Photosystem II in the context of Oxidizing


Photosystem II in the context of Oxidizing

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⭐ Core Definition: Photosystem II

Photosystem II (or water-plastoquinone oxidoreductase) is the first protein complex in the light-dependent reactions of oxygenic photosynthesis. It is located in the thylakoid membrane of plants, algae, and cyanobacteria. Within the photosystem, enzymes capture photons of light to energize electrons that are then transferred through a variety of coenzymes and cofactors to reduce plastoquinone to plastoquinol. The energized electrons are replaced by oxidizing water to form hydrogen ions and molecular oxygen.

By replenishing lost electrons with electrons from the splitting of water, photosystem II provides the electrons for all oxygenic photosynthesis to occur. The hydrogen ions (protons) generated by the oxidation of water help to create a proton gradient that is used by ATP synthase to generate ATP. The energized electrons transferred to plastoquinone are ultimately used to reduce NADP
to NADPH or are used in non-cyclic electron flow. DCMU is a chemical often used in laboratory settings to inhibit photosynthesis. When present, DCMU inhibits electron flow from photosystem II to plastoquinone.

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Photosystem II in the context of Chlorophyll b

Chlorophyll b is a form of chlorophyll. Chlorophyll b helps in photosynthesis by absorbing light energy. It is more soluble than chlorophyll a in polar solvents because of its carbonyl group. Its color is green, and it primarily absorbs blue light.

In land plants, the light-harvesting antennae around photosystem II contain the majority of chlorophyll b. Hence, in shade-adapted chloroplasts, which have an increased ratio of photosystem II to photosystem I, there is a higher ratio of chlorophyll b to chlorophyll a. This is adaptive, as increasing chlorophyll b increases the range of wavelengths absorbed by the shade chloroplasts.

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Photosystem II in the context of Phaeophytin

Pheophytin or phaeophytin is a chemical compound that serves as the first electron carrier intermediate in the electron transfer pathway of Photosystem II (PS II) in plants, and the type II photosynthetic reaction center (RC P870) found in purple bacteria. In both PS II and RC P870, light drives electrons from the reaction center through pheophytin, which then passes the electrons to a quinone (QA) in RC P870 and RC P680. The overall mechanisms, roles, and purposes of the pheophytin molecules in the two transport chains are analogous to each other.

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Photosystem II in the context of Light-dependent reactions

Light-dependent reactions are the chemical reactions involved in photosynthesis induced by light; all light-dependent reactions occur in thylakoids. There are two light-dependent reactions: the first occurs at photosystem II (PSII) and the second occurs at photosystem I (PSI).

PSII absorbs a photon to produce a so-called high energy electron which transfers via an electron transport chain to cytochrome b6f and then to PSI. The then-reduced PSI, absorbs another photon producing a more highly reducing electron, which converts NADP to NADPH. In oxygenic photosynthesis, the first electron donor is water, creating oxygen (O2) as a by-product. In anoxygenic photosynthesis, various electron donors are used.Cytochrome b6f and ATP synthase work together to produce ATP (photophosphorylation) in two distinct ways. In non-cyclic photophosphorylation, cytochrome b6f uses electrons from PSII and energy from PSI to pump protons from the cytoplasm (or stroma in chloroplasts), to the lumen of the thylakoid. The resulting proton gradient across the thylakoid membrane creates a proton-motive force, used by ATP synthase to form ATP. In cyclic photophosphorylation, cytochrome b6f uses electrons and energy from PSI to create more ATP and to stop the production of NADPH. Cyclic phosphorylation is important to create ATP and maintain NADPH in the right proportion for the light-independent reactions.

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Photosystem II in the context of P680

P680, or photosystem II primary donor, is the reaction-center chlorophyll a molecular dimer associated with photosystem II in plants, algae, and cyanobacteria, and central to oxygenic photosynthesis.

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Photosystem II in the context of Photosystem I

Photosystem I (PSI, or plastocyanin–ferredoxin oxidoreductase) is one of two photosystems in the photosynthetic light reactions of algae, plants, and cyanobacteria. Photosystem I is an integral membrane protein complex that uses light energy to catalyze the transfer of electrons across the thylakoid membrane from plastocyanin to ferredoxin. Ultimately, the electrons that are transferred by Photosystem I are used to produce the moderate-energy hydrogen carrier NADPH. The photon energy absorbed by Photosystem I also produces a proton-motive force that is used to generate ATP. PSI is composed of more than 110 cofactors, significantly more than Photosystem II.

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