Phosphorescence in the context of UV light

Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colored visible light. The color of the light emitted depends on the chemical composition of the substance. Fluorescent materials generally cease to glow nearly immediately when the radiation source stops. This distinguishes them from the other type of light emission, phosphorescence. Phosphorescent materials continue to emit light for some time after the radiation stops.This difference in duration is a result of quantum spin effects.

Fluorescence occurs when a photon from incoming radiation is absorbed by a molecule, exciting it to a higher energy level, followed by the emission of light as the molecule returns to a lower energy state. The emitted light may have a longer wavelength and, therefore, a lower photon energy than the absorbed radiation. For example, the absorbed radiation could be in the ultraviolet region of the electromagnetic spectrum (invisible to the human eye), while the emitted light is in the visible region. This gives the fluorescent substance a distinct color, best seen when exposed to UV light, making it appear to glow in the dark. However, any light with a shorter wavelength may cause a material to fluoresce at a longer wavelength. Fluorescent materials may also be excited by certain wavelengths of visible light, which can mask the glow, yet their colors may appear bright and intensified. Other fluorescent materials emit their light in the infrared or even the ultraviolet regions of the spectrum.

Maurice Hugh Frederick Wilkins CBE FRS (15 December 1916 – 5 October 2004) was a New Zealand-born British biophysicist and Nobel laureate whose research spanned multiple areas of physics and biophysics, contributing to the scientific understanding of phosphorescence, isotope separation, optical microscopy, and X-ray diffraction. He is most noted for initiating and leading early X-ray diffraction studies on DNA at King's College London, and for his pivotal role in enabling the discovery of the double helix structure of DNA.

Wilkins began investigating nucleic acids in 1948. By 1950, he and his team had produced some of the first high-quality X-ray diffraction images of DNA fibers. He presented this work in 1951 at a conference in Naples, where it significantly influenced James Watson, prompting Watson to pursue DNA structure research with Francis Crick.

Phosphorus is a chemical element; it has symbol P and atomic number 15. All elemental forms of phosphorus are highly reactive and are therefore never found in nature. They can nevertheless be prepared artificially, the two most common allotropes being white phosphorus and red phosphorus. With P as its only stable isotope, phosphorus has an occurrence in Earth's crust of about 0.1%, generally as phosphate rock. A member of the pnictogen family, phosphorus readily forms a wide variety of organic and inorganic compounds, with as its main oxidation states +5, +3 and −3.

The isolation of white phosphorus in 1669 by Hennig Brand marked the scientific community's first discovery of an element since antiquity. The name phosphorus is a reference to the god of the Morning star in Greek mythology, inspired by the faint glow of white phosphorus when exposed to oxygen. This property is also at the origin of the term phosphorescence, meaning glow after illumination, although white phosphorus itself does not exhibit phosphorescence, but chemiluminescence caused by its oxidation. Its high toxicity makes exposure to white phosphorus very dangerous, while its flammability and pyrophoricity can be weaponised in the form of incendiaries. Red phosphorus is less dangerous and is used in matches and fire retardants.

A Tesla coil is an electrical resonant transformer device designed by inventor Nikola Tesla in 1891. It is used to produce high voltage, low current, high frequency alternating current. Tesla experimented with a number of different configurations consisting of two, or sometimes three, coupled resonant electric circuits.

Tesla used these devices to conduct innovative experiments in electrical lighting, phosphorescence, X-ray generation, high-frequency alternating current phenomena, electrotherapy, and the wireless transmission of electrical energy. Tesla coil circuits were used commercially in spark-gap transmitters for wireless telegraphy until the 1920s, and in medical equipment such as electrotherapy and violet ray devices. Today, their main usage is for entertainment and educational displays, although small coils are still used as leak detectors for high-vacuum systems.

A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam (cathode rays) in a cathode-ray tube.

When a phosphor is exposed to radiation, the orbital electrons in its molecules are excited to a higher energy level; when they return to their former level they emit the energy as light of a certain color. Phosphors can be classified into two categories: fluorescent substances which emit the energy immediately and stop glowing when the exciting radiation is turned off, and phosphorescent substances which emit the energy after a delay, so they keep glowing after the radiation is turned off, decaying in brightness over a period of milliseconds to days.

The optical properties of a material define how it interacts with light. The optical properties of matter are studied in optical physics (a subfield of optics) and applied in materials science. The optical properties of matter include:

• Refractive index
• Dispersion
• Transmittance and Transmission coefficient
• Absorption
• Scattering
• Turbidity
• Reflectance and Reflectivity (reflection coefficient)
• Albedo
• Perceived color
• Fluorescence
• Phosphorescence
• Photoluminescence
• Optical bistability
• Dichroism
• Birefringence
• Optical activity
• Photosensitivity

A basic distinction is between isotropic materials, which exhibit the same properties regardless of the direction of the light, and anisotropic ones, which exhibit different properties when light passes through them in different directions.

A scintillator (/ˈsɪntɪleɪtər/ SIN-til-ay-ter) is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the absorbed energy in the form of light). Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed (necessitating anywhere from a few nanoseconds to hours depending on the material). The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.

Witherite is a barium carbonate mineral, BaCO₃, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The specific gravity is 4.3, which is high for a translucent mineral. It fluoresces light blue under both long- and short-wave UV light, and is phosphorescent under short-wave UV light.

Witherite forms in low-temperature hydrothermal environments. It is commonly associated with fluorite, celestine, galena, barite, calcite, and aragonite. Witherite occurrences include: Cave-in-Rock, Illinois, US; Pigeon Roost Mine, Glenwood, Arkansas, US; Settlingstones Mine Northumberland; Alston Moor, Cumbria; Anglezarke, Lancashire and Burnhope, County Durham, England; Thunder Bay area, Ontario, Canada, Germany, and Poland (Tarnowskie Góry and Tajno at Suwałki Region).

Electron backscatter diffraction (EBSD) is a scanning electron microscopy (SEM) technique used to study the crystallographic structure of materials. EBSD is carried out in a scanning electron microscope equipped with an EBSD detector comprising at least a phosphorescent screen, a compact lens and a low-light camera. In the microscope an incident beam of electrons hits a tilted sample. As backscattered electrons leave the sample, they interact with the atoms and are both elastically diffracted and lose energy, leaving the sample at various scattering angles before reaching the phosphor screen forming Kikuchi patterns (EBSPs). The EBSD spatial resolution depends on many factors, including the nature of the material under study and the sample preparation. They can be indexed to provide information about the material's grain structure, grain orientation, and phase at the micro-scale. EBSD is used for impurities and defect studies, plastic deformation, and statistical analysis for average misorientation, grain size, and crystallographic texture. EBSD can also be combined with energy-dispersive X-ray spectroscopy (EDS), cathodoluminescence (CL), and wavelength-dispersive X-ray spectroscopy (WDS) for advanced phase identification and materials discovery.

The change and sharpness of the electron backscatter patterns (EBSPs) provide information about lattice distortion in the diffracting volume. Pattern sharpness can be used to assess the level of plasticity. Changes in the EBSP zone axis position can be used to measure the residual stress and small lattice rotations. EBSD can also provide information about the density of geometrically necessary dislocations (GNDs). However, the lattice distortion is measured relative to a reference pattern (EBSP₀). The choice of reference pattern affects the measurement precision; e.g., a reference pattern deformed in tension will directly reduce the tensile strain magnitude derived from a high-resolution map while indirectly influencing the magnitude of other components and the spatial distribution of strain. Furthermore, the choice of EBSP₀ slightly affects the GND density distribution and magnitude.

Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transitions from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. If the system in question is excited by some means other than heating, the spontaneous emission is called luminescence. There are different sub-categories of luminescence depending on how excited atoms are produced (electroluminescence, chemiluminescence etc.). If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Some systems have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission.

Spontaneous emission cannot be explained by classical electromagnetic theory and is fundamentally a quantum process. Albert Einstein first predicted the phenomenon of spontaneous emission in a series of papers starting in 1916, culminating in what is now called the Einstein A Coefficient. Einstein's quantum theory of radiation anticipated ideas later expressed in quantum electrodynamics and quantum optics by several decades. Later, after the formal discovery of quantum mechanics in 1926, the rate of spontaneous emission was accurately described from first principles by Paul Dirac in his quantum theory of radiation, the precursor to the theory which he later called quantum electrodynamics. Contemporary physicists, when asked to give a physical explanation for spontaneous emission, generally invoke the zero-point energy of the electromagnetic field. In 1963, the Jaynes–Cummings model was developed describing the system of a two-level atom interacting with a quantized field mode (i.e. the vacuum) within an optical cavity. This model predicted that the rate of spontaneous emission could be controlled depending on the boundary conditions of the surrounding vacuum field. These experiments gave rise to cavity quantum electrodynamics (CQED), the study of effects of mirrors and cavities on radiative corrections.

Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and softest of the lanthanides. It is soft enough to be cut with a knife. Europium was discovered in 1896, provisionally designated as Σ; in 1901, it was named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role but is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

Robert Williams Wood (May 2, 1868 – August 11, 1955) was an American physicist and inventor who made pivotal contributions to the field of optics. He pioneered infrared and ultraviolet photography. Wood's patents and theoretical work inform modern understanding of the physics of ultraviolet light, and made possible myriad uses of UV fluorescence, which became popular after World War I. He published many articles on spectroscopy, phosphorescence, diffraction, and ultraviolet light.

Luminous paint (or luminescent paint) is paint that emits visible light through fluorescence, phosphorescence, or radioluminescence.