Photodegradation is the alteration of materials by light. Commonly, the term is used loosely to refer to the combined action of sunlight and air, which cause oxidation and hydrolysis. Often photodegradation is intentionally avoided, since it destroys paintings and other artifacts. It is, however, partly responsible for remineralization of biomass and is used intentionally in some disinfection technologies. Photodegradation does not apply to how materials may be aged or degraded via infrared light or heat, but does include degradation in all of the ultraviolet light wavebands.
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👉 Photodegradation in the context of Photosensitizer
Photosensitizers are light absorbers that alter the course of a photochemical reaction. They usually are catalysts. They can function by many mechanisms; sometimes they abstract an electron from the substrate, and sometimes they abstract a hydrogen atom from the substrate. At the end of this process, the photosensitizer returns to its ground state, where it remains chemically intact, poised to absorb more light. One branch of chemistry which frequently utilizes photosensitizers is polymer chemistry, using photosensitizers in reactions such as photopolymerization, photocrosslinking, and photodegradation. Photosensitizers are also used to generate prolonged excited electronic states in organic molecules with uses in photocatalysis, photon upconversion and photodynamic therapy. Generally, photosensitizers absorb electromagnetic radiation consisting of infrared radiation, visible light radiation, and ultraviolet radiation and transfer absorbed energy into neighboring molecules. This absorption of light is made possible by photosensitizers' large de-localized π-systems, which lowers the energy of HOMO and LUMO orbitals to promote photoexcitation. While many photosensitizers are organic or organometallic compounds, there are also examples of using semiconductor quantum dots as photosensitizers.
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Photodegradation in the context of Marine plastic pollution
Marine plastic pollution is a type of marine pollution by plastics, ranging in size from large original material such as bottles and bags, down to microplastics formed from the fragmentation of plastic material. Marine debris is mainly discarded human rubbish which floats on, or is suspended in the ocean. Eighty percent of marine debris is plastic. Microplastics and nanoplastics result from the breakdown or photodegradation of plastic waste in surface waters, rivers or oceans. Recently, scientists have uncovered nanoplastics in heavy snow, more specifically about 3,000 tons that cover Switzerland yearly.
It is approximated that there is a stock of 86 million tons of plastic marine debris in the worldwide ocean as of the end of 2013, assuming that 1.4% of global plastics produced from 1950 to 2013 has entered the ocean and has accumulated there. Global consumption of plastics is estimated to be 300 million tonnes per year as of 2022, with around 8 million tonnes ending up in the oceans as macroplastics. Approximately 1.5 million tonnes of primary microplastics end up in the seas. Around 98% of this volume is created by land-based activities, with the remaining 2% being generated by sea-based activities. It is estimated that 19–23 million tonnes of plastic leaks into aquatic ecosystems annually. The 2017 United Nations Ocean Conference estimated that the oceans might contain more weight in plastics than fish by the year 2050.
View the full Wikipedia page for Marine plastic pollutionPhotodegradation in the context of Singlet oxygen
Singlet oxygen, systematically named dioxygen(singlet) and dioxidene, is a gaseous inorganic chemical with two oxygen atoms in a quantum state where all electrons are spin-paired, known as a singlet state. It is the lowest excited state of the diatomic oxygen molecule, which in general has the chemical structure O=O and chemical formula O
2. Singlet oxygen can be written more specifically as
[O
2] or
O
2. The more prevalent ground state of O
2 is known as triplet oxygen. At room temperature, singlet oxygen will slowly decay into triplet oxygen, releasing the energy of excitation.
Singlet oxygen is a gas with physical properties differing only subtly from the ground state. In terms of its chemical reactivity, however, singlet oxygen is far more reactive toward organic compounds. It is responsible for the photodegradation of many materials but can be put to constructive use in preparative organic chemistry and photodynamic therapy. Trace amounts of singlet oxygen are found in the upper atmosphere and in polluted urban atmospheres where it contributes to the formation of lung-damaging nitrogen dioxide. It often appears and coexists confounded in environments that also generate ozone, such as pine forests with photodegradation of turpentine.
View the full Wikipedia page for Singlet oxygenPhotodegradation in the context of Plastic soup
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Marine plastic pollution is a type of marine pollution by plastics, ranging in size from large original material such as bottles and bags, down to microplastics formed from the fragmentation of plastic material. Marine debris is mainly discarded human rubbish which floats on, or is suspended in the ocean. Eighty percent of marine debris is plastic. Microplastics and nanoplastics result from the breakdown or photodegradation of plastic waste in surface waters, rivers or oceans. Recently, scientists have uncovered nanoplastics in heavy snow, more specifically about 3,000 tons that cover Switzerland yearly.
View the full Wikipedia page for Plastic soup