P-orbital in the context of Domain coloring


P-orbital in the context of Domain coloring

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⭐ Core Definition: P-orbital

In quantum mechanics, an atomic orbital (/ˈɔːrbɪtəl/ ) is a function describing the location and wave-like behavior of an electron in an atom. This function describes an electron's charge distribution around the atom's nucleus, and can be used to calculate the probability of finding an electron in a specific region around the nucleus.

Each orbital in an atom is characterized by a set of values of three quantum numbers n, , and m, which respectively correspond to an electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis (magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally complex-valued. Real-valued orbitals can be formed as linear combinations of m and −m orbitals, and are often labeled using associated harmonic polynomials (e.g., xy, xy) which describe their angular structure.

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P-orbital in the context of Conjugation (organic chemistry)

In physical organic chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds. Lone pairs, radicals or carbenium ions may be part of the system, which may be cyclic, acyclic, linear or mixed. The term "conjugated" was coined in 1899 by the German chemist Johannes Thiele.

Conjugation is the overlap of one p-orbital with another across an adjacent σ bond. (In transition metals, d-orbitals can be involved.)

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