Phonon in the context of "Electron energy loss spectroscopy"

The number density (symbol: n or ρ_N) is an intensive quantity used to describe the degree of concentration of countable objects (particles, molecules, phonons, cells, galaxies, etc.) in physical space: three-dimensional volumetric number density, two-dimensional areal number density, or one-dimensional linear number density. Population density is an example of areal number density. The term number concentration (symbol: lowercase n, or C, to avoid confusion with amount of substance indicated by uppercase N) is sometimes used in chemistry for the same quantity, particularly when comparing with other concentrations.

Rarefaction is the reduction of an item's density, the opposite of compression. Like compression, which can travel in waves (sound waves, for instance), rarefaction waves also exist in nature. A common rarefaction wave is the area of low relative pressure following a shock wave (see picture).

Rarefaction waves expand with time (much like sea waves spread out as they reach a beach); in most cases rarefaction waves keep the same overall profile ('shape') at all times throughout the wave's movement: it is a self-similar expansion. Each part of the wave travels at the local speed of sound, in the local medium. This expansion behaviour contrasts with that of pressure increases, which gets narrower with time until they steepen into shock waves.

In quantum mechanics, indistinguishable particles (also called identical or indiscernible particles) are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to, elementary particles (such as electrons), composite subatomic particles (such as atomic nuclei), as well as atoms and molecules. Although all known indistinguishable particles only exist at the quantum scale, there is no exhaustive list of all possible sorts of particles nor a clear-cut limit of applicability, as explored in quantum statistics. They were first discussed by Werner Heisenberg and Paul Dirac in 1926.

There are two main categories of identical particles: bosons, which can share quantum states, and fermions, which cannot (as described by the Pauli exclusion principle). Examples of bosons are photons, gluons, phonons, helium-4 nuclei and all mesons. Examples of fermions are electrons, neutrinos, quarks, protons, neutrons, and helium-3 nuclei.

An optical amplifier is a device that amplifies an optical signal directly, without the need to first convert it to an electrical signal. An optical amplifier may be thought of as a laser without an optical cavity, or one in which feedback from the cavity is suppressed. Optical amplifiers are important in optical communication and laser physics. They are used as optical repeaters in the long distance fiber-optic cables which carry much of the world's telecommunication links.

There are several different physical mechanisms that can be used to amplify a light signal, which correspond to the major types of optical amplifiers. In doped fiber amplifiers and bulk lasers, stimulated emission in the amplifier's gain medium causes amplification of incoming light. In semiconductor optical amplifiers (SOAs), electron–hole recombination occurs. In Raman amplifiers, Raman scattering of incoming light with phonons in the lattice of the gain medium produces photons coherent with the incoming photons. Parametric amplifiers use parametric amplification.

A clathrate is a chemical substance consisting of a lattice that traps or contains molecules. The word clathrate is derived from the Latin clathratus (clatratus), meaning 'with bars, latticed'. Most clathrate compounds are polymeric and completely envelop the guest molecule, but in modern usage clathrates also include host–guest complexes and inclusion compounds. According to IUPAC, clathrates are inclusion compounds "in which the guest molecule is in a cage formed by the host molecule or by a lattice of host molecules." The term refers to many molecular hosts, including calixarenes and cyclodextrins and even some inorganic polymers such as zeolites.

Clathrates can be divided into two categories: clathrate hydrates and inorganic clathrates. Each clathrate is made up of a framework and guests that reside the framework. Most common clathrate crystal structures can be composed of cavities such as dodecahedral, tetrakaidecahedral, and hexakaidecahedral cavities.Unlike hydrates, inorganic clathrates have a covalently bonded framework of inorganic atoms with guests typically consisting of alkali or alkaline earth metals. Due to the stronger covalent bonding, the cages are often smaller than hydrates. Guest atoms interact with the host by ionic or covalent bonds. Therefore, partial substitution of guest atoms follow Zintl rules so that the charge of the overall compound is conserved. Most inorganic clathrates have full occupancy of its framework cages by a guest atom to be in stable phase. Inorganic clathrates can be synthesized by direct reaction using ball milling at high temperatures or high pressures. Crystallization from melt is another common synthesis route. Due to the wide variety of composition of host and guest species, inorganic clathrates are much more chemically diverse and possess a wide range of properties. Most notably, inorganic clathrates can be found to be both an insulator and a superconductor (Ba₈Si₄₆). A common property of inorganic clathrates that has attracted researchers is low thermal conductivity. Low thermal conductivity is attributed to the ability of the guest atom to "rattle" within the host framework. The freedom of movement of the guest atoms scatters phonons that transport heat.

In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature).

The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy level is known as de-excitation and is the inverse of excitation.

In condensed matter physics, a quasiparticle is a concept used to describe a collective behavior of a group of particles that can be treated as if they were a single particle. Formally, quasiparticles and collective excitations are closely related phenomena that arise when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.

For example, as an electron travels through a semiconductor, its motion is disturbed in a complex way by its interactions with other electrons and with atomic nuclei. The electron behaves as though it has a different effective mass travelling unperturbed in vacuum. Such an electron is called an electron quasiparticle. In another example, the aggregate motion of electrons in the valence band of a semiconductor or a hole band in a metal behave as though the material instead contained positively charged quasiparticles called electron holes. Other quasiparticles or collective excitations include the phonon, a quasiparticle derived from the vibrations of atoms in a solid, and the plasmon, a particle derived from plasma oscillation.

Neutron scattering, the irregular dispersal of free neutrons by matter, can refer to either the naturally occurring physical process itself or to the man-made experimental techniques that use the natural process for investigating materials. The natural/physical phenomenon is of elemental importance in nuclear engineering and the nuclear sciences. Regarding the experimental technique, understanding and manipulating neutron scattering is fundamental to the applications used in crystallography, physics, physical chemistry, biophysics, and materials research.

Neutron scattering is practiced at research reactors and spallation neutron sources that provide neutron radiation of varying intensities. Neutron diffraction (elastic scattering) techniques are used for analyzing structures; where inelastic neutron scattering is used in studying atomic vibrations and other excitations.

In nuclear physics, atomic recoil is the result of the interaction of an atom with an energetic elementary particle, when the momentum of the interacting particle is transferred to the atom as a whole without altering non-translational degrees of freedom of the atom. It is a purely quantum phenomenon. Atomic recoil was discovered by Harriet Brooks, Canada's first female nuclear physicist, in 1904, but interpreted wrongly. Otto Hahn reworked, explained and demonstrated it in 1908/09.The physicist Walther Gerlach described radioactive recoil as "a profoundly significant discovery in physics with far-reaching consequences".

If the transferred momentum of atomic recoil is enough to disrupt the crystal lattice of the material, a vacancy defect is formed; therefore a phonon is generated.

Raman spectroscopy (/ˈrɑːmən/) (named after physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which molecules can be identified.

Raman spectroscopy relies upon inelastic scattering of photons, known as Raman scattering. A source of monochromatic light, usually from a laser in the visible, near infrared, or near ultraviolet range is used, although X-rays can also be used. The laser light interacts with molecular vibrations, phonons or other excitations in the system, resulting in the energy of the laser photons being shifted up or down. The shift in energy gives information about the vibrational modes in the system. Time-resolved spectroscopy and infrared spectroscopy typically yield similar yet complementary information.

The Lorentz oscillator model (classical electron oscillator or CEO model) describes the optical response of bound charges. The model is named after the Dutch physicist Hendrik Antoon Lorentz. It is a classical, phenomenological model for materials with characteristic resonance frequencies (or other characteristic energy scales) for optical absorption, e.g. ionic and molecular vibrations, interband transitions (semiconductors), phonons, and collective excitations.

A polaron is a quasiparticle used in condensed matter physics to understand the interactions between electrons and atoms in a solid material. The polaron concept was proposed by Lev Landau in 1933 and Solomon Pekar in 1946 to describe an electron moving in a dielectric crystal where the atoms displace from their equilibrium positions to effectively screen the charge of an electron, known as a phonon cloud. This lowers the electron mobility and increases the electron's effective mass.

The general concept of a polaron has been extended to describe other interactions between the electrons and ions in metals that result in a bound state, or a lowering of energy compared to the non-interacting system. Major theoretical work has focused on solving Fröhlich and Holstein Hamiltonians. This is still an active field of research to find exact numerical solutions to the case of one or two electrons in a large crystal lattice, and to study the case of many interacting electrons.