Pig iron in the context of "Song Yingxing"

Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an oxidizing environment to burn the carbon, resulting in wrought iron. It was one of the most important processes for making the first appreciable volumes of valuable and useful bar iron (malleable wrought iron) without the use of charcoal. Eventually, the furnace would be used to make small quantities of specialty steels.

Though it was not the first process to produce bar iron without charcoal, puddling was by far the most successful, and replaced the earlier potting and stamping processes, as well as the much older charcoal finery and bloomery processes. This enabled a great expansion of iron production to take place in Great Britain, and shortly afterwards, in North America. That expansion constitutes the beginnings of the Industrial Revolution so far as the iron industry is concerned. Most 19th century applications of wrought iron, including the Eiffel Tower, bridges, and the original framework of the Statue of Liberty, used puddled iron.

Ferrous metallurgy is the metallurgy of iron and its alloys. The earliest surviving prehistoric iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from ores began, but by the end of the 2nd millennium BC iron was being produced from iron ores in the region from Greece to India, The use of wrought iron (worked iron) was known by the 1st millennium BC, and its spread defined the Iron Age. During the medieval period, smiths in Europe found a way of producing wrought iron from cast iron, in this context known as pig iron, using finery forges. All these processes required charcoal as fuel.

By the 4th century BC southern India had started exporting wootz steel, with a carbon content between pig iron and wrought iron, to ancient China, Africa, the Middle East, and Europe. Archaeological evidence of cast iron appears in 5th-century BC China. New methods of producing it by carburizing bars of iron in the cementation process were devised in the 17th century. During the Industrial Revolution, new methods of producing bar iron emerged, by substituting charcoal in favor of coke, and these were later applied to produce steel, ushering in a new era of greatly increased use of iron and steel that some contemporaries described as a new "Iron Age".

Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the form of magnetite (Fe
₃O
₄, 72.4% Fe), hematite (Fe
₂O
₃, 69.9% Fe), goethite (FeO(OH), 62.9% Fe), limonite (FeO(OH)·n(H₂O), 55% Fe), or siderite (FeCO₃, 48.2% Fe).

Ores containing very high quantities of hematite or magnetite (typically greater than about 60% iron) are known as natural ore or [direct shipping ore], and can be fed directly into iron-making blast furnaces. Iron ore is the raw material used to make pig iron, which is one of the primary raw materials to make steel — 98% of the mined iron ore is used to make steel. In 2011 the Financial Times quoted Christopher LaFemina, mining analyst at Barclays Capital, saying that iron ore is "more integral to the global economy than any other commodity, except perhaps oil".

Many significant developments in the history of science and technology in China took place during the Han dynasty (202 BCE – 220 CE).

The Han period saw great innovations in metallurgy. Following the inventions of the blast furnace and cupola furnace during the Zhou dynasty (c. 1046 – 256 BCE) to make pig iron and cast iron respectively, the Han period saw the development of steel and wrought iron by use of the finery forge and puddling process. With the drilling of deep boreholes into the earth, the Chinese used not only derricks to lift brine up to the surface to be boiled into salt, but also set up bamboo-crafted pipeline transport systems which brought natural gas as fuel to the furnaces.

The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities and undesired elements, primarily excess carbon contained in the pig iron by oxidation with air being blown through the molten iron. Oxidation of the excess carbon also raises the temperature of the iron mass and keeps it molten.Virtually all the pig iron carbon is removed by the converter and so carbon must be added at the end of the process to create steel, 0.25% carbon content is a typical value for low carbon steel which is used in construction and other low-stress applications.

The modern process is named after its inventor, the Englishman Henry Bessemer, who took out a patent on the process in 1856. The process was said to be independently discovered in 1851 by the American inventor William Kelly though the claim is controversial.

An open-hearth furnace or open hearth furnace is any of several kinds of industrial furnace in which excess carbon and other impurities are burnt out of pig iron to produce steel. Because steel is difficult to manufacture owing to its high melting point, normal fuels and furnaces were insufficient for mass production of steel, and the open-hearth type of furnace was one of several technologies developed in the nineteenth century to overcome this difficulty. Compared with the Bessemer process, which it displaced, its main advantages were that it did not embrittle the steel from excessive nitrogen exposure, was easier to control, and permitted the melting and refining of large amounts of scrap iron and steel.

The open-hearth furnace was first developed by German/British engineer Carl Wilhelm Siemens. In 1865, the French engineer Pierre-Émile Martin took out a licence from Siemens and first applied his regenerative furnace for making steel. Their process was known as the Siemens–Martin process or Martin–Siemens process, and the furnace as an "open-hearth" furnace. Most open hearth furnaces were closed by the early 1990s, not least because of their slow operation, being replaced by the basic oxygen furnace or electric arc furnace.

Potting and stamping is a modern name for one of the 18th-century processes for refining pig iron without the use of charcoal.