially fatal radiation doses if they occur in an unprotected environment.

Under normal circumstances, a critical or supercritical fission reaction (one that is self-sustaining in power or increasing in power) should only occur inside a safely shielded location, such as a reactor core or a suitable test environment. A criticality accident occurs if the same reaction is achieved unintentionally, for example in an unsafe environment or during reactor maintenance.

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Plutonium in the context of Chernobyl Nuclear Power Plant sarcophagus

The Chernobyl Nuclear Power Plant sarcophagus or Shelter Structure (Ukrainian: Об'єкт "Укриття", romanizedOb'yekt "Ukryttya", Russian: Объект «Укрытие», romanizedOb"yekt «Ukrytiye») is a massive steel and concrete structure covering the nuclear reactor number 4 building of the Chernobyl Nuclear Power Plant. Built in the aftermath of the 1986 Chernobyl disaster, the sarcophagus was designed to limit radioactive contamination of the environment by encasing the most dangerous area and protecting it from climate exposure. The sarcophagus locked in an estimated 200 tons of radioactive lava-like corium, 30 tons of highly contaminated dust and 16 tons of uranium and plutonium.

Structurally, the sarcophagus is largely supported by the damaged reactor building. By 1996, the structure had deteriorated to the point where numerous stabilization measures were required. Internal radiation levels were estimated to be as high as 10000 röntgens per hour in certain areas (normal background radiation in cities is usually around 20–50 microröntgens per hour, and a lethal dose is 500 röntgens over 5 hours). By 2017, the sarcophagus was surrounded by the New Safe Confinement structure, which is designed to protect the environment while the sarcophagus undergoes demolition and the nuclear cleanup continues. The reactor site is located within a large restricted area known as the Chernobyl Exclusion Zone.

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Plutonium in the context of Dolphin-class submarine

The Dolphin class (Hebrew: הצוללות מסדרת דולפין) is a diesel-electric submarine developed in Israel and constructed by Howaldtswerke-Deutsche Werft (HDW) in Kiel, Germany, for the Israeli Navy's Shayetet 7 flotilla. The first boats of the class were based on the export-only German 209-class submarines, but modified and enlarged. The Dolphin 1 sub-class is slightly larger than the German Navy Type 212 in length and displacement. The three newer air-independent propulsion (AIP) equipped boats are similar to the Type 212 vessels in underwater endurance, but are 12 metres (39 ft) longer, nearly 500 tonnes heavier in submerged displacement and have a larger crew than either the Type 212 or the Type 214.

The Dolphin 2 class submarines are the largest to have been built in Germany since World War II and the most expensive single vehicles in the Israel Defense Forces. The Dolphin class replaced the aging Gal class, which had served in the Israeli navy since the late 1970s. Each Dolphin-class submarine is capable of carrying a combined total of up to 16 torpedoes and Popeye Turbo submarine-launched cruise missiles (SLCMs). The cruise missiles have a range of at least 1,500 km (930 mi) and are widely believed to be equipped with a 200 kiloton nuclear warhead containing up to 6 kilograms (13 lb) of plutonium. The latter, if true, would provide Israel with an offshore nuclear second-strike capability.

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Plutonium in the context of Uranium dioxide

Uranium dioxide or uranium(IV) oxide (UO2), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reactors. A mixture of uranium and plutonium dioxides is used as MOX fuel. It has been used as an orange, yellow, green, and black color in ceramic glazes and glass.

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